IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v131y2017icp1-12.html
   My bibliography  Save this article

Algae pyrolytic poly-generation: Influence of component difference and temperature on products characteristics

Author

Listed:
  • Chen, Wei
  • Yang, Haiping
  • Chen, Yingquan
  • Xia, Mingwei
  • Yang, Zixu
  • Wang, Xianhua
  • Chen, Hanping

Abstract

Pyrolytic poly-generation of three algae (Enteromorpha prolifera (EP), Spirulina platensis (SP) and Nannochloropsis sp. (NS)) was carried out in a fixed bed reactor and pyrolysis mechanism was explored in detail. Influences of pyrolysis temperature (400–800 °C) and biochemical components (carbohydrates, proteins and lipids) of algae on pyrolytic behavior and products characteristics were investigated. EP showed higher char yield, while SP and NS showed high bio-oil yields. At lower temperature (400–500 °C), CO2 was the main gas product, while H2, CH4 and CO evolved out quickly with temperature increasing. EP cracking could release more CO, while SP and NS cracking could release more H2, CH4 and C2. While for bio-oil, it was variant with algae composition and temperature, as EP showed higher furans, SP yielded large amounts of N-containing chemicals, while aliphatics and carboxylic acids were the dominated components for NS. However, aromatics gradually became the major compounds for all bio-oil at 700–800 °C. For char, C-O/C-O-C/C=N, C=O/C-N and COO- groups cracking gradually with temperature increasing and resulted in more aromatic C=C. The optimum operating temperature is 500–600 °C for algae pyrolytic poly-generation to achieve higher value of char, bio-oil and gas products together.

