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Highly efficient conversion of glucose into methyl levulinate catalyzed by tin-exchanged montmorillonite

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  • Liu, Jie
  • Wang, Xue-Qian
  • Yang, Bei-Bei
  • Liu, Chun-Ling
  • Xu, Chun-Li
  • Dong, Wen-Sheng

Abstract

Tin-exchanged montmorillonite catalysts were prepared by an ion exchange method and examined as solid acid catalysts. The synthesized catalysts were characterized by X-ray fluorescence spectroscopy, inductively coupled plasma optical emission spectroscopy, N2 adsorption–desorption analysis, powder X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, NH3 temperature-programmed desorption analysis, and pyridine adsorption Fourier transform infrared spectroscopy. Subsequently, the catalysts were examined for use in the conversion of glucose into methyl levulinate in methanol. A high yield of methyl levulinate of 59.7% was obtained upon conversion of 0.3 g glucose in 24 g methanol over 0.15 g catalyst at 220 °C under 2 MPa N2 for 6 h. The recyclability of the catalyst was also examined, and the conversions of glucose and methanol remained mostly unchanged under repeated usage of the catalyst in five catalytic runs; in contrast, the yield of methyl levulinate decreased slightly. The excellent catalytic performance of the tin-exchanged montmorillonite catalyst was attributed to a combination of the presence of a large amount of acidic sites and balanced amounts of Lewis and Brønsted acid sites on the catalyst.

Suggested Citation

  • Liu, Jie & Wang, Xue-Qian & Yang, Bei-Bei & Liu, Chun-Ling & Xu, Chun-Li & Dong, Wen-Sheng, 2018. "Highly efficient conversion of glucose into methyl levulinate catalyzed by tin-exchanged montmorillonite," Renewable Energy, Elsevier, vol. 120(C), pages 231-240.
    • Handle: RePEc:eee:renene:v:120:y:2018:i:c:p:231-240
    DOI: 10.1016/j.renene.2017.12.104
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    References listed on IDEAS

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    1. Xu, Guizhuan & Chang, Chun & Fang, Shuqi & Ma, Xiaojian, 2015. "Cellulose reactivity in ethanol at elevate temperature and the kinetics of one-pot preparation of ethyl levulinate from cellulose," Renewable Energy, Elsevier, vol. 78(C), pages 583-589.
    2. Peng, Lincai & Lin, Lu & Li, Hui & Yang, Qiulin, 2011. "Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts," Applied Energy, Elsevier, vol. 88(12), pages 4590-4596.
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    1. Tang, Yiwei & Liu, Xiaoning & Xi, Ran & Liu, Le & Qi, Xinhua, 2022. "Catalytic one-pot conversion of biomass-derived furfural to ethyl levulinate over bifunctional Nb/Ni@OMC," Renewable Energy, Elsevier, vol. 200(C), pages 821-831.
    2. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    3. Mohammadbagheri, Zahra & Najafi Chermahini, Alireza, 2020. "Direct production of hexyl levulinate as a potential fuel additive from glucose catalyzed by modified dendritic fibrous nanosilica," Renewable Energy, Elsevier, vol. 147(P1), pages 2229-2237.

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