IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v182y2022icp443-451.html
   My bibliography  Save this article

Valorization of biomass-derived CO2 residues with Cu-MnOx catalysts for RWGS reaction

Author

Listed:
  • González-Arias, Judith
  • González-Castaño, Miriam
  • Sánchez, Marta Elena
  • Cara-Jiménez, Jorge
  • Arellano-García, Harvey

Abstract

This study delivers useful understanding towards the design of effective catalytic systems for upgrading real CO2–rich residual streams derived from biomass valorization. Within this perspective, a catalysts' series based on (5 wt%) Cu - (X wt%) Mn/Al2O3 with X = 0, 3, 8 and 10 is employed. The improved catalyst performance achieved through Mn incorporation is ascribed to enhanced Cu dispersions and promoted surface basic concentrations. Under standard RWGS conditions, the highest reaction rates achieved by (5 wt%) Cu - (8 wt%) Mn/Al2O3 catalyst were associated to improved Cu dispersions along with the constitution of highly active Cu-MnOx domains. Remarkably, variations on the optimal Cu to Mn ratios were detected as a function of the RWGS reaction conditions. Thus, under simulated CO2-rich residual feedstock's, i.e., in presence of CO and CH4, the further promotion on the Cu dispersion attained by the larger amounts of MnOx rendered the (5 wt%) Cu - (10 wt%) Mn/Al2O3 catalyst as the best performing sample. Overall, the presented outcomes underline operative strategies for developing catalytic systems with advanced implementation potentialities.

