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Graphene, Graphene Oxide and Carbon Nanotubes in Raman Spectroscopy

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  • Amelia Carolina Sparavigna

Abstract

In previous discussions we have considered the Raman spectra of specific carbon-based materials, such as diamond, graphite, and the biochar resulting from pyrolysis of biomass. We have shown how spectra can be decomposed, according to the intended number of components and the proper line shapes. Here, we approach the Raman spectra of graphene and graphene oxide, to understand how many components are required to interpret the related fingerprints. Besides graphene and graphene oxides, here we also review some literature about the Raman spectroscopy of carbon nanotubes, focusing especially on the line shapes. As shown by literature, the Raman spectra are able of giving information on the nature of nanotubes (metallic or semiconducting) and if they are single- or multi-walled structures. We will find that the Raman spectroscopy is able of investigating even a single nanotube. It will be stressed the role of curvature in breaking the symmetry of carbon layers, to produce the observed Raman bands. In particular, the existence of Breit-Wigner-Fano lines will be investigated.

Suggested Citation

  • Amelia Carolina Sparavigna, 2024. "Graphene, Graphene Oxide and Carbon Nanotubes in Raman Spectroscopy," International Journal of Sciences, Office ijSciences, vol. 13(07), pages 1-26, July.
    • Handle: RePEc:adm:journl:v:13:y:2024:i:7:p:1-26
    DOI: 10.18483/ijSci.2773
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    References listed on IDEAS

    as
    1. Amelia Carolina Sparavigna, 2023. "q-Gaussian Tsallis Line Shapes and Raman Spectral Bands," International Journal of Sciences, Office ijSciences, vol. 12(03), pages 27-40, March.
    2. Dmitriy A. Dikin & Sasha Stankovich & Eric J. Zimney & Richard D. Piner & Geoffrey H. B. Dommett & Guennadi Evmenenko & SonBinh T. Nguyen & Rodney S. Ruoff, 2007. "Preparation and characterization of graphene oxide paper," Nature, Nature, vol. 448(7152), pages 457-460, July.
    3. Amelia Carolina Sparavigna, 2023. "SERS Spectral Bands of L-Cysteine, Cysteamine and Homocysteine Fitted by Tsallis q-Gaussian Functions," International Journal of Sciences, Office ijSciences, vol. 12(09), pages 14-24, September.
    4. Amelia Carolina Sparavigna, 2024. "Raman Spectroscopy of Siderite with q-Gaussian and split-q-Gaussian Analyses," International Journal of Sciences, Office ijSciences, vol. 13(02), pages 8-21, February.
    5. R. Hanel & S. Thurner & C. Tsallis, 2009. "Limit distributions of scale-invariant probabilistic models of correlated random variables with the q-Gaussian as an explicit example," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 72(2), pages 263-268, November.
    6. Sasha Stankovich & Dmitriy A. Dikin & Geoffrey H. B. Dommett & Kevin M. Kohlhaas & Eric J. Zimney & Eric A. Stach & Richard D. Piner & SonBinh T. Nguyen & Rodney S. Ruoff, 2006. "Graphene-based composite materials," Nature, Nature, vol. 442(7100), pages 282-286, July.
    7. Devi, Sandhya, 2021. "Asymmetric Tsallis distributions for modeling financial market dynamics," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 578(C).
    8. Sandhya Devi, 2021. "Asymmetric Tsallis distributions for modelling financial market dynamics," Papers 2102.04532, arXiv.org.
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