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Effect of lanthanide ion doping on Mg−Al mixed oxides as active acid−base catalysts for fatty acid ethyl ester synthesis

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  • de Souza Rossi, Jessika
  • Perrone, Olavo Micali
  • Siqueira, Marcos Rechi
  • Volanti, Diogo Paschoalini
  • Gomes, Eleni
  • Da-Silva, Roberto
  • Boscolo, Mauricio

Abstract

MgAl-hydrotalcites (HT) containing 1–2% of the lanthanide ions La3+, Ce3+ and Lu3+ were evaluated as heterogeneous catalysts in the transesterification process for fatty acid ethyl ester (FAEE) synthesis in order to understand the effect of the high ionic-radii of these metals in the material structure and their catalytic activity. The addition of lanthanides to the catalysts resulted in a decrease of the thermal degradation temperature as well as the specific surface, but, on the other hand, it increases the basicity, crystallinity, and improve the yield in biodiesel production. In general, MMOs with 1% of lanthanides showed higher yields than those with 2%, and the oxide with 1% of Lu3+ reached the best catalytic result for ethanol biodiesel production (84%), about 4.5 times greater than the reference material.

Suggested Citation

  • de Souza Rossi, Jessika & Perrone, Olavo Micali & Siqueira, Marcos Rechi & Volanti, Diogo Paschoalini & Gomes, Eleni & Da-Silva, Roberto & Boscolo, Mauricio, 2019. "Effect of lanthanide ion doping on Mg−Al mixed oxides as active acid−base catalysts for fatty acid ethyl ester synthesis," Renewable Energy, Elsevier, vol. 133(C), pages 367-372.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:367-372
    DOI: 10.1016/j.renene.2018.10.038
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    References listed on IDEAS

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    1. Ramachandran, K. & Suganya, T. & Nagendra Gandhi, N. & Renganathan, S., 2013. "Recent developments for biodiesel production by ultrasonic assist transesterification using different heterogeneous catalyst: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 410-418.
    2. Likozar, Blaž & Levec, Janez, 2014. "Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics ," Applied Energy, Elsevier, vol. 123(C), pages 108-120.
    3. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
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    1. Lima-Corrêa, Renata A.B. & Castro, Cínthia S. & Damasceno, Amanda S. & Assaf, José M., 2020. "The enhanced activity of base metal modified MgAl mixed oxides from sol-gel hydrotalcite for ethylic transesterification," Renewable Energy, Elsevier, vol. 146(C), pages 1984-1990.

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