Suggested Citation

  • González-Arias, Judith & González-Castaño, Miriam & Sánchez, Marta Elena & Cara-Jiménez, Jorge & Arellano-García, Harvey, 2022. "Valorization of biomass-derived CO2 residues with Cu-MnOx catalysts for RWGS reaction," Renewable Energy, Elsevier, vol. 182(C), pages 443-451.
  • Handle: RePEc:eee:renene:v:182:y:2022:i:c:p:443-451
    DOI: 10.1016/j.renene.2021.10.029
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121014865
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2021.10.029?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Diamantis, Vasileios & Eftaxias, Alexandros & Stamatelatou, Katerina & Noutsopoulos, Constantinos & Vlachokostas, Christos & Aivasidis, Alexandros, 2021. "Bioenergy in the era of circular economy: Anaerobic digestion technological solutions to produce biogas from lipid-rich wastes," Renewable Energy, Elsevier, vol. 168(C), pages 438-447.
    2. Cheng-Shiuan Li & Gérôme Melaet & Walter T. Ralston & Kwangjin An & Christopher Brooks & Yifan Ye & Yi-Sheng Liu & Junfa Zhu & Jinghua Guo & Selim Alayoglu & Gabor A. Somorjai, 2015. "High-performance hybrid oxide catalyst of manganese and cobalt for low-pressure methanol synthesis," Nature Communications, Nature, vol. 6(1), pages 1-5, May.
    3. Pagés-Díaz, Jhosané & Cerda Alvarado, Andrés Osvaldo & Montalvo, Silvio & Diaz-Robles, Luis & Curio, César Huiliñir, 2020. "Anaerobic bio-methane potential of the liquors from hydrothermal carbonization of different lignocellulose biomasses," Renewable Energy, Elsevier, vol. 157(C), pages 182-189.
    4. Ateka, Ainara & Portillo, Ander & Sánchez-Contador, Miguel & Bilbao, Javier & Aguayo, Andres T., 2021. "Macro-kinetic model for CuO–ZnO–ZrO2@SAPO-11 core-shell catalyst in the direct synthesis of DME from CO/CO2," Renewable Energy, Elsevier, vol. 169(C), pages 1242-1251.
    5. Dasireddy, Venkata D.B.C. & Valand, Jignesh & Likozar, Blaž, 2018. "PROX reaction of CO in H2/H2O/CO2 Water–Gas Shift (WGS) feedstocks over Cu–Mn/Al2O3 and Cu–Ni/Al2O3 catalysts for fuel cell applications," Renewable Energy, Elsevier, vol. 116(PA), pages 75-87.
    6. Shrestha, Ankita & Acharya, Bishnu & Farooque, Aitazaz A., 2021. "Study of hydrochar and process water from hydrothermal carbonization of sea lettuce," Renewable Energy, Elsevier, vol. 163(C), pages 589-598.
    7. Li, Liang & Flora, Joseph R.V. & Berge, Nicole D., 2020. "Predictions of energy recovery from hydrochar generated from the hydrothermal carbonization of organic wastes," Renewable Energy, Elsevier, vol. 145(C), pages 1883-1889.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aragon-Briceño, Christian & Pożarlik, Artur & Bramer, Eddy & Brem, Gerrit & Wang, Shule & Wen, Yuming & Yang, Weihong & Pawlak-Kruczek, Halina & Niedźwiecki, Łukasz & Urbanowska, Agnieszka & Mościcki,, 2022. "Integration of hydrothermal carbonization treatment for water and energy recovery from organic fraction of municipal solid waste digestate," Renewable Energy, Elsevier, vol. 184(C), pages 577-591.
    2. Aragón-Briceño, C.I. & Ross, A.B. & Camargo-Valero, M.A., 2021. "Mass and energy integration study of hydrothermal carbonization with anaerobic digestion of sewage sludge," Renewable Energy, Elsevier, vol. 167(C), pages 473-483.
    3. Wang, Ruikun & Liu, Senyang & Xue, Qiao & Lin, Kai & Yin, Qianqian & Zhao, Zhenghui, 2022. "Analysis and prediction of characteristics for solid product obtained by hydrothermal carbonization of biomass components," Renewable Energy, Elsevier, vol. 183(C), pages 575-585.
    4. Yang, Le & Lin, Hongju & Fang, Zhihao & Yang, Yanhui & Liu, Xiaohao & Ouyang, Gangfeng, 2023. "Recent advances on methane partial oxidation toward oxygenates under mild conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    5. Śliz, Maciej & Wilk, Małgorzata, 2020. "A comprehensive investigation of hydrothermal carbonization: Energy potential of hydrochar derived from Virginia mallow," Renewable Energy, Elsevier, vol. 156(C), pages 942-950.
    6. Xu, Xiaodong & Sielicki, Krzysztof & Min, Jiakang & Li, Jiaxin & Hao, Chuncheng & Wen, Xin & Chen, Xuecheng & Mijowska, Ewa, 2022. "One-step converting biowaste wolfberry fruits into hierarchical porous carbon and its application for high-performance supercapacitors," Renewable Energy, Elsevier, vol. 185(C), pages 187-195.
