IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v153y2020icp1320-1329.html
   My bibliography  Save this article

Modification and synthesis of low pour point plant-based lubricants with ionic liquid catalysis

Author

Listed:
  • Zhang, Wei
  • Wu, Jinquan
  • Yu, Senshen
  • Shen, Ying
  • Wu, Yamin
  • Chen, Biqiang
  • Nie, Kaili
  • Zhang, Xu

Abstract

Due to the poor biodegradability and toxicity of mineral-based lubricants, the development and application of plant-based biolubricants are increasing. However, low stability and poor low temperature performance restrict plant oils to use as lubricants directly. Hence, the paper tried to find an efficient and green way to modify the plant oil derivate oleic acid and obtained high-performance biolubricants. This study demonstrated that modification of oleic acid through epoxidation combined with ring opening reaction, and further esterification, was an efficient strategy for modifying unsaturated fatty acids for the biolubricant production. Meanwhile, catalytic effects of ionic liquids were compared with other catalysts. The results indicated that ionic liquid [HMIm][PF6] is an efficient catalyst for the ring opening and esterification for the synthesis of biolubricants with different kinds of fatty acids. Modified biolubricants from this research exhibited excellent viscosity index (>116) and low temperature performance (pour point < −48 °C). The results of high frequency reciprocating friction experiments exhibited superior lubrication performance of the lubricant. These findings provide a new green and efficient method for improving plant oils as biolubricants.

