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High seebeck coefficient thermo-electrochemical cell using nickel hollow microspheres electrodes

Author

Listed:
  • Burmistrov, Igor
  • Gorshkov, Nikolay
  • Kovyneva, Natalya
  • Kolesnikov, Evgeny
  • Khaidarov, Bekzod
  • Karunakaran, Gopalu
  • Cho, Eun-Bum
  • Kiselev, Nikolay
  • Artyukhov, Denis
  • Kuznetsov, Denis
  • Gorokhovsky, Alexander

Abstract

High-performance harvesting of waste heat energy and its conversion into electric energy via thermo-electrochemical cells is an essential strategy of renewable energy development. Even though there is a large amount of scientific research available, but due to expensive electrode materials and low efficiency, the thermo-electrochemical cells have not found practical application. Here we demonstrated thermo-electrochemical cell with nickel (Ni) hollow microspheres-based electrodes, provided the highest hypothetical Seebeck coefficient of 4.5 mV/K (for aqueous electrolyte based thermocells) until today and open-circuit voltage values of up to 0.2 V. High values of Seebeck coefficient provide the ability to collect low-temperature heat, and high output potential differences which allow to fabricate batteries for commercial power circuits for various microelectronic devices. This work also proposed a mechanism and science behind the electrode processes, which explains a extremely high values of the hypothetical Seebeck coefficient. This is the first time to use Ni hollow microsphere in thermo-electrochemical cell for heat harvesting and thermal energy conversion into electricity. Because of the low cost of Ni microspheres electrode-based developed thermo cells could be commercially feasible for harvesting low-quality thermal energy.

Suggested Citation

  • Burmistrov, Igor & Gorshkov, Nikolay & Kovyneva, Natalya & Kolesnikov, Evgeny & Khaidarov, Bekzod & Karunakaran, Gopalu & Cho, Eun-Bum & Kiselev, Nikolay & Artyukhov, Denis & Kuznetsov, Denis & Gorokh, 2020. "High seebeck coefficient thermo-electrochemical cell using nickel hollow microspheres electrodes," Renewable Energy, Elsevier, vol. 157(C), pages 1-8.
    • Handle: RePEc:eee:renene:v:157:y:2020:i:c:p:1-8
    DOI: 10.1016/j.renene.2020.04.001
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    References listed on IDEAS

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    1. Hyeongwook Im & Taewoo Kim & Hyelynn Song & Jongho Choi & Jae Sung Park & Raquel Ovalle-Robles & Hee Doo Yang & Kenneth D. Kihm & Ray H. Baughman & Hong H. Lee & Tae June Kang & Yong Hyup Kim, 2016. "High-efficiency electrochemical thermal energy harvester using carbon nanotube aerogel sheet electrodes," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
    2. Jiangjiang Duan & Guang Feng & Boyang Yu & Jia Li & Ming Chen & Peihua Yang & Jiamao Feng & Kang Liu & Jun Zhou, 2018. "Aqueous thermogalvanic cells with a high Seebeck coefficient for low-grade heat harvest," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
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    1. Denis Artyukhov & Nikolay Kiselev & Nikolay Gorshkov & Natalya Kovyneva & Olga Ganzha & Maria Vikulova & Alexander Gorokhovsky & Peter Offor & Elena Boychenko & Igor Burmistrov, 2021. "Harvesting Waste Thermal Energy Using a Surface-Modified Carbon Fiber-Based Thermo-Electrochemical Cell," Sustainability, MDPI, vol. 13(3), pages 1-12, January.
    2. Demir, Hasan, 2024. "Simulation and forecasting of power by energy harvesting method in photovoltaic panels using artificial neural network," Renewable Energy, Elsevier, vol. 222(C).
    3. Denis Artyukhov & Nikolay Gorshkov & Maria Vikulova & Nikolay Kiselev & Artem Zemtsov & Ivan Artyukhov, 2022. "Power Supply of Wireless Sensors Based on Energy Conversion of Separated Gas Flows by Thermoelectrochemical Cells," Energies, MDPI, vol. 15(4), pages 1-16, February.
    4. Fatih Selimefendigil & Damla Okulu & Hakan F. Öztop, 2023. "Photovoltaic Thermal Management by Combined Utilization of Thermoelectric Generator and Power-Law-Nanofluid-Assisted Cooling Channel," Sustainability, MDPI, vol. 15(6), pages 1-29, March.
    5. Igor Burmistrov & Rita Khanna & Nikolay Gorshkov & Nikolay Kiselev & Denis Artyukhov & Elena Boychenko & Andrey Yudin & Yuri Konyukhov & Maksim Kravchenko & Alexander Gorokhovsky & Denis Kuznetsov, 2022. "Advances in Thermo-Electrochemical (TEC) Cell Performances for Harvesting Low-Grade Heat Energy: A Review," Sustainability, MDPI, vol. 14(15), pages 1-17, August.

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