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Form-stable oxalic acid dihydrate/glycolic acid-based composite PCMs for thermal energy storage

Author

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  • Wang, Jie
  • Han, Weifang
  • Ge, Chunhua
  • Guan, Hongyu
  • Yang, Huizhi
  • Zhang, Xiangdong

Abstract

The development of high efficient materials for storage and utilization of sustainable thermal energy is very meaningful. Herein, in this research, an oxalic acid dihydrate/glycolic acid (OG) binary eutectic mixtures with the ratio of 80 wt%/20 wt% was prepared as phase change material (PCM), hydrothermal carbon (HTC) and poly (acrylamide-co-acrylic acid) copolymer (PAAAM) were separately and together used as support materials to solve liquid-state leakage problem and improve thermal conductivity. Three form-stable PCM composites (OG/PAAAM, OG/HTC/PAAAM and OG/HTC) were synthesized. The prepared composites were studied by XRD and FT-IR spectra, their thermophysical properties and PCM storage properties were investigated using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The OG/PAAAM, OG/HTC/PAAAM and OG/HTC showed the high loading rate to OG content, which are 1718 wt%, 1329 wt% and 1150 wt%, and the latent heat are 289.6, 313.2 and 318.8 J/g, respectively. In addition, the composites possess excellent recyclability after 101 times melting-freezing cycles. Compared to pure OG, OG/PAAAM and OG/HTC/PAAAM (0.2766, 0.3125 and 0.8538 W/m K), the OG/HTC exhibit a higher thermal conductivity of 1.3867 W/m K.

Suggested Citation

  • Wang, Jie & Han, Weifang & Ge, Chunhua & Guan, Hongyu & Yang, Huizhi & Zhang, Xiangdong, 2019. "Form-stable oxalic acid dihydrate/glycolic acid-based composite PCMs for thermal energy storage," Renewable Energy, Elsevier, vol. 136(C), pages 657-663.
    • Handle: RePEc:eee:renene:v:136:y:2019:i:c:p:657-663
    DOI: 10.1016/j.renene.2019.01.063
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