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Biolubricant base stock with improved low temperature performance: Ester complex production using housefly (Musca domestica L.) larval lipid

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  • Wu, Sheng-qing
  • Sun, Ting-ting
  • Cai, Zi-zhe
  • Shen, Juan
  • Yang, Wen-zhe
  • Zhao, Zhi-min
  • Yang, De-po

Abstract

Lipid generated from housefly (Musca domestica L.) larvae fed by municipal waste is a renewable lipid resource, however, the low unsaturated degree prevents it from producing trimethylolpropane fatty acid triester as lubricant, due to its poor low-temperature performance. A new fatty acid esters complex consisting of trimethylolpropane fatty acid triester and 2-ethylhexyl fatty acid ester was produced from housefly larval lipid. Separated from molecular distillation, the acylglycerols were first trans-esterified into fatty acid methyl ester and then further trans-esterified with trimethylolpropane into trimethylolpropane esters. The purified trimethylolpropane fatty acid triester is with purity of 98.4% and further blended with 30 wt% 2-ethylhexyl fatty acid ester derived from housefly larval free fatty acid. The pour point was substantially lowered from −3 °C to −12 °C while the lubricity performance is within standard of ISO VG 32, with minor improvement of water separability compared with pure trimethylolpropane fatty acid triester. By blending two type bio-lubricants with different advantages on viscosity and pour point, the ester complex with favorable properties was produced using saturated non-food lipid source rather than unsaturated virginal vegetable oil. This study also offers a cleaner and energy-efficient approach for high value-added product production for non-food lipid industry.

Suggested Citation

  • Wu, Sheng-qing & Sun, Ting-ting & Cai, Zi-zhe & Shen, Juan & Yang, Wen-zhe & Zhao, Zhi-min & Yang, De-po, 2020. "Biolubricant base stock with improved low temperature performance: Ester complex production using housefly (Musca domestica L.) larval lipid," Renewable Energy, Elsevier, vol. 162(C), pages 1940-1951.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:1940-1951
    DOI: 10.1016/j.renene.2020.10.001
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    References listed on IDEAS

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    1. Zheng, Longyu & Li, Qing & Zhang, Jibin & Yu, Ziniu, 2012. "Double the biodiesel yield: Rearing black soldier fly larvae, Hermetia illucens, on solid residual fraction of restaurant waste after grease extraction for biodiesel production," Renewable Energy, Elsevier, vol. 41(C), pages 75-79.
    2. Feng, Weiliang & Xiong, Huan & Wang, Weiguo & Duan, Xiaoling & Yang, Tong & Wu, Cheng & Yang, Fang & Wang, Teilin & Wang, Cunwen, 2020. "A facile and mild one-pot process for direct extraction of lipids from wet energy insects of black soldier fly larvae," Renewable Energy, Elsevier, vol. 147(P1), pages 584-593.
    3. Yang, Sen & Li, Qing & Gao, Yang & Zheng, Longyu & Liu, Ziduo, 2014. "Biodiesel production from swine manure via housefly larvae (Musca domestica L.)," Renewable Energy, Elsevier, vol. 66(C), pages 222-227.
    4. Li, Zhuoxue & Yang, Depo & Huang, Miaoling & Hu, Xinjun & Shen, Jiangang & Zhao, Zhimin & Chen, Jianping, 2012. "Chrysomya megacephala (Fabricius) larvae: A new biodiesel resource," Applied Energy, Elsevier, vol. 94(C), pages 349-354.
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    6. Wu, Sheng-qing & Cai, Zi-zhe & Niu, Yi & Zheng, Dong & He, Guo-rui & Wang, Yong & Yang, De-po, 2017. "A renewable lipid source for biolubricant feedstock oil from housefly (Musca domestica) larva," Renewable Energy, Elsevier, vol. 113(C), pages 546-553.
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    1. Bahadi, Murad & Salimon, Jumat & Derawi, Darfizzi, 2021. "Synthesis of di-trimethylolpropane tetraester-based biolubricant from Elaeis guineensis kernel oil via homogeneous acid-catalyzed transesterification," Renewable Energy, Elsevier, vol. 171(C), pages 981-993.
    2. Ji Eun Lee & Hyun Sung Jang & Yeo Jin Yun & Gi Bo Han & Young Kyu Park & Young Cheol Yang & Jung Hee Jang, 2024. "Application of the Hydrodeoxygenation of Black Soldier Fly Larvae Lipids in Green Diesel Production," Sustainability, MDPI, vol. 16(2), pages 1-12, January.
    3. Nor, Nurazira Mohd & Salih, Nadia & Salimon, Jumat, 2022. "Optimization and lubrication properties of Malaysian crude palm oil fatty acids based neopentyl glycol diester green biolubricant," Renewable Energy, Elsevier, vol. 200(C), pages 942-956.
    4. Xie, Min & Xu, Daqian & Shen, Juanjuan & Zhang, Chunyun, 2024. "Achieving the good thermal-stability and lubricity via a dihydroxy biolubricant from the agro-waste of Codonopsis pilosula," Renewable Energy, Elsevier, vol. 221(C).

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