IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v193y2020ics0360544219323916.html
   My bibliography  Save this article

The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries

Author

Listed:
  • Surup, Gerrit Ralf
  • Hunt, Andrew J.
  • Attard, Thomas
  • Budarin, Vitaliy L.
  • Forsberg, Fredrik
  • Arshadi, Mehrdad
  • Abdelsayed, Victor
  • Shekhawat, Dushyant
  • Trubetskaya, Anna

Abstract

This work demonstrates that the integration of supercritical carbon dioxide extraction with slow pyrolysis is an effective method for the production of value-added chemicals and charcoal that is an attractive alternative to coke for industry. Integration of technologies is key for the development of holistic biorefineries that exploit all parts of the biomass feedstock and generate little or ideally no waste. In fact, the use of waste or low valued wood fractions is attractive due to their plentiful abundance and lack of exploitation. Supercritical carbon dioxide has been demonstrated to be effective at the removal of over half of extractives from low quality wood and forestry wastes, which can account for up to 11 wt %, of the dried biomass in waste needles. High extractive yields by supercritical carbon dioxide extraction illustrates the potential of utilizing low quality wood as an alternative feedstock for the sustainable production of value-added chemicals. High yields of steroids and derivatives, terpenes and other plant metabolites were obtained in the extracts of needles, branches and bark. Importantly, supercritical carbon dioxide extraction had little impact neither on the physical properties of original wood nor on the yield of solid charcoal. This indicates that extraction by supercritical carbon dioxide can be used as a method for adding further value to the process by removal of bio-based chemicals, whilst still maintaining the yield of the solid fuel product. Moreover, the heat treatment temperature and supercritical carbon dioxide extraction had a significant impact on the tar yields during pyrolysis, leading to an increase in naphthalene, polycyclic aromatic hydrocarbons, aromatic and phenolic fractions with greater temperature. These results are promising as they show that the charcoal obtained from this renewable feedstock could be used as an alternative to fossil-based coke in applications including ferroalloy industries.

