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Critical phenomena and their effect on thermal energy storage in supercritical fluids

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  • Hobold, Gustavo M.
  • da Silva, Alexandre K.

Abstract

Large-scale implementation of concentrated solar power plants requires energy storage systems if fossil sources are to be fully replaced. While several candidates have appeared, most still face major issues such as cost, limited energy density and material compatibility. The present paper explores the influence of property variation in the proximity of the critical point on thermal energy storage using supercritical fluids (sTES) from thermodynamic and heat transfer standpoints. Influence of thermodynamic operational parameters on energy density of isobaric and isochoric sTES and their optima is discussed, showing that the energy density results from a competition between average specific heat and loaded density. Moreover, sTES is shown to be applicable to virtually any storage temperature, depending only on the fluid’s critical point. Finally, a heat transfer and energy density comparison to other existing storage mechanisms is presented and supercritical water is shown to be competitive for high temperature thermal energy storage.

Suggested Citation

  • Hobold, Gustavo M. & da Silva, Alexandre K., 2017. "Critical phenomena and their effect on thermal energy storage in supercritical fluids," Applied Energy, Elsevier, vol. 205(C), pages 1447-1458.
    • Handle: RePEc:eee:appene:v:205:y:2017:i:c:p:1447-1458
    DOI: 10.1016/j.apenergy.2017.09.081
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    1. Battisti, F.G. & de Araujo Passos, L.A. & da Silva, A.K., 2022. "Economic and environmental assessment of a CO2 solar-powered plant with packed-bed thermal energy storage," Applied Energy, Elsevier, vol. 314(C).
    2. Zhang, Jibao & Zhang, Xin & Wang, Tao & Hou, Xiaosen, 2019. "A numerical study on jet characteristics under different supercritical conditions for engine applications," Applied Energy, Elsevier, vol. 252(C), pages 1-1.

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