IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v91y2015icp772-781.html
   My bibliography  Save this article

Study of metal-organic framework MIL-101(Cr) for natural gas (methane) storage and compare with other MOFs (metal-organic frameworks)

Author

Listed:
  • Kayal, Sibnath
  • Sun, Baichuan
  • Chakraborty, Anutosh

Abstract

Natural gas, containing mainly methane (CH4), has the potential to substitute petroleum as fuel for vehicles. However, the storage of natural gas at adequately high densities to fulfil the requirement of driving range is a challenging task. One prospective solution is the use of porous materials to adsorb natural gas at lower pressures and temperatures resulting in higher density storage. In this article, we present an extensive study on synthesis, characterization and property evaluation of MIL-101(Cr) MOF (metal-organic framework) for CH4 adsorption. At 298 K, it is observed that the total volumetric uptake of CH4 on MIL-101(Cr) MOF is about (i) 150 cm3/cm3 at 35 bar, (ii) 215 cm3/cm3 at 65 bar, and (iii) 30 cm3/cm3 at 5 bar. Further, we have demonstrated a novel idea to store CH4 on MOFs in an ANG (adsorbed natural gas) vessel below critical point temperature employing LNG (liquefied natural gas) regasification. This LNG–ANG coupling improves the competitiveness of ANG storage and increases the CH4 working capacity. Employing LNG-ANG coupling, it is found that MIL-101(Cr) exhibits high CH4 delivery or working capacity which is (i) 240 cm3/cm3 for the operating parameters ranging from 6 bar at 160 K to 5 bar at 298 K, and (ii) 125 cm3/cm3 for the operating parameters varying from 1.2 bar at 160 K to 5 bar at 298 K.

Suggested Citation

  • Kayal, Sibnath & Sun, Baichuan & Chakraborty, Anutosh, 2015. "Study of metal-organic framework MIL-101(Cr) for natural gas (methane) storage and compare with other MOFs (metal-organic frameworks)," Energy, Elsevier, vol. 91(C), pages 772-781.
  • Handle: RePEc:eee:energy:v:91:y:2015:i:c:p:772-781
    DOI: 10.1016/j.energy.2015.08.096
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215011731
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2015.08.096?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wegrzyn, J. & Gurevich, M., 1996. "Adsorbent storage of natural gas," Applied Energy, Elsevier, vol. 55(2), pages 71-83, October.
    2. Miana, Mario & Hoyo, Rafael del & Rodrigálvarez, Vega & Valdés, José Ramón & Llorens, Raúl, 2010. "Calculation models for prediction of Liquefied Natural Gas (LNG) ageing during ship transportation," Applied Energy, Elsevier, vol. 87(5), pages 1687-1700, May.
    3. Waller, Michael G. & Williams, Eric D. & Matteson, Schuyler W. & Trabold, Thomas A., 2014. "Current and theoretical maximum well-to-wheels exergy efficiency of options to power vehicles with natural gas," Applied Energy, Elsevier, vol. 127(C), pages 55-63.
    4. Middleton, Richard S. & Eccles, Jordan K., 2013. "The complex future of CO2 capture and storage: Variable electricity generation and fossil fuel power," Applied Energy, Elsevier, vol. 108(C), pages 66-73.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Park, Jaewoo & Attia, Nour F. & Jung, Minji & Lee, Myoung Eun & Lee, Kiyoung & Chung, Jaewoo & Oh, Hyunchul, 2018. "Sustainable nanoporous carbon for CO2, CH4, N2, H2 adsorption and CO2/CH4 and CO2/N2 separation," Energy, Elsevier, vol. 158(C), pages 9-16.
    2. Rupam, Tahmid Hasan & Palash, M.L. & Islam, Md Amirul & Saha, Bidyut Baran, 2022. "Transitional metal-doped aluminum fumarates for ultra-low heat driven adsorption cooling systems," Energy, Elsevier, vol. 