IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v153y2020icp1-11.html
   My bibliography  Save this article

Biodiesel production from refined used cooking oil using co-metal oxide catalyzed transesterification

Author

Listed:
  • Sulaiman, Nur Fatin
  • Hashim, Ainul Nadia Nor
  • Toemen, Susilawati
  • Rosid, Salmiah Jamal Mat
  • Mokhtar, Wan Nur Aini Wan
  • Nadarajan, Renugambaal
  • Bakar, Wan Azelee Wan Abu

Abstract

The world is challenged with depletion of non-renewable fossil fuel and environmental pollution. Thus, this research was emphasized on converting refined used cooking oil to safer and low toxicity biodiesel by base-catalyzed transesterification reaction. Alumina supported magnesium, calcium, strontium and barium oxide-based catalysts with iron as its dopant were optimized according to various calcination temperatures and iron loadings. The optimum conditions over potential catalyst was achieved with 20 wt% of Fe loading for Fe/Ba/Al2O3 catalyst calcined at 800 °C which gave the maximum biodiesel production of 84.02%. Characterization of catalyst carried out by XRD showed that the 20Fe:80Ba/Al2O3 catalyst calcined at 800 °C had a polycrystalline structure with high BET surface area (133.59 m2/g) while FESEM analysis displayed a morphology of uniform plate-like shape grains with fine particles in the range of 55–60 nm. CO2-TPD results showed that the catalyst exhibited highest basicity of 2.5854 mmol/g, while TGA analysis proved that 800 °C was the optimum calcination temperature. The transesterification process of refined used cooking oil to produce high yield biodiesel was effectively attained using 20Fe:80Ba/Al2O3 catalyst.