Suggested Citation

  • Zhang, Wei & Wu, Jinquan & Yu, Senshen & Shen, Ying & Wu, Yamin & Chen, Biqiang & Nie, Kaili & Zhang, Xu, 2020. "Modification and synthesis of low pour point plant-based lubricants with ionic liquid catalysis," Renewable Energy, Elsevier, vol. 153(C), pages 1320-1329.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1320-1329
    DOI: 10.1016/j.renene.2020.02.067
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120302585
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.02.067?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    2. Chan, Chung-Hung & Tang, Sook Wah & Mohd, Noor Khairin & Lim, Wen Huei & Yeong, Shoot Kian & Idris, Zainab, 2018. "Tribological behavior of biolubricant base stocks and additives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 145-157.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xie, Min & Xu, Daqian & Shen, Juanjuan & Zhang, Chunyun, 2024. "Achieving the good thermal-stability and lubricity via a dihydroxy biolubricant from the agro-waste of Codonopsis pilosula," Renewable Energy, Elsevier, vol. 221(C).
    2. Hájek, Martin & Kocián, David & Douda, Miroslav, 2023. "Statistical evaluation of the epoxidation of esters from vegetable oils and optimization of reaction conditions," Renewable Energy, Elsevier, vol. 213(C), pages 157-164.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gurunathan Manikandan & P. Rajesh Kanna & Dawid Taler & Tomasz Sobota, 2023. "Review of Waste Cooking Oil (WCO) as a Feedstock for Biofuel—Indian Perspective," Energies, MDPI, vol. 16(4), pages 1-17, February.
    2. Đặng, Tấn-Hiệp & Nguyễn, Xuân-Hoàn & Chou, Chi-Lin & Chen, Bing-Hung, 2021. "Preparation of cancrinite-type zeolite from diatomaceous earth as transesterification catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 347-358.
    3. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    4. Rahmath Abdulla & Eryati Derman & Thivyasri K.Mathialagan & Abu Zahrim Yaser & Mohd Armi Abu Samah & Jualang Azlan Gansau & Syed Umar Faruq Syed Najmuddin, 2022. "Biodiesel Production from Waste Palm Cooking Oil Using Immobilized Candida rugosa Lipase," Sustainability, MDPI, vol. 14(20), pages 1-18, October.
    5. Chen, Ying-Chen & Lin, Dai-Ying & Chen, Bing-Hung, 2019. "Metasilicate-based catalyst prepared from natural diatomaceous earth for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 1042-1050.
    6. Sergio Nogales-Delgado & José María Encinar & Juan Félix González, 2019. "Safflower Biodiesel: Improvement of its Oxidative Stability by Using BHA and TBHQ," Energies, MDPI, vol. 12(10), pages 1-13, May.
    7. Hamnas, Amina & Unnikrishnan, G., 2023. "Bio-lubricants from vegetable oils: Characterization, modifications, applications and challenges – Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    8. Teo, Siow Hwa & Islam, Aminul & Mansir, Nasar & Shamsuddin, Mohd Razali & Joseph, Collin G. & Goto, Motonobu & Taufiq-Yap, Yun Hin, 2022. "Sustainable biofuel production approach: Critical methanol green transesterification by efficient and stable heterogeneous catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    9. Radosław Ciesielski & Mateusz Zakrzewski & Oleksandr Shtyka & Tomasz Maniecki & Adam Rylski & Marek Wozniak & Przemyslaw Kubiak & Krzysztof Siczek, 2022. "The Research on Characteristics of CI Engine Supplied with Biodiesels from Brown and Yellow Grease," Energies, MDPI, vol. 15(11), pages 1-17, June.
    10. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.
    11. Haris Mahmood Khan & Tanveer Iqbal & Saima Yasin & Muhammad Irfan & Muhammad Mujtaba Abbas & Ibham Veza & Manzoore Elahi M. Soudagar & Anas Abdelrahman & Md. Abul Kalam, 2022. "Heterogeneous Catalyzed Biodiesel Production Using Cosolvent: A Mini Review," Sustainability, MDPI, vol. 14(9), pages 1-11, April.
    12. Bahadi, Murad & Salimon, Jumat & Derawi, Darfizzi, 2021. "Synthesis of di-trimethylolpropane tetraester-based biolubricant from Elaeis guineensis kernel oil via homogeneous acid-catalyzed transesterification," Renewable Energy, Elsevier, vol. 171(C), pages 981-993.
    13. Mia Gotovuša & Ivan Pucko & Marko Racar & Fabio Faraguna, 2022. "Biodiesel Produced from Propanol and Longer Chain Alcohols—Synthesis and Properties," Energies, MDPI, vol. 15(14), pages 1-21, July.
    14. Le-Phuc, Nguyen & Tran, Tri V. & Phan, Thien T. & Ngo, Phuong T. & Ha, Quan L.M. & Luong, Thuy N. & Tran, Thinh H. & Phan, Tuan T., 2021. "High-efficient production of biofuels using spent fluid catalytic cracking (FCC) catalysts and high acid value waste cooking oils," Renewable Energy, Elsevier, vol. 168(C), pages 57-63.
    15. Hosseinzadeh-Bandbafha, Homa & Nizami, Abdul-Sattar & Kalogirou, Soteris A. & Gupta, Vijai Kumar & Park, Young-Kwon & Fallahi, Alireza & Sulaiman, Alawi & Ranjbari, Meisam & Rahnama, Hassan & Aghbashl, 2022. "Environmental life cycle assessment of biodiesel production from waste cooking oil: A systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    16. Luqman Razzaq & Muhammad Farooq & M. A. Mujtaba & Farooq Sher & Muhammad Farhan & Muhammad Tahir Hassan & Manzoore Elahi M. Soudagar & A. E. Atabani & M. A. Kalam & Muhammad Imran, 2020. "Modeling Viscosity and Density of Ethanol-Diesel-Biodiesel Ternary Blends for Sustainable Environment," Sustainability, MDPI, vol. 12(12), pages 1-20, June.
    17. Omojola Awogbemi & Daramy Vandi Von Kallon & Emmanuel Idoko Onuh & Victor Sunday Aigbodion, 2021. "An Overview of the Classification, Production and Utilization of Biofuels for Internal Combustion Engine Applications," Energies, MDPI, vol. 14(18), pages 1-43, September.
    18. Rasep, Z. & Muhammad Yazid, M.N.A.W. & Samion, S., 2021. "Lubrication of textured journal bearing by using vegetable oil: A review of approaches, challenges, and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    19. Ho, Calvin K. & McAuley, Kimberley B. & Peppley, Brant A., 2019. "Biolubricants through renewable hydrocarbons: A perspective for new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    20. Petchsoongsakul, Nattawat & Ngaosuwan, Kanokwan & Kiatkittipong, Worapon & Wongsawaeng, Doonyapong & Assabumrungrat, Suttichai, 2020. "Different water removal methods for facilitating biodiesel production from low-cost waste cooking oil containing high water content in hybridized reactive distillation," Renewable Energy, Elsevier, vol. 162(C), pages 1906-1918.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1320-1329. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.