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Evidence for cross-polymerization between the biomass-derived furans and phenolics

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  • Sun, Kai
  • Zhang, Lijun
  • Xu, Qing
  • Zhang, Zhanming
  • Shao, Yuewen
  • Dong, Dehua
  • Gao, Guanggang
  • Liu, Qing
  • Wang, Shuang
  • Hu, Xun

Abstract

The high tendency of bio-oil towards polymerization is one of the key challenges in hydrotreatment of bio-oil for production of bio-fuels. However, such properties of bio-oil could be used to produce carbon materials, but the mechanism for the polymerization has not been clarified. Bio-oil contains sugars, derivatives of sugars (i.e. furans et al.), phenolic monomers and oligomers. Among of them, the furans and phenolics are the typical compounds in bio-oil. In this study, the potential cross-polymerization between the furans (furan, furfural and furfuryl alcohol (FA)) and the phenolics (vanillin and guaiacol) in bio-oil was explored in water with/without H2SO4. The furans could polymerize via ring-opening to produce reactive reaction intermediates. Furfural and FA contained branched functionalities in furan ring, which was more reactive towards polymerization, especially for furfuryl alcohol. In general, the furans were more reactive towards polymerization than vanillin and guaiacol. Nevertheless, the cross-polymerization between the furans and phenolics occurred and significantly enhanced its tendency towards polymerization. The reaction intermediates formed via opening of the furan ring were the key initiator for the cross-polymerizations. Additionally, the presence of H2SO4 could enhance consumption of the CO during the polymerization and the thermal stability of the resulting polymer.

Suggested Citation

  • Sun, Kai & Zhang, Lijun & Xu, Qing & Zhang, Zhanming & Shao, Yuewen & Dong, Dehua & Gao, Guanggang & Liu, Qing & Wang, Shuang & Hu, Xun, 2020. "Evidence for cross-polymerization between the biomass-derived furans and phenolics," Renewable Energy, Elsevier, vol. 154(C), pages 517-531.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:517-531
    DOI: 10.1016/j.renene.2020.03.030
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    References listed on IDEAS

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    1. Hu, Xun & Lievens, Caroline & Mourant, Daniel & Wang, Yi & Wu, Liping & Gunawan, Richard & Song, Yao & Li, Chun-Zhu, 2013. "Investigation of deactivation mechanisms of a solid acid catalyst during esterification of the bio-oils from mallee biomass," Applied Energy, Elsevier, vol. 111(C), pages 94-103.
    2. Akhtar, Javaid & Amin, Nor Aishah Saidina, 2011. "A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1615-1624, April.
    3. Feng, Dongdong & Zhang, Yu & Zhao, Yijun & Sun, Shaozeng, 2018. "Catalytic effects of ion-exchangeable K+ and Ca2+ on rice husk pyrolysis behavior and its gas–liquid–solid product properties," Energy, Elsevier, vol. 152(C), pages 166-177.
    4. Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
    5. Lin, Bo-Jhih & Chen, Wei-Hsin & Hsieh, Tzu-Hsien & Ong, Hwai Chyuan & Show, Pau Loke & Naqvi, Salman Raza, 2019. "Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels," Renewable Energy, Elsevier, vol. 136(C), pages 223-234.
    6. Ansari, Khursheed B. & Gaikar, Vilas G., 2019. "Investigating production of hydrocarbon rich bio-oil from grassy biomass using vacuum pyrolysis coupled with online deoxygenation of volatile products over metallic iron," Renewable Energy, Elsevier, vol. 130(C), pages 305-318.
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