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Pyrolysis kinetics and product distribution of α-cellulose: Effect of potassium and calcium impregnation

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  • Tran, Quoc Khanh
  • Vo, Thuan Anh
  • Ly, Hoang Vu
  • Kwon, Byeongwan
  • Kim, Kwang Ho
  • Kim, Seung-Soo
  • Kim, Jinsoo

Abstract

Cellulose accounts for the largest proportion of lignocellulosic biomass. Herein, experimental and simulation studies are used to deeply understand the kinetic characteristics of the thermal decomposition of α-cellulose. The simulated data is in good agreement with the experimental data in the aspects of the conversion and the conversion rate versus temperature. The decomposition of α-cellulose, mainly occurring at 270–420 °C, induced an apparent activation energy ranging from 175.42 kJ/mol to 197.73 kJ/mol at a conversion of 10–90%. With 0.1–0.2 wt% K or Ca impregnation into the α-cellulose, the mean activation energy for pyrolysis was lowered (from 181.47 kJ/mol (for α-cellulose) to 141.11 kJ/mol (for 0.2 wt% K/α-cellulose) and 159.46 kJ/mol (for 0.1 wt% Ca/α-cellulose)) and higher amounts of liquid and gas products were produced. Furthermore, the addition of potassium and calcium increased the production of lower molecular weight components, such as furfural and its derivatives. The kinetic parameters of the α-cellulose pyrolysis were determined based on a nonlinear least-squares regression of the experimental data assuming first-order kinetics and correlated with the simulated result. The kinetic rate constants indicate that the predominant reaction pathway is from α-cellulose into a liquid product, rather than from α-cellulose into a gas product.

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  • Tran, Quoc Khanh & Vo, Thuan Anh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Kwang Ho & Kim, Seung-Soo & Kim, Jinsoo, 2022. "Pyrolysis kinetics and product distribution of α-cellulose: Effect of potassium and calcium impregnation," Renewable Energy, Elsevier, vol. 181(C), pages 329-340.
  • Handle: RePEc:eee:renene:v:181:y:2022:i:c:p:329-340
    DOI: 10.1016/j.renene.2021.08.098
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    References listed on IDEAS

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    1. Vo, The Ky & Ly, Hoang Vu & Lee, Ok Kyung & Lee, Eun Yeol & Kim, Chul Ho & Seo, Jeong-Woo & Kim, Jinsoo & Kim, Seung-Soo, 2017. "Pyrolysis characteristics and kinetics of microalgal Aurantiochytrium sp. KRS101," Energy, Elsevier, vol. 118(C), pages 369-376.
    2. Ly, Hoang Vu & Kim, Jinsoo & Kim, Seung-Soo, 2013. "Pyrolysis characteristics and kinetics of palm fiber in a closed reactor," Renewable Energy, Elsevier, vol. 54(C), pages 91-95.
    3. Ly, Hoang Vu & Park, Jeong Woo & Kim, Seung-Soo & Hwang, Hyun Tae & Kim, Jinsoo & Woo, Hee Chul, 2020. "Catalytic pyrolysis of bamboo in a bubbling fluidized-bed reactor with two different catalysts: HZSM-5 and red mud for upgrading bio-oil," Renewable Energy, Elsevier, vol. 149(C), pages 1434-1445.
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