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A simplified kinetic model based on a universal description for solid fuels pyrolysis: Theoretical derivation, experimental validation, and application demonstration

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  • Gu, Tianbao
  • Fu, Zhufu
  • Berning, Torsten
  • Li, Xuantian
  • Yin, Chungen

Abstract

A kinetic model for the prediction of the conversion rate is crucial for research and development of biomass pyrolysis. The complexity of the existing kinetic studies and the diversity in pyrolysis kinetic data largely compromise the application of kinetic models. For the purpose of developing a generalized kinetic model, in this paper, we derive a universal description for all the common reaction mechanisms of solid fuels pyrolysis, among which the first-order reactions can be described as standardized general extreme value distribution. Based on the universal description, a simplified kinetic model with only one kinetic parameter is proposed. Then, we perform an experimental study of cellulose and poplar wood pyrolysis in order to validate the new model and to demonstrate its usefulness. The prediction results of the new model are very consistent with those from the conventional Arrhenius model and also agree well with the experimental data. Afterwards, the new model is applied to evaluate the kinetics for poplar wood pyrolysis, and comparisons between our model results and the commonly used Friedman method in terms of accuracy and applicability are shown. The new model also illustrates that the activation energies vary remarkably with the conversion degree and heating rate.

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  • Gu, Tianbao & Fu, Zhufu & Berning, Torsten & Li, Xuantian & Yin, Chungen, 2021. "A simplified kinetic model based on a universal description for solid fuels pyrolysis: Theoretical derivation, experimental validation, and application demonstration," Energy, Elsevier, vol. 225(C).
    • Handle: RePEc:eee:energy:v:225:y:2021:i:c:s0360544221003820
    DOI: 10.1016/j.energy.2021.120133
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    1. Gu, Tianbao & Yin, Chungen & Ma, Wenchao & Chen, Guanyi, 2019. "Municipal solid waste incineration in a packed bed: A comprehensive modeling study with experimental validation," Applied Energy, Elsevier, vol. 247(C), pages 127-139.
    2. Heidari, Mohammad & Salaudeen, Shakirudeen & Arku, Precious & Acharya, Bishnu & Tasnim, Syeda & Dutta, Animesh, 2021. "Development of a mathematical model for hydrothermal carbonization of biomass: Comparison of experimental measurements with model predictions," Energy, Elsevier, vol. 214(C).
    3. Sharma, Abhishek & Pareek, Vishnu & Zhang, Dongke, 2015. "Biomass pyrolysis—A review of modelling, process parameters and catalytic studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1081-1096.
    4. Fang, Shiwen & Yu, Zhaosheng & Ma, Xiaoqian & Lin, Yan & Chen, Lin & Liao, Yanfen, 2018. "Analysis of catalytic pyrolysis of municipal solid waste and paper sludge using TG-FTIR, Py-GC/MS and DAEM (distributed activation energy model)," Energy, Elsevier, vol. 143(C), pages 517-532.
    5. Siddiqi, Hammad & Kumari, Usha & Biswas, Subrata & Mishra, Asmita & Meikap, B.C., 2020. "A synergistic study of reaction kinetics and heat transfer with multi-component modelling approach for the pyrolysis of biomass waste," Energy, Elsevier, vol. 204(C).
    6. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    7. Vo, The Ky & Ly, Hoang Vu & Lee, Ok Kyung & Lee, Eun Yeol & Kim, Chul Ho & Seo, Jeong-Woo & Kim, Jinsoo & Kim, Seung-Soo, 2017. "Pyrolysis characteristics and kinetics of microalgal Aurantiochytrium sp. KRS101," Energy, Elsevier, vol. 118(C), pages 369-376.
    8. Almazrouei, Manar & Janajreh, Isam, 2020. "Model-fitting approach to kinetic analysis of non-isothermal pyrolysis of pure and crude glycerol," Renewable Energy, Elsevier, vol. 145(C), pages 1693-1708.
    9. Nzihou, Ange & Stanmore, Brian & Lyczko, Nathalie & Minh, Doan Pham, 2019. "The catalytic effect of inherent and adsorbed metals on the fast/flash pyrolysis of biomass: A review," Energy, Elsevier, vol. 170(C), pages 326-337.
    10. Wang, Shurong & Dai, Gongxin & Ru, Bin & Zhao, Yuan & Wang, Xiaoliu & Xiao, Gang & Luo, Zhongyang, 2017. "Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose," Energy, Elsevier, vol. 120(C), pages 864-871.
    11. López-González, D. & Avalos-Ramirez, A. & Giroir-Fendler, A. & Godbout, S. & Fernandez-Lopez, M. & Sanchez-Silva, L. & Valverde, J.L., 2015. "Combustion kinetic study of woody and herbaceous crops by thermal analysis coupled to mass spectrometry," Energy, Elsevier, vol. 90(P2), pages 1626-1635.
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    1. Zhang, Jidan & Ji, Wenhui & Yuan, Yanping & Nan, Wei & Yuan, Wenhui, 2024. "Pyrolysis characteristics and kinetics study of four typical trolley case materials in passenger trains," Energy, Elsevier, vol. 292(C).
    2. Sharma, Ajay & Aravind Kumar, A. & Mohanty, Bikash & Sawarkar, Ashish N., 2023. "Critical insights into pyrolysis and co-pyrolysis of poplar and eucalyptus wood sawdust: Physico-chemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis," Renewable Energy, Elsevier, vol. 210(C), pages 321-334.
    3. Tianbao Gu & Torsten Berning & Chungen Yin, 2021. "Application of a New Statistical Model for the Description of Solid Fuel Decomposition in the Analysis of Artemisia apiacea Pyrolysis," Energies, MDPI, vol. 14(18), pages 1-12, September.

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