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Three-dimensional interconnected porous TiO2 ceramics for high-temperature thermal storage

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  • Zhao, Siyi
  • Li, Jinhong
  • Wu, Yifan
  • Song, Shuang
  • Liu, Lijie

Abstract

Porous TiO2 ceramics (PTC) with uniform, controllable, 3D fully interconnected pore structure and high porosities were prepared by a facile particle-stabilized emulsion templating method, and adjustable porosity of PTC could be obtained by controlling its solid content from 20 to 35 wt %. The Na2SO4 were selected as the high temperature phase change material and PTC as the support material, a kind of novelty form stable composite phase change material with high heat storage capacity and excellent shape stability were manufactured by impregnation under high temperature condition, which named PTCN1-4. SEM results showed that the Na2SO4 were evenly distributed into the pores of PTC, XRD and FT-IR tests confirmed the excellent chemical compatibility between Na2SO4 and PTC. The maximum melting enthalpy and solidification enthalpy of the composite phase change material were 212.6 and 161.0 J/g, respectively, and the corresponding maximum impregnation ratio reached 96.9%. TGA results showed that composite phase change material had excellent thermal stability in high temperature range. Therefore, PTC is a promising high temperature heat storage carrier material.

Suggested Citation

  • Zhao, Siyi & Li, Jinhong & Wu, Yifan & Song, Shuang & Liu, Lijie, 2021. "Three-dimensional interconnected porous TiO2 ceramics for high-temperature thermal storage," Renewable Energy, Elsevier, vol. 178(C), pages 701-708.
    • Handle: RePEc:eee:renene:v:178:y:2021:i:c:p:701-708
    DOI: 10.1016/j.renene.2021.06.091
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    References listed on IDEAS

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    1. Quan, Bingqing & Wang, Jinzhi & Li, Yi & Sui, Miao & Xie, Heng & Liu, Zhigang & Wu, Hao & Lu, Xiang & Tong, Yi, 2023. "Cellulose nanofibrous/MXene aerogel encapsulated phase change composites with excellent thermal energy conversion and storage capacity," Energy, Elsevier, vol. 262(PB).

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