Suggested Citation

  • Sulaiman, Nur Fatin & Hashim, Ainul Nadia Nor & Toemen, Susilawati & Rosid, Salmiah Jamal Mat & Mokhtar, Wan Nur Aini Wan & Nadarajan, Renugambaal & Bakar, Wan Azelee Wan Abu, 2020. "Biodiesel production from refined used cooking oil using co-metal oxide catalyzed transesterification," Renewable Energy, Elsevier, vol. 153(C), pages 1-11.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1-11
    DOI: 10.1016/j.renene.2020.01.158
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120301804
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.01.158?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.
    2. Baskar, G. & Soumiya, S., 2016. "Production of biodiesel from castor oil using iron (II) doped zinc oxide nanocatalyst," Renewable Energy, Elsevier, vol. 98(C), pages 101-107.
    3. Marinković, Dalibor M. & Stanković, Miroslav V. & Veličković, Ana V. & Avramović, Jelena M. & Miladinović, Marija R. & Stamenković, Olivera O. & Veljković, Vlada B. & Jovanović, Dušan M., 2016. "Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1387-1408.
    4. Melero, Juan A. & Bautista, L. Fernando & Morales, Gabriel & Iglesias, Jose & Sánchez-Vázquez, Rebeca, 2015. "Acid-catalyzed production of biodiesel over arenesulfonic SBA-15: Insights into the role of water in the reaction network," Renewable Energy, Elsevier, vol. 75(C), pages 425-432.
    5. Sulaiman, Nur Fatin & Wan Abu Bakar, Wan Azelee & Ali, Rusmidah, 2017. "Response surface methodology for the optimum production of biodiesel over Cr/Ca/γ-Al2O3 catalyst: Catalytic performance and physicochemical studies," Renewable Energy, Elsevier, vol. 113(C), pages 697-705.
    6. Sulaiman, Nur Fatin & Wan Abu Bakar, Wan Azelee & Toemen, Susilawati & Kamal, Norhasyimah Mohd & Nadarajan, Renugambaal, 2019. "In depth investigation of bi-functional, Cu/Zn/γ-Al2O3 catalyst in biodiesel production from low-grade cooking oil: Optimization using response surface methodology," Renewable Energy, Elsevier, vol. 135(C), pages 408-416.
    7. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chanthon, Narita & Munbupphachart, Nattawadee & Ngaosuwan, Kanokwan & Kiatkittipong, Worapon & Wongsawaeng, Doonyapong & Mens, Weerinda & Rokhum, Samuel Lalthazuala & Assabumrungrat, Suttichai, 2023. "Metal loading on CaO/Al2O3 pellet catalyst as a booster for transesterification in biodiesel production," Renewable Energy, Elsevier, vol. 218(C).
    2. Ezzati, Rohollah & Ranjbar, Shahram & Soltanabadi, Azim, 2021. "Kinetics models of transesterification reaction for biodiesel production: A theoretical analysis," Renewable Energy, Elsevier, vol. 168(C), pages 280-296.
    3. Abdullah, Rose Fadzilah & Rashid, Umer & Ibrahim, Mohd Lokman & Hazmi, Balkis & Alharthi, Fahad A. & Nehdi, Imededdine Arbi, 2021. "Bifunctional nano-catalyst produced from palm kernel shell via hydrothermal-assisted carbonization for biodiesel production from waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    4. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    5. Cai, Dongren & Zhan, Guowu & Xiao, Jingran & Zhou, Shu-Feng & Qiu, Ting, 2021. "Design and synthesis of novel amphipathic ionic liquids for biodiesel production from soapberry oil," Renewable Energy, Elsevier, vol. 168(C), pages 779-790.
    6. Lani, Nurul Saadiah & Ngadi, Norzita & Haron, Saharudin & Mohammed Inuwa, Ibrahim & Anako Opotu, Lawal, 2024. "The catalytic effect of calcium oxide and magnetite loading on magnetically supported calcium oxide-zeolite catalyst for biodiesel production from used cooking oil," Renewable Energy, Elsevier, vol. 222(C).
    7. Sulaiman, Nur Fatin & Lee, Siew Ling & Toemen, Susilawati & Bakar, Wan Azelee Wan Abu, 2020. "Physicochemical characteristics of Cu/Zn/γ-Al2O3 catalyst and its mechanistic study in transesterification for biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 142-157.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sulaiman, Nur Fatin & Lee, Siew Ling & Toemen, Susilawati & Bakar, Wan Azelee Wan Abu, 2020. "Physicochemical characteristics of Cu/Zn/γ-Al2O3 catalyst and its mechanistic study in transesterification for biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 142-157.
    2. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    3. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    4. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.
    5. Shemelis N. Gebremariam & Trine Hvoslef-Eide & Meseret T. Terfa & Jorge M. Marchetti, 2019. "Techno-Economic Performance of Different Technological Based Bio-Refineries for Biofuel Production," Energies, MDPI, vol. 12(20), pages 1-21, October.
    6. Qu, Tongxin & Niu, Shengli & Gong, Zhiqiang & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2020. "Wollastonite decorated with calcium oxide as heterogeneous transesterification catalyst for biodiesel production: Optimized by response surface methodology," Renewable Energy, Elsevier, vol. 159(C), pages 873-884.
    7. Sulaiman, Nur Fatin & Wan Abu Bakar, Wan Azelee & Toemen, Susilawati & Kamal, Norhasyimah Mohd & Nadarajan, Renugambaal, 2019. "In depth investigation of bi-functional, Cu/Zn/γ-Al2O3 catalyst in biodiesel production from low-grade cooking oil: Optimization using response surface methodology," Renewable Energy, Elsevier, vol. 135(C), pages 408-416.
    8. Suryajaya, Stefanus Kevin & Mulyono, Yohanes Ricky & Santoso, Shella Permatasari & Yuliana, Maria & Kurniawan, Alfin & Ayucitra, Aning & Sun, Yueting & Hartono, Sandy Budi & Soetaredjo, Felycia Edi & , 2021. "Iron (II) impregnated double-shelled hollow mesoporous silica as acid-base bifunctional catalyst for the conversion of low-quality oil to methyl esters," Renewable Energy, Elsevier, vol. 169(C), pages 1166-1174.
    9. Liu, Xiaoyan & Zhu, Fenfen & Zhang, Rongyan & Zhao, Luyao & Qi, Juanjuan, 2021. "Recent progress on biodiesel production from municipal sewage sludge," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    10. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    11. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    12. Harsha Hebbar, H.R. & Math, M.C. & Yatish, K.V., 2018. "Optimization and kinetic study of CaO nano-particles catalyzed biodiesel production from Bombax ceiba oil," Energy, Elsevier, vol. 143(C), pages 25-34.
    13. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    14. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    15. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    16. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Nizami, Abdul-Sattar & Sultana, Shazia & Zafar, Muhammad & Rehan, Mohammad & Srinivasan, Gokul Raghavendra & Ali, Arshid Mahmood & Al, 2021. "Biodiesel production from novel non-edible caper (Capparis spinosa L.) seeds oil employing Cu–Ni doped ZrO2 catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    17. Liu, Kang & Wang, Rui & Yu, Meiqing, 2018. "An efficient, recoverable solid base catalyst of magnetic bamboo charcoal: Preparation, characterization, and performance in biodiesel production," Renewable Energy, Elsevier, vol. 127(C), pages 531-538.
    18. Shu, Qing & Tang, Guoqiang & Lesmana, Herry & Zou, Laixi & Xiong, Daolin, 2018. "Preparation, characterization and application of a novel solid Brönsted acid catalyst SO42−/La3+/C for biodiesel production via esterification of oleic acid and methanol," Renewable Energy, Elsevier, vol. 119(C), pages 253-261.
    19. Adepoju, T.F. & Ibeh, M.A. & Udoetuk, E.N. & Babatunde, E.O., 2021. "Quaternary blend of Carica papaya - Citrus sinesis - Hibiscus sabdariffa - Waste used oil for biodiesel synthesis using CaO-based catalyst derived from binary mix of Lattorina littorea and Mactra cora," Renewable Energy, Elsevier, vol. 171(C), pages 22-33.
    20. Khan, Ihtisham Wali & Naeem, Abdul & Farooq, Muhammad & Mahmood, Tahira & Ahmad, Bashir & Hamayun, Muhammad & Ahmad, Zahoor & Saeed, Tooba, 2020. "Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay," Renewable Energy, Elsevier, vol. 155(C), pages 181-188.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1-11. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.