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Simulation and evaluation of a process concept for the generation of synthetic fuel from CO2 and H2

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  • König, Daniel H.
  • Baucks, Nadine
  • Dietrich, Ralph-Uwe
  • Wörner, Antje

Abstract

Future aviation, shipping and heavy load transportation will continue to depend on energy carriers with a high energy density. The Power-to-Liquid technology is an approach to produce synthetic hydrocarbons, which fulfill this requirement. The proposed concept is based on H2 from electrolysis, which reacts with CO2 via the reverse water-gas shift reaction to syngas. Syngas is then synthesized to liquid hydrocarbons by Fischer-Tropsch synthesis. A downstream product separation and upgrading section allows the production of defined fractions for specific applications. A flowsheet process model is build and heat integration is conducted. The input capacity is set to 100 MWLHV of H2. A total amount of 1260 bbl/d liquid hydrocarbons (67.1 MWLHV) is generated. The carbon conversion and the Power-to-Liquid efficiency, which is defined as the fraction of the electrical energy chemically bound into liquid hydrocarbons, are identified as the parameters to evaluate the overall process performance. The Power-to-Liquid efficiency is found to be 43.3%. The carbon conversion rate of 73.7% indicates the exploiting of the introduced CO2.

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  • König, Daniel H. & Baucks, Nadine & Dietrich, Ralph-Uwe & Wörner, Antje, 2015. "Simulation and evaluation of a process concept for the generation of synthetic fuel from CO2 and H2," Energy, Elsevier, vol. 91(C), pages 833-841.
    • Handle: RePEc:eee:energy:v:91:y:2015:i:c:p:833-841
    DOI: 10.1016/j.energy.2015.08.099
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