Suggested Citation

  • Chen, Wei & Yang, Haiping & Chen, Yingquan & Xia, Mingwei & Yang, Zixu & Wang, Xianhua & Chen, Hanping, 2017. "Algae pyrolytic poly-generation: Influence of component difference and temperature on products characteristics," Energy, Elsevier, vol. 131(C), pages 1-12.
    • Handle: RePEc:eee:energy:v:131:y:2017:i:c:p:1-12
    DOI: 10.1016/j.energy.2017.05.019
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421730765X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.05.019?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    2. Hu, Zhiquan & Zheng, Yang & Yan, Feng & Xiao, Bo & Liu, Shiming, 2013. "Bio-oil production through pyrolysis of blue-green algae blooms (BGAB): Product distribution and bio-oil characterization," Energy, Elsevier, vol. 52(C), pages 119-125.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cao, Bin & Wang, Shuang & Hu, Yamin & Abomohra, Abd El-Fatah & Qian, Lili & He, Zhixia & Wang, Qian & Uzoejinwa, Benjamin Bernard & Esakkimuthu, Sivakumar, 2019. "Effect of washing with diluted acids on Enteromorpha clathrata pyrolysis products: Towards enhanced bio-oil from seaweeds," Renewable Energy, Elsevier, vol. 138(C), pages 29-38.
    2. Chen, Wei & Li, Kaixu & Xia, Mingwei & Yang, Haiping & Chen, Yingquan & Chen, Xu & Che, Qingfeng & Chen, Hanping, 2018. "Catalytic deoxygenation co-pyrolysis of bamboo wastes and microalgae with biochar catalyst," Energy, Elsevier, vol. 157(C), pages 472-482.
    3. Aniza, Ria & Chen, Wei-Hsin & Lin, Yu-Ying & Tran, Khanh-Quang & Chang, Jo-Shu & Lam, Su Shiung & Park, Young-Kwon & Kwon, Eilhann E. & Tabatabaei, Meisam, 2021. "Independent parallel pyrolysis kinetics of extracted proteins and lipids as well as model carbohydrates in microalgae," Applied Energy, Elsevier, vol. 300(C).
    4. Xia, Sunwen & Yang, Haiping & Lei, shuaishuai & Lu, Wang & Cai, Ning & Xiao, Haoyu & Chen, Yingquan & Chen, Hanping, 2023. "Iron salt catalytic pyrolysis of biomass: Influence of iron salt type," Energy, Elsevier, vol. 262(PA).
    5. Jiang, Yuan & Zong, Peijie & Ming, Xue & Wei, Haixin & Zhang, Xin & Bao, Yuan & Tian, Bin & Tian, Yuanyu & Qiao, Yingyun, 2021. "High-temperature fast pyrolysis of coal: An applied basic research using thermal gravimetric analyzer and the downer reactor," Energy, Elsevier, vol. 223(C).
    6. Zhu, Liang & Cai, Wei & Li, Jie & Chen, Dengyu & Ma, Zhongqing, 2024. "Highly selective production of light aromatics from co-catalytic fast pyrolysis of pre-deoxygenated biomass and hydrogen-rich polyethylene using a dual-catalyst system," Energy, Elsevier, vol. 296(C).
    7. Li, Qingyin & Lin, Haisheng & Fan, Huailin & Zhang, Shu & Yuan, Xiangzhou & Wang, Yi & Xiang, Jun & Hu, Song & Bkangmo Kontchouo, Félix Mérimé & Hu, Xun, 2021. "Co-pyrolysis of swine manure and pinewood sawdust: Evidence of cross-interaction of the volatiles and profound impacts on product characteristics," Renewable Energy, Elsevier, vol. 179(C), pages 1370-1384.
    8. Azizi, Kolsoom & Moshfegh Haghighi, Ali & Keshavarz Moraveji, Mostafa & Olazar, Martin & Lopez, Gartzen, 2019. "Co-pyrolysis of binary and ternary mixtures of microalgae, wood and waste tires through TGA," Renewable Energy, Elsevier, vol. 142(C), pages 264-271.
    9. Lu, Chen & Zhang, Xitong & Gao, Ying & Lin, Yunhao & Xu, Jiayu & Zhu, Chong & Zhu, Yuezhao, 2021. "Parametric study of catalytic co-gasification of cotton stalk and aqueous phase from wheat straw using hydrothermal carbonation," Energy, Elsevier, vol. 216(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Wei & Li, Kaixu & Xia, Mingwei & Yang, Haiping & Chen, Yingquan & Chen, Xu & Che, Qingfeng & Chen, Hanping, 2018. "Catalytic deoxygenation co-pyrolysis of bamboo wastes and microalgae with biochar catalyst," Energy, Elsevier, vol. 157(C), pages 472-482.
    2. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    3. Zahedi, Ali Reza & Mirnezami, Seyed Abolfazl, 2020. "Experimental analysis of biomass to biodiesel conversion using a novel renewable combined cycle system," Renewable Energy, Elsevier, vol. 162(C), pages 1177-1194.
    4. Gang Li & Yuguang Zhou & Fang Ji & Ying Liu & Benu Adhikari & Li Tian & Zonghu Ma & Renjie Dong, 2013. "Yield and Characteristics of Pyrolysis Products Obtained from Schizochytrium limacinum under Different Temperature Regimes," Energies, MDPI, vol. 6(7), pages 1-14, July.
    5. Yu, Dayu & Hu, Shuang & Liu, Weishan & Wang, Xiaoning & Jiang, Haifeng & Dong, Nanhang, 2020. "Pyrolysis of oleaginous yeast biomass from wastewater treatment: Kinetics analysis and biocrude characterization," Renewable Energy, Elsevier, vol. 150(C), pages 831-839.
    6. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    7. Lin, Kuang C. & Lin, Yuan-Chung & Hsiao, Yi-Hsing, 2014. "Microwave plasma studies of Spirulina algae pyrolysis with relevance to hydrogen production," Energy, Elsevier, vol. 64(C), pages 567-574.
    8. Diaz-Mendez, S.E. & Sierra-Grajeda, J.M.T. & Hernandez-Guerrero, A. & Rodriguez-Lelis, J.M., 2013. "Entropy generation as an environmental impact indicator and a sample application to freshwater ecosystems eutrophication," Energy, Elsevier, vol. 61(C), pages 234-239.
    9. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    10. Park, Ji-Yeon & Kim, Min-Cheol & Cheng, Jun & Yang, Weijuan & Kim, Deog-Keun, 2020. "Extraction of microalgal oil from Nannochloropsis oceanica by potassium hydroxide-assisted solvent extraction for heterogeneous transesterification," Renewable Energy, Elsevier, vol. 162(C), pages 2056-2065.
    11. Fazril Ideris & Mohd Faiz Muaz Ahmad Zamri & Abd Halim Shamsuddin & Saifuddin Nomanbhay & Fitranto Kusumo & Islam Md Rizwanul Fattah & Teuku Meurah Indra Mahlia, 2022. "Progress on Conventional and Advanced Techniques of In Situ Transesterification of Microalgae Lipids for Biodiesel Production," Energies, MDPI, vol. 15(19), pages 1-32, September.
    12. Ma, Yingqun & Wang, Qunhui & Gao, Zhen & Sun, Xiaohong & Wang, Nan & Niu, Ruxuan & Ma, Hongzhi, 2016. "Transesterification of waste cooking oil using FeCl3-modified resin catalyst and the research of catalytic mechanism," Renewable Energy, Elsevier, vol. 86(C), pages 643-650.
    13. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    14. Srivatsa, Srikanth Chakravartula & Li, Fanghua & Bhattacharya, Sankar, 2019. "Optimization of reaction parameters for bio-oil production by catalytic pyrolysis of microalga Tetraselmis suecica: Influence of Ni-loading on the bio-oil composition," Renewable Energy, Elsevier, vol. 142(C), pages 426-436.
    15. Rahman, M.A., 2020. "Valorizing of weeds algae through the solar assisted pyrolysis: Effects of dependable parameters on yields and characterization of products," Renewable Energy, Elsevier, vol. 147(P1), pages 937-946.
    16. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    17. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Rahimi, A. & Yusaf, Talal & Mamat, Rizalman & Sidik, N.A.C. & Azmi, W.H., 2017. "Effects of biodiesel fuel obtained from Salvia macrosiphon oil (ultrasonic-assisted) on performance and emissions of diesel engine," Energy, Elsevier, vol. 131(C), pages 289-296.
    18. Ly, Hoang Vu & Kim, Seung-Soo & Woo, Hee Chul & Choi, Jae Hyung & Suh, Dong Jin & Kim, Jinsoo, 2015. "Fast pyrolysis of macroalga Saccharina japonica in a bubbling fluidized-bed reactor for bio-oil production," Energy, Elsevier, vol. 93(P2), pages 1436-1446.
    19. Zhu, Liandong & Nugroho, Y.K. & Shakeel, S.R. & Li, Zhaohua & Martinkauppi, B. & Hiltunen, E., 2017. "Using microalgae to produce liquid transportation biodiesel: What is next?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 391-400.
    20. Marcin Dębowski & Magda Dudek & Marcin Zieliński & Anna Nowicka & Joanna Kazimierowicz, 2021. "Microalgal Hydrogen Production in Relation to Other Biomass-Based Technologies—A Review," Energies, MDPI, vol. 14(19), pages 1-27, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:131:y:2017:i:c:p:1-12. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.