Suggested Citation

  • Surup, Gerrit Ralf & Hunt, Andrew J. & Attard, Thomas & Budarin, Vitaliy L. & Forsberg, Fredrik & Arshadi, Mehrdad & Abdelsayed, Victor & Shekhawat, Dushyant & Trubetskaya, Anna, 2020. "The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    • Handle: RePEc:eee:energy:v:193:y:2020:i:c:s0360544219323916
    DOI: 10.1016/j.energy.2019.116696
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219323916
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.116696?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Riva, Lorenzo & Surup, Gerrit Ralf & Buø, Therese Videm & Nielsen, Henrik Kofoed, 2019. "A study of densified biochar as carbon source in the silicon and ferrosilicon production," Energy, Elsevier, vol. 181(C), pages 985-996.
    2. Riva, Lorenzo & Nielsen, Henrik Kofoed & Skreiberg, Øyvind & Wang, Liang & Bartocci, Pietro & Barbanera, Marco & Bidini, Gianni & Fantozzi, Francesco, 2019. "Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke," Applied Energy, Elsevier, vol. 256(C).
    3. Trubetskaya, Anna & Souihi, Nabil & Umeki, Kentaro, 2019. "Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature," Renewable Energy, Elsevier, vol. 141(C), pages 751-759.
    4. Surup, Gerrit & Vehus, Tore & Eidem, Per-Anders & Trubetskaya, Anna & Nielsen, Henrik Kofoed, 2019. "Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 167(C), pages 337-345.
    5. Candice Ellison & Murat Sean McKeown & Samir Trabelsi & Dorin Boldor, 2017. "Dielectric Properties of Biomass/Biochar Mixtures at Microwave Frequencies," Energies, MDPI, vol. 10(4), pages 1-11, April.
    6. Ruiz, Héctor A. & Rodríguez-Jasso, Rosa M. & Fernandes, Bruno D. & Vicente, António A. & Teixeira, José A., 2013. "Hydrothermal processing, as an alternative for upgrading agriculture residues and marine biomass according to the biorefinery concept: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 35-51.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
    2. Surup, Gerrit Ralf & Nielsen, Henrik Kofoed & Großarth, Marius & Deike, Rüdiger & Van den Bulcke, Jan & Kibleur, Pierre & Müller, Michael & Ziegner, Mirko & Yazhenskikh, Elena & Beloshapkin, Sergey & , 2020. "Effect of operating conditions and feedstock composition on the properties of manganese oxide or quartz charcoal pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 193(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Surup, Gerrit Ralf & Nielsen, Henrik Kofoed & Großarth, Marius & Deike, Rüdiger & Van den Bulcke, Jan & Kibleur, Pierre & Müller, Michael & Ziegner, Mirko & Yazhenskikh, Elena & Beloshapkin, Sergey & , 2020. "Effect of operating conditions and feedstock composition on the properties of manganese oxide or quartz charcoal pellets for the use in ferroalloy industries," Energy, Elsevier, vol. 193(C).
    2. Gerrit Ralf Surup & Hamideh Kaffash & Yan Ma & Anna Trubetskaya & Johan Berg Pettersen & Merete Tangstad, 2022. "Life Cycle Based Climate Emissions of Charcoal Conditioning Routes for the Use in the Ferro-Alloy Production," Energies, MDPI, vol. 15(11), pages 1-28, May.
    3. Yu-Chiao Lu & Liviu Brabie & Andrey V. Karasev & Chuan Wang, 2022. "Applications of Hydrochar and Charcoal in the Iron and Steelmaking Industry—Part 2: Carburization of Liquid Iron by Addition of Iron–Carbon Briquettes," Sustainability, MDPI, vol. 14(9), pages 1-20, April.
    4. Surup, Gerrit Ralf & Leahy, James J. & Timko, Michael T. & Trubetskaya, Anna, 2020. "Hydrothermal carbonization of olive wastes to produce renewable, binder-free pellets for use as metallurgical reducing agents," Renewable Energy, Elsevier, vol. 155(C), pages 347-357.
    5. Riva, Lorenzo & Nielsen, Henrik Kofoed & Skreiberg, Øyvind & Wang, Liang & Bartocci, Pietro & Barbanera, Marco & Bidini, Gianni & Fantozzi, Francesco, 2019. "Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke," Applied Energy, Elsevier, vol. 256(C).
    6. Gul, Eid & Riva, Lorenzo & Nielsen, Henrik Kofoed & Yang, Haiping & Zhou, Hewen & Yang, Qing & Skreiberg, Øyvind & Wang, Liang & Barbanera, Marco & Zampilli, Mauro & Bartocci, Pietro & Fantozzi, Franc, 2021. "Substitution of coke with pelletized biocarbon in the European and Chinese steel industries: An LCA analysis," Applied Energy, Elsevier, vol. 304(C).
    7. Ras Izzati Ismail & Chu Yee Khor & Alina Rahayu Mohamed, 2023. "Pelletization Temperature and Pressure Effects on the Mechanical Properties of Khaya senegalensis Biomass Energy Pellets," Sustainability, MDPI, vol. 15(9), pages 1-12, May.
    8. Dan Liu & Da Teng & Yan Zhu & Xingde Wang & Hanyang Wang, 2023. "Optimization of Process Parameters for Pellet Production from Corn Stalk Rinds Using Box–Behnken Design," Energies, MDPI, vol. 16(12), pages 1-20, June.
    9. Hamid Gilvari & Wiebren De Jong & Dingena L. Schott, 2020. "The Effect of Biomass Pellet Length, Test Conditions and Torrefaction on Mechanical Durability Characteristics According to ISO Standard 17831-1," Energies, MDPI, vol. 13(11), pages 1-16, June.
    10. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    11. Erić, Aleksandar & Cvetinović, Dejan & Milutinović, Nada & Škobalj, Predrag & Bakić, Vukman, 2022. "Combined parametric modelling of biomass devolatilisation process," Renewable Energy, Elsevier, vol. 193(C), pages 13-22.
    12. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    13. Kouteu Nanssou, Paul Alain & Jiokap Nono, Yvette & Kapseu, César, 2016. "Pretreatment of cassava stems and peelings by thermohydrolysis to enhance hydrolysis yield of cellulose in bioethanol production process," Renewable Energy, Elsevier, vol. 97(C), pages 252-265.
    14. Zhou, Hewen & Yang, Qing & Gul, Eid & Shi, Mengmeng & Li, Jiashuo & Yang, Minjiao & Yang, Haiping & Chen, Bin & Zhao, Haibo & Yan, Yunjun & Erdoğan, Güneş & Bartocci, Pietro & Fantozzi, Francesco, 2021. "Decarbonizing university campuses through the production of biogas from food waste: An LCA analysis," Renewable Energy, Elsevier, vol. 176(C), pages 565-578.
    15. Corton, J. & Donnison, I.S. & Ross, A.B. & Lea-Langton, A.R. & Wachendorf, M. & Fraser, M.D., 2021. "Impact of vegetation type and pre-processing on product yields and properties following hydrothermal conversion of conservation biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    16. Wioletta Żukiewicz-Sobczak & Agnieszka Latawiec & Paweł Sobczak & Bernardo Strassburg & Dorota Plewik & Małgorzata Tokarska-Rodak, 2020. "Biochars Originating from Different Biomass and Pyrolysis Process Reveal to Have Different Microbial Characterization: Implications for Practice," Sustainability, MDPI, vol. 12(4), pages 1-13, February.
    17. da Silva, Francinaldo Leite & de Oliveira Campos, Alan & dos Santos, Davi Alves & Batista Magalhães, Emilianny Rafaely & de Macedo, Gorete Ribeiro & dos Santos, Everaldo Silvino, 2018. "Valorization of an agroextractive residue—Carnauba straw—for the production of bioethanol by simultaneous saccharification and fermentation (SSF)," Renewable Energy, Elsevier, vol. 127(C), pages 661-669.
    18. Cuevas, Manuel & Sánchez, Sebastián & García, Juan F. & Baeza, Jaime & Parra, Carolina & Freer, Juanita, 2015. "Enhanced ethanol production by simultaneous saccharification and fermentation of pretreated olive stones," Renewable Energy, Elsevier, vol. 74(C), pages 839-847.
    19. Giacomo Fabbrizi & Tommaso Giannoni & Leonardo Lorenzi & Andrea Nicolini & Paola Iodice & Valentina Coccia & Gianluca Cavalaglio & Mattia Gelosia, 2022. "High Solid and Low Cellulase Enzymatic Hydrolysis of Cardoon Stems Pretreated by Acidified γ-Valerolactone/Water Solution," Energies, MDPI, vol. 15(7), pages 1-12, April.
    20. Siddique, Istiaq Jamil & Salema, Arshad Adam & Antunes, Elsa & Vinu, Ravikrishnan, 2022. "Technical challenges in scaling up the microwave technology for biomass processing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:193:y:2020:i:c:s0360544219323916. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.