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Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite

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Listed:
  • Zhang, Xiaoguang
  • Yin, Zhaoyu
  • Meng, Dezhi
  • Huang, Zhaohui
  • Wen, Ruilong
  • Huang, Yaoting
  • Min, Xin
  • Liu, Yangai
  • Fang, Minghao
  • Wu, Xiaowen

Abstract

Stearic acid (SA) and modified expanded vermiculite (EV) shape-stabilized composite phase change materials (ss-CPCMs) with enhanced thermal conductivity were prepared. EV was impregnated with a starch solution, and then a composite of EV and carbon (EVC) was obtained by carbonizing starch in-situ in the EV layers. 63.12 wt % of SA was retained in the SA/EVC ss-CPCMs without leakage. Scanning electron microscopy (SEM) images showed that the EVC with highly porous micro-pores acted as a good support matrix for absorbing molten SA. The thermal conductivity of the SA/EVC ss-CPCMs was 0.52 W/(m K), and this was an increase of 52.9% compared with that of the SA/EV ss-CPCMs. The results from Fourier transform infrared spectroscopy (FT-IR), Differential scanning calorimeter (DSC), thermogravimetric analysis (TGA), and thermal cycling tests indicated that the prepared SA/EVC ss-CPCMs are a promising material for energy efficient buildings because of their optimum phase-change temperature, a high enthalpy of phase change, ideal thermal conductivity, and good chemical and thermal stability.

Suggested Citation

  • Zhang, Xiaoguang & Yin, Zhaoyu & Meng, Dezhi & Huang, Zhaohui & Wen, Ruilong & Huang, Yaoting & Min, Xin & Liu, Yangai & Fang, Minghao & Wu, Xiaowen, 2017. "Shape-stabilized composite phase change materials with high thermal conductivity based on stearic acid and modified expanded vermiculite," Renewable Energy, Elsevier, vol. 112(C), pages 113-123.
    • Handle: RePEc:eee:renene:v:112:y:2017:i:c:p:113-123
    DOI: 10.1016/j.renene.2017.05.026
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    11. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
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    15. Zhang, Xialan & Lin, Qilang & Luo, Huijun & Luo, Shiyuan, 2020. "Three-dimensional graphitic hierarchical porous carbon/stearic acid composite as shape-stabilized phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 260(C).

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