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Harvesting Waste Thermal Energy Using a Surface-Modified Carbon Fiber-Based Thermo-Electrochemical Cell

Author

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  • Denis Artyukhov

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Nikolay Kiselev

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia
    Department of Functional Nanosystems and High-Temperature Materials, National University of Science and Technology «MISiS», 119049 Moscow, Russia
    Engineering Center, Plekhanov Russian University of Economics, 117997 Moscow, Russia)

  • Nikolay Gorshkov

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Natalya Kovyneva

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Olga Ganzha

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Maria Vikulova

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Alexander Gorokhovsky

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia)

  • Peter Offor

    (Metallurgical and Materials Engineering Department, University of Nigeria, Nsukka 410001, Nigeria
    Africa Centre of Excellence for Sustainable Power and Energy Development (ACE-SPED), University of Nigeria, Nsukka 410001, Nigeria)

  • Elena Boychenko

    (Department of Functional Nanosystems and High-Temperature Materials, National University of Science and Technology «MISiS», 119049 Moscow, Russia
    Engineering Center, Plekhanov Russian University of Economics, 117997 Moscow, Russia)

  • Igor Burmistrov

    (Department of Chemistry and Chemical Technology of Materials, Yuri Gagarin State Technical University of Saratov, 410054 Saratov, Russia
    Department of Functional Nanosystems and High-Temperature Materials, National University of Science and Technology «MISiS», 119049 Moscow, Russia
    Engineering Center, Plekhanov Russian University of Economics, 117997 Moscow, Russia)

Abstract

An important direction in the development of energy saving policy is harvesting and conversion into electricity of low-grade waste heat. The present paper is devoted to the improvement of the efficiency of thermo-electrochemical cells based on carbon fiber electrodes and potassium ferri-/ferrocyanide redox electrolyte. The influence of the carbon fiber electrode surface modification (magnetron deposition of silver and titanium or infiltration implantation of nanoscale titanium oxide) on the output power and parameters of the impedance equivalent scheme of a thermo-electrochemical cell has been studied. Two kinds of cell designs (a conventional electrochemical cell with a salt bridge and a coin cell-type body) were investigated. It was found that the nature of the surface modification of electrodes can change the internal resistance of the cell by three orders of magnitude. The dependence of the equivalent scheme parameters and output power density of the thermoelectric cell on the type of electrode materials was presented. It was observed that the maximum power for carbon fiber modified with titanium metal and titanium oxide was 25.2 mW/m 2 and the efficiency was 1.37%.

Suggested Citation

  • Denis Artyukhov & Nikolay Kiselev & Nikolay Gorshkov & Natalya Kovyneva & Olga Ganzha & Maria Vikulova & Alexander Gorokhovsky & Peter Offor & Elena Boychenko & Igor Burmistrov, 2021. "Harvesting Waste Thermal Energy Using a Surface-Modified Carbon Fiber-Based Thermo-Electrochemical Cell," Sustainability, MDPI, vol. 13(3), pages 1-12, January.
    • Handle: RePEc:gam:jsusta:v:13:y:2021:i:3:p:1377-:d:488849
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    References listed on IDEAS

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    1. Burmistrov, Igor & Gorshkov, Nikolay & Kovyneva, Natalya & Kolesnikov, Evgeny & Khaidarov, Bekzod & Karunakaran, Gopalu & Cho, Eun-Bum & Kiselev, Nikolay & Artyukhov, Denis & Kuznetsov, Denis & Gorokh, 2020. "High seebeck coefficient thermo-electrochemical cell using nickel hollow microspheres electrodes," Renewable Energy, Elsevier, vol. 157(C), pages 1-8.
    2. Jiangjiang Duan & Guang Feng & Boyang Yu & Jia Li & Ming Chen & Peihua Yang & Jiamao Feng & Kang Liu & Jun Zhou, 2018. "Aqueous thermogalvanic cells with a high Seebeck coefficient for low-grade heat harvest," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
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    Cited by:

    1. Denis Artyukhov & Nikolay Gorshkov & Maria Vikulova & Nikolay Kiselev & Artem Zemtsov & Ivan Artyukhov, 2022. "Power Supply of Wireless Sensors Based on Energy Conversion of Separated Gas Flows by Thermoelectrochemical Cells," Energies, MDPI, vol. 15(4), pages 1-16, February.
    2. Igor Burmistrov & Rita Khanna & Nikolay Gorshkov & Nikolay Kiselev & Denis Artyukhov & Elena Boychenko & Andrey Yudin & Yuri Konyukhov & Maksim Kravchenko & Alexander Gorokhovsky & Denis Kuznetsov, 2022. "Advances in Thermo-Electrochemical (TEC) Cell Performances for Harvesting Low-Grade Heat Energy: A Review," Sustainability, MDPI, vol. 14(15), pages 1-17, August.

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