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Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Author

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  • Lin, Bo-Jhih
  • Chen, Wei-Hsin
  • Hsieh, Tzu-Hsien
  • Ong, Hwai Chyuan
  • Show, Pau Loke
  • Naqvi, Salman Raza

Abstract

Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

Suggested Citation

  • Lin, Bo-Jhih & Chen, Wei-Hsin & Hsieh, Tzu-Hsien & Ong, Hwai Chyuan & Show, Pau Loke & Naqvi, Salman Raza, 2019. "Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels," Renewable Energy, Elsevier, vol. 136(C), pages 223-234.
    • Handle: RePEc:eee:renene:v:136:y:2019:i:c:p:223-234
    DOI: 10.1016/j.renene.2018.12.111
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