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Characterizing and using a new bi-functional catalyst to sustainably synthesize methyl levulinate from biomass carbohydrates

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  • Oprescu, Elena-Emilia
  • Enascuta, Cristina-Emanuela
  • Doukeh, Rami
  • Calin, Catalina
  • Lavric, Vasile

Abstract

In recent years, significant attention has been dedicated to converting biomass carbohydrates into alkyl levulinates (biofuel additives) in alcoholic media, in search of various cheap and active solid catalysts through relatively easy pathways and from non-dangerous precursors. The synthesis of methyl levulinate (ML) using a new Brønsted/Lewis acid sites catalyst was investigated, emphasizing the influence of three parameters (catalyst loading, the molar concentration of fructose in methanol, and reaction temperature) on the process. The synthetized catalyst, SO42−/TiO2–La2O3 coating Fe3O4, was characterized by different techniques (FT-IR, XRD, TGA, TEM-EDX, ICP-OES). The design of the ML synthesis experiment was carried out using the Box-Behnken technique, while the response surface methodology was applied to obtain the optimized process conditions. A mathematical model of the catalytic synthesis was built, based upon first principles, and the experimental time variation of the reaction mixture concentrations was used to find, through regression, the values of the constants of a newly proposed kinetic model.

Suggested Citation

  • Oprescu, Elena-Emilia & Enascuta, Cristina-Emanuela & Doukeh, Rami & Calin, Catalina & Lavric, Vasile, 2021. "Characterizing and using a new bi-functional catalyst to sustainably synthesize methyl levulinate from biomass carbohydrates," Renewable Energy, Elsevier, vol. 176(C), pages 651-662.
    • Handle: RePEc:eee:renene:v:176:y:2021:i:c:p:651-662
    DOI: 10.1016/j.renene.2021.05.120
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    References listed on IDEAS

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    1. Mohammadbagheri, Zahra & Najafi Chermahini, Alireza, 2020. "Direct production of hexyl levulinate as a potential fuel additive from glucose catalyzed by modified dendritic fibrous nanosilica," Renewable Energy, Elsevier, vol. 147(P1), pages 2229-2237.
    2. Peng, Lincai & Lin, Lu & Li, Hui & Yang, Qiulin, 2011. "Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts," Applied Energy, Elsevier, vol. 88(12), pages 4590-4596.
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    Cited by:

    1. Zhang, Ronghua & Zhang, Wenhao & Jiang, Jianchun & Xu, Junming & Wang, Kui & Feng, Junfeng & Pan, Hui, 2024. "Catalytic valorization of biomass carbohydrates into levulinic acid/ester by using bifunctional catalysts," Renewable Energy, Elsevier, vol. 221(C).
    2. Samanta, Ritika & Chakraborty, Rajat, 2023. "Methyl levulinate synthesis from rice husk employing e-waste derived silica supported nano CuO–CdSO4 photocatalyst: Assessment of production environmental impacts, engine performance and emissions," Renewable Energy, Elsevier, vol. 210(C), pages 842-858.

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