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Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature

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  • Trubetskaya, Anna
  • Souihi, Nabil
  • Umeki, Kentaro

Abstract

This study presents how the yields of different tar compounds from pure lignocellulosic compounds respond to the change in temperature and residence time. Experiments were carried out with a drop tube furnace in the temperature range from 800 to 1250 °C. The tar composition was characterized by gas chromatography with a flame ionization detector and mass spectrometry using a dual detector system. Longer residence time and higher heat treatment temperatures increased the soot formation and decreased the tar yields. Soot yields from lignin samples were greater than soot yields from holocellulose pyrolysis. The dominating products in tars from pyrolysis of all lignocellulosic compounds were benzene and toluene. Cellulose and hemicellulose pyrolysis produced greater amount of oxygenates in tars, whereas lignin tar was rich in phenols, polycyclic hydrocarbons and naphthalenes. Simultaneous reduction of tar and soot was achieved by impregnation of lignin from wheat straw with alkali metals. The OPLS-DA model can accurately explain the differences in tar composition based on the experimental mass spectrometry data.

Suggested Citation

  • Trubetskaya, Anna & Souihi, Nabil & Umeki, Kentaro, 2019. "Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature," Renewable Energy, Elsevier, vol. 141(C), pages 751-759.
    • Handle: RePEc:eee:renene:v:141:y:2019:i:c:p:751-759
    DOI: 10.1016/j.renene.2019.04.033
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    References listed on IDEAS

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    1. Umeki, Kentaro & Yamamoto, Kouichi & Namioka, Tomoaki & Yoshikawa, Kunio, 2010. "High temperature steam-only gasification of woody biomass," Applied Energy, Elsevier, vol. 87(3), pages 791-798, March.
    2. Trubetskaya, Anna & Jensen, Peter Arendt & Jensen, Anker Degn & Garcia Llamas, Angel David & Umeki, Kentaro & Gardini, Diego & Kling, Jens & Bates, Richard B. & Glarborg, Peter, 2016. "Effects of several types of biomass fuels on the yield, nanostructure and reactivity of soot from fast pyrolysis at high temperatures," Applied Energy, Elsevier, vol. 171(C), pages 468-482.
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    1. Čespiva, Jakub & Wnukowski, Mateusz & Niedzwiecki, Lukasz & Skřínský, Jan & Vereš, Ján & Ochodek, Tadeáš & Pawlak-Kruczek, Halina & Borovec, Karel, 2020. "Characterization of tars from a novel, pilot scale, biomass gasifier working under low equivalence ratio regime," Renewable Energy, Elsevier, vol. 159(C), pages 775-785.
    2. Erić, Aleksandar & Cvetinović, Dejan & Milutinović, Nada & Škobalj, Predrag & Bakić, Vukman, 2022. "Combined parametric modelling of biomass devolatilisation process," Renewable Energy, Elsevier, vol. 193(C), pages 13-22.
    3. Chen, Tao & Sjöblom, Jonas & Ström, Henrik, 2022. "Numerical investigations of soot generation during wood-log combustion," Applied Energy, Elsevier, vol. 325(C).
    4. Kumar, Avnish & Biswas, Bijoy & Saini, Komal & Kumar, Adarsh & Kumar, Jitendra & Krishna, Bhavya B. & Bhaskar, Thallada, 2021. "Py-GC/MS study of prot lignin with cobalt impregnated titania, ceria and zirconia catalysts," Renewable Energy, Elsevier, vol. 172(C), pages 121-129.
    5. Trubetskaya, Anna & Timko, Michael T & Umeki, Kentaro, 2020. "Prediction of fast pyrolysis products yields using lignocellulosic compounds and ash contents," Applied Energy, Elsevier, vol. 257(C).
    6. Surup, Gerrit Ralf & Hunt, Andrew J. & Attard, Thomas & Budarin, Vitaliy L. & Forsberg, Fredrik & Arshadi, Mehrdad & Abdelsayed, Victor & Shekhawat, Dushyant & Trubetskaya, Anna, 2020. "The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    7. Shen, Yafei & Zhou, Yuewei & Fu, Yuhong & Zhang, Niyu, 2020. "Activated carbons synthesized from unaltered and pelletized biomass wastes for bio-tar adsorption in different phases," Renewable Energy, Elsevier, vol. 146(C), pages 1700-1709.

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