    7. Dasireddy, Venkata D.B.C. & Likozar, Blaž, 2022. "Cu–Mn–O nano-particle/nano-sheet spinel-type materials as catalysts in methanol steam reforming (MSR) and preferential oxidation (PROX) reaction for purified hydrogen production," Renewable Energy, Elsevier, vol. 182(C), pages 713-724.
    8. Marcin Dębowski & Marcin Zieliński & Joanna Kazimierowicz & Anna Nowicka & Magda Dudek, 2024. "Optimisation of Biogas Production in the Co-Digestion of Pre-Hydrodynamically Cavitated Aerobic Granular Sludge with Waste Fats," Energies, MDPI, vol. 17(4), pages 1-16, February.
    9. Magdziarz, Aneta & Mlonka-Mędrala, Agata & Sieradzka, Małgorzata & Aragon-Briceño, Christian & Pożarlik, Artur & Bramer, Eddy A. & Brem, Gerrit & Niedzwiecki, Łukasz & Pawlak-Kruczek, Halina, 2021. "Multiphase analysis of hydrochars obtained by anaerobic digestion of municipal solid waste organic fraction," Renewable Energy, Elsevier, vol. 175(C), pages 108-118.
    10. Aaron E. Brown & Jessica M. M. Adams & Oliver R. Grasham & Miller Alonso Camargo-Valero & Andrew B. Ross, 2020. "An Assessment of Different Integration Strategies of Hydrothermal Carbonisation and Anaerobic Digestion of Water Hyacinth," Energies, MDPI, vol. 13(22), pages 1-26, November.
    11. Joana Silva & Rita Fragoso, 2023. "Enhanced Biomethanation: The Impact of Incorporating Fish Waste on the Co-Digestion of Pig Slurry and Orange Pomace," Energies, MDPI, vol. 16(16), pages 1-14, August.
    12. Alexandros Eftaxias & Evangelia Anna Passa & Christos Michailidis & Christodoulos Daoutis & Apostolos Kantartzis & Vasileios Diamantis, 2022. "Residual Forest Biomass in Pinus Stands: Accumulation and Biogas Production Potential," Energies, MDPI, vol. 15(14), pages 1-11, July.
    13. Lu, Peng & Chang, Xiaoning & Yu, Wenjia & Hu, Qianwen & Ali, Kime Mala & Xing, Chuang & Du, Ce & Yang, Zhixiang & Chen, Shuyao, 2023. "Synergistic effects of ZnO–ZrO2@SAPO-34 core-shell catalyst in catalyzing CO2 hydrogenation for the synthesis of light olefins," Renewable Energy, Elsevier, vol. 209(C), pages 546-557.
    14. Swarna Saha & Md Tahmid Islam & Joshua Calhoun & Toufiq Reza, 2023. "Effect of Hydrothermal Carbonization on Fuel and Combustion Properties of Shrimp Shell Waste," Energies, MDPI, vol. 16(14), pages 1-15, July.
    15. Logan, Mohanakrishnan & Tan, Lea Chua & Nzeteu, Corine Orline & Lens, Piet N.L., 2023. "Effect of selenate on treatment of glycerol containing wastewater in UASB reactors," Renewable Energy, Elsevier, vol. 206(C), pages 97-110.
    16. Ramirez-Corredores, M.M. & Diaz, Luis A. & Gaffney, Anne M. & Zarzana, Christopher A., 2021. "Identification of opportunities for integrating chemical processes for carbon (dioxide) utilization to nuclear power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    17. Anna Jasińska & Anna Grosser & Erik Meers & Dagmara Piłyp, 2024. "Stimulating Methane Production from Poultry Manure Digest with Sewage Sludge and Organic Waste by Thermal Pretreatment and Adding Iron or Sodium Hydroxide," Energies, MDPI, vol. 17(11), pages 1-23, May.
    18. Djandja, Oraléou Sangué & Salami, Adekunlé Akim & Wang, Zhi-Cong & Duo, Jia & Yin, Lin-Xin & Duan, Pei-Gao, 2022. "Random forest-based modeling for insights on phosphorus content in hydrochar produced from hydrothermal carbonization of sewage sludge," Energy, Elsevier, vol. 245(C).
    19. Xu, Fuqing & Okopi, Solomon Inalegwu & Jiang, Yongmei & Chen, Zhou & Meng, Liyun & Li, Yebo & Sun, Weimin & Li, Chaokun, 2022. "Multi-criteria assessment of food waste and waste paper anaerobic co-digestion: Effects of inoculation ratio, total solids content, and feedstock composition," Renewable Energy, Elsevier, vol. 194(C), pages 40-50.
    20. Sica, Daniela & Esposito, Benedetta & Supino, Stefania & Malandrino, Ornella & Sessa, Maria Rosaria, 2023. "Biogas-based systems: An opportunity towards a post-fossil and circular economy perspective in Italy," Energy Policy, Elsevier, vol. 182(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:182:y:2022:i:c:p:443-451. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.