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Esterification of palm fatty acid distillate (PFAD) to biodiesel using Bi-functional catalyst synthesized from waste angel wing shell (Cyrtopleura costata)

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  • Syazwani, Osman Nur
  • Rashid, Umer
  • Mastuli, Mohd Sufri
  • Taufiq-Yap, Yun Hin

Abstract

In this work, a green solid acid catalyst derived from the waste material of the angel wing shell (AWS) was synthesized using a two-step method: calcination followed by sulfonation. The calcined angel wing shell (CAWS) was supported with varied concentrations of sulphuric acid to obtain an optimum high acidity level of the catalyst. The CaO-based calcined angel wing shell sulphated (CAWS-(x)SO4) catalysts, where x = sulphuric acid concentration, were analysed using X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, temperature programmed desorption of carbon dioxide and ammonia, BET surface area, and scanning electron microscope. The specific surface area, pore volume, and pore diameter of the CAWS was increased significantly after being sulphated at the optimum sulphuric acid concentration; whereas, the CAWS-(7) SO4 showed the highest total amount of acidity (4726 μmol/g). The optimal FAME conversion (98%) from the PFAD was acquired at the reaction temperature of 80 °C, 15:1 MeOH:PFAD molar ratio and 5 wt% catalyst loading for a 3 h reaction time. The CAWS-(7)SO4 catalyst was reused two times with a high FAME yield without further treatment under optimized reaction conditions. The use of the AWS for the synthesis of catalysts has enormous potential for biodiesel production from high FFA oils due to its lower production cost, abundant availability and high catalytic activity.

Suggested Citation

  • Syazwani, Osman Nur & Rashid, Umer & Mastuli, Mohd Sufri & Taufiq-Yap, Yun Hin, 2019. "Esterification of palm fatty acid distillate (PFAD) to biodiesel using Bi-functional catalyst synthesized from waste angel wing shell (Cyrtopleura costata)," Renewable Energy, Elsevier, vol. 131(C), pages 187-196.
    • Handle: RePEc:eee:renene:v:131:y:2019:i:c:p:187-196
    DOI: 10.1016/j.renene.2018.07.031
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    3. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    4. Sangar, Shatesh Kumar & Syazwani, Osman Nur & Farabi, M.S. Ahmad & Razali, S.M. & Shobhana, Gnanasekhar & Teo, Siow Hwa & Taufiq-Yap, Yun Hin, 2019. "Effective biodiesel synthesis from palm fatty acid distillate (PFAD) using carbon-based solid acid catalyst derived glycerol," Renewable Energy, Elsevier, vol. 142(C), pages 658-667.
    5. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    6. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.
    7. Silva, Sónia M. & Peixoto, Andreia F. & Freire, Cristina, 2020. "Organosulfonic acid functionalized montmorillonites as solid catalysts for (trans) esterification of free fatty acids and (waste) oils," Renewable Energy, Elsevier, vol. 146(C), pages 2416-2429.

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