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Chemical pretreatment of sugarcane bagasse with liquid fraction recycling

Author

Listed:
  • Vaz, Fernanda Leitão
  • da Rocha Lins, Jennyfer
  • Alves Alencar, Bárbara Ribeiro
  • Silva de Abreu, Íthalo Barbosa
  • Vidal, Esteban Espinosa
  • Ribeiro, Ester
  • Valadares de Sá Barretto Sampaio, Everardo
  • Cezar Menezes, Rômulo Simões
  • Dutra, Emmanuel Damilano

Abstract

Pre-treating lignocellulosic biomass is a major technological challenge. Recycling the liquid fraction may reduce chemical inputs and water use but may have lower efficiency. Seven chemical pre-treatments of sugarcane bagasse were compared: four acids (sulfuric, citric, phosphoric, and oxalic), two alkaline (sodium and calcium hydroxides) and an oxidative (alkaline hydrogen peroxide). The liquid fractions resulting from these pre-treatments were reused up to five times. After each pre-treatment cycle, the solid fraction was hydrolyzed with Celluclast 1.5L enzyme in a 1:10 solid-liquid ratio. Sulfuric and oxalic acids solubilized 80% of the hemicellulose over the cycles. Sodium and calcium hydroxides and hydrogen peroxide removed lignin until the fourth cycle. About 70% of lignin were removed with alkaline hydrogen peroxide. This pre-treatment lead to the highest glucose release after the enzymatic hydrolysis, above 50% in the three cycles analyzed. The best efficiency in enzymatic hydrolysis followed the order H2O2-alkaline > NaOH > oxalic acid > phosphoric acid > H2SO4 > citric acid > Ca (OH)2. With the recycling, more than 62% in reagents used in the pre-treatment of sugarcane bagasse were saved, enabling an economy in the costs at this stage of the process.

Suggested Citation

  • Vaz, Fernanda Leitão & da Rocha Lins, Jennyfer & Alves Alencar, Bárbara Ribeiro & Silva de Abreu, Íthalo Barbosa & Vidal, Esteban Espinosa & Ribeiro, Ester & Valadares de Sá Barretto Sampaio, Everardo, 2021. "Chemical pretreatment of sugarcane bagasse with liquid fraction recycling," Renewable Energy, Elsevier, vol. 174(C), pages 666-673.
  • Handle: RePEc:eee:renene:v:174:y:2021:i:c:p:666-673
    DOI: 10.1016/j.renene.2021.04.087
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    References listed on IDEAS

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