IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v160y2020icp42-51.html
   My bibliography  Save this article

Biodiesel production via stearic acid esterification over mesoporous ZrO2/SiO2 catalysts synthesized by surfactant-assisted sol-gel auto-combustion route

Author

Listed:
  • Mahmoud, Hala R.
  • El-Molla, Sahar A.
  • Ibrahim, Marwa M.

Abstract

Biodiesel production from the esterification of stearic acid with ethanol catalyzed by the mesoporous ZrO2/SiO2 catalysts which successfully synthesized by surfactant-assisted sol-gel auto-combustion method. These catalysts were characterized by various physico-chemical techniques such as XRD, BET surface area measurement, HR-TEM and NH3-TPD. The mesoporous catalyst prepared with cationic surfactant (ZrSiOC) showed a maximum BET surface area and pore volume. Interestingly, the ZrSiOC catalyst exhibited the largest acidity value among all catalysts. The results showed that the mesoporous ZrO2/SiO2 catalysts prepared with cationic (ZrSiOC) and non-ionic (ZrSiOT) surfactants demonstrated higher stearic acid conversion than those with anionic (ZrSiOS) or without surfactant (ZrSiO). Significantly, the ZrSiOC and ZrSiOT catalysts exhibited the highest conversion of 69.2% and 63.1% at 120 °C after 3 h, respectively. Additionally, it was observed that the conversion increased extremely with increasing the reaction temperature giving a maximum conversion of 76.9% at 125 °C by using the most active catalyst (ZrSiOC). Interestingly, the ZrSiOC catalyst displays suitable recycling as it kept performance of 72.5% after five recycle runs without significant lack in performance. Moreover, the kinetic study confirmed that esterification follows pseudo first-order equation.

Suggested Citation

  • Mahmoud, Hala R. & El-Molla, Sahar A. & Ibrahim, Marwa M., 2020. "Biodiesel production via stearic acid esterification over mesoporous ZrO2/SiO2 catalysts synthesized by surfactant-assisted sol-gel auto-combustion route," Renewable Energy, Elsevier, vol. 160(C), pages 42-51.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:42-51
    DOI: 10.1016/j.renene.2020.06.005
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120308983
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.06.005?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Malhotra, Rashi & Ali, Amjad, 2018. "Lithium-doped ceria supported SBA−15 as mesoporous solid reusable and heterogeneous catalyst for biodiesel production via simultaneous esterification and transesterification of waste cottonseed oil," Renewable Energy, Elsevier, vol. 119(C), pages 32-44.
    2. Almeida, T.A. & Rodrigues, I.A. & Estrela, T.S. & Nunes, C.N.F. & Machado, L.L. & Leão, K.V. & Barros, I.C.L. & Amorim, F.A.C. & Braga, V.S., 2016. "Synthesis of ethyl biodiesel from soybean oil, frying oil and chicken fat, using catalysts based on vanadium pentoxide," Energy, Elsevier, vol. 97(C), pages 528-533.
    3. Wan, Zuraida & Lim, J.K. & Hameed, B.H., 2017. "Chromium–tungsten–manganese oxides for synthesis of fatty acid methyl ester via esterification of palm fatty acid distillate," Energy, Elsevier, vol. 141(C), pages 1989-1997.
    4. Narowska, Beata & Kułażyński, Marek & Łukaszewicz, Marcin & Burchacka, Ewa, 2019. "Use of activated carbons as catalyst supports for biodiesel production," Renewable Energy, Elsevier, vol. 135(C), pages 176-185.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Han, Xiaoxiang & Jiang, Shengchou & Chen, Ziyi & Zeng, Zhiwei & Chen, Qing & Niu, Fuge & Pan, Weichun & Tang, Xiujuan & Liu, Shang-Bin, 2023. "Highly active sulfonic ionic liquid modified heteropoly acid composite catalysts for efficient production of ethyl palmitate," Renewable Energy, Elsevier, vol. 215(C).
    2. Sangsiri, Pimpajee & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2022. "Synthesis of sulfonated carbon-based catalysts from organosolv lignin and methanesulfonic acid: Its activity toward esterification of stearic acid," Renewable Energy, Elsevier, vol. 193(C), pages 113-127.
    3. Ibrahim, Shaimaa M., 2021. "Preparation, characterization and application of novel surface-modified ZrSnO4 as Sn-based TMOs catalysts for the stearic acid esterification with methanol to biodiesel," Renewable Energy, Elsevier, vol. 173(C), pages 151-163.
    4. Ning, Yilin & Niu, Shengli & Wang, Yongzheng & Zhao, Jianli & Lu, Chunmei, 2021. "Sono-modified halloysite nanotube with NaAlO2 as novel heterogeneous catalyst for biodiesel production: Optimization via GA_BP neural network," Renewable Energy, Elsevier, vol. 175(C), pages 391-404.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Haiping & Chen, Zhiqun & Chen, Wei & Chen, Yingquan & Wang, Xianhua & Chen, Hanping, 2020. "Role of porous structure and active O-containing groups of activated biochar catalyst during biomass catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    2. Liu, Ju-Zhao & Cui, Qi & Kang, Yu-Fei & Meng, Yao & Gao, Ming-Zhu & Efferth, Thomas & Fu, Yu-Jie, 2019. "Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel," Renewable Energy, Elsevier, vol. 133(C), pages 261-267.
    3. Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.
    4. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    5. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    6. Soltani, Soroush & Roodbar Shojaei, Taha & Khanian, Nasrin & Shean Yaw Choong, Thomas & Asim, Nilofar & Zhao, Yue, 2022. "Artificial neural network method modeling of microwave-assisted esterification of PFAD over mesoporous TiO2‒ZnO catalyst," Renewable Energy, Elsevier, vol. 187(C), pages 760-773.
    7. Wan, Zuraida & Lim, J.K. & Hameed, B.H., 2017. "Chromium–tungsten–manganese oxides for synthesis of fatty acid methyl ester via esterification of palm fatty acid distillate," Energy, Elsevier, vol. 141(C), pages 1989-1997.
    8. Zhang-Chun Tang & Yanjun Xia & Qi Xue & Jie Liu, 2018. "A Non-Probabilistic Solution for Uncertainty and Sensitivity Analysis on Techno-Economic Assessments of Biodiesel Production with Interval Uncertainties," Energies, MDPI, vol. 11(3), pages 1-17, March.
    9. Chen, Ying-Chen & Lin, Dai-Ying & Chen, Bing-Hung, 2019. "Metasilicate-based catalyst prepared from natural diatomaceous earth for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 1042-1050.
    10. Li, Hui & Liu, Fengsheng & Ma, Xiaoling & Cui, Ping & Guo, Min & Li, Yan & Gao, Yan & Zhou, Shoujun & Yu, Mingzhi, 2020. "An efficient basic heterogeneous catalyst synthesis of magnetic mesoporous Fe@C support SrO for transesterification," Renewable Energy, Elsevier, vol. 149(C), pages 816-827.
    11. R, Gopi & Thangarasu, Vinoth & Vinayakaselvi M, Angkayarkan & Ramanathan, Anand, 2022. "A critical review of recent advancements in continuous flow reactors and prominent integrated microreactors for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    12. Ali, Adnan Hayel & Wanderlind, Eduardo H. & Almerindo, Gizelle I., 2024. "Activated carbon obtained from malt bagasse as a support in heterogeneous catalysis for biodiesel production," Renewable Energy, Elsevier, vol. 220(C).
    13. Li, Mantian & Chen, Jinyi & Huang, Youjie & Li, Meichen & Lin, Xiaocheng & Qiu, Ting, 2020. "Reusable and efficient heterogeneous catalysts for biodiesel production from free fatty acids and oils: Self-solidifying hybrid ionic liquids," Energy, Elsevier, vol. 211(C).
    14. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    15. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    16. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    17. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.
    18. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.
    19. El yaakouby, Ichraq & Rhrissi, Ilyass & Abouliatim, Youness & Hlaibi, Miloudi & Kamil, Noureddine, 2023. "Moroccan sardine scales as a novel and renewable source of heterogeneous catalyst for biodiesel production using palm fatty acid distillate," Renewable Energy, Elsevier, vol. 217(C).
    20. Ashok, A. & Ratnaji, T. & John Kennedy, L. & Judith Vijaya, J. & Gnana Pragash, R., 2021. "Magnetically recoverable Mg substituted zinc ferrite nanocatalyst for biodiesel production: Process optimization, kinetic and thermodynamic analysis," Renewable Energy, Elsevier, vol. 163(C), pages 480-494.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:160:y:2020:i:c:p:42-51. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.