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Multi-SO3H functionalized mesoporous polymeric acid catalyst for biodiesel production and fructose-to-biodiesel additive conversion

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  • Pan, Hu
  • Liu, Xiaofang
  • Zhang, Heng
  • Yang, Kaili
  • Huang, Shan
  • Yang, Song

Abstract

Novel and efficient multi-SO3H functionalized mesoporous polymeric solid acid (PD-En-SO3H) was synthesized from sulfonation of ethylenediamine (En)-functionalization of mesoporous polydivinylbenzene (PD). The catalyst was characterized by XPS, FT-IR, N2 adsorption-desorption, TEM, SEM, TG and elemental analysis. Characterizations suggest that PD-En-SO3H possess abundant mesoporosity, high BET surface area (369.00 m2/g) and high acidity (2.10 mmol/g). The catalytic activity was investigated for biodiesel (BD) production by esterification of various free fatty acids (FFAs) and synthesis of levulinate esters (BD additive) from fructose. The effects of reaction conditions such as reaction temperature, reaction time, molar ratio of methanol to oil and catalyst amount on conversion of oleic acid were also explored. Interestingly, PD-En-SO3H showed excellent catalytic performance, which was more active than commercial Amberlyst 15 and Nafion NR50. Moreover, it could be reused for four times and still maintained high catalytic activity.

Suggested Citation

  • Pan, Hu & Liu, Xiaofang & Zhang, Heng & Yang, Kaili & Huang, Shan & Yang, Song, 2017. "Multi-SO3H functionalized mesoporous polymeric acid catalyst for biodiesel production and fructose-to-biodiesel additive conversion," Renewable Energy, Elsevier, vol. 107(C), pages 245-252.
    • Handle: RePEc:eee:renene:v:107:y:2017:i:c:p:245-252
    DOI: 10.1016/j.renene.2017.02.009
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    1. Zhang, Yue & Wong, Wing-Tak & Yung, Ka-Fu, 2014. "Biodiesel production via esterification of oleic acid catalyzed by chlorosulfonic acid modified zirconia," Applied Energy, Elsevier, vol. 116(C), pages 191-198.
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    3. Peng, Lincai & Lin, Lu & Li, Hui & Yang, Qiulin, 2011. "Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts," Applied Energy, Elsevier, vol. 88(12), pages 4590-4596.
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    4. Zhang, Heng & Li, Hu & Pan, Hu & Wang, Anping & Souzanchi, Sadra & Xu, Chunbao (Charles) & Yang, Song, 2018. "Magnetically recyclable acidic polymeric ionic liquids decorated with hydrophobic regulators as highly efficient and stable catalysts for biodiesel production," Applied Energy, Elsevier, vol. 223(C), pages 416-429.
    5. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    6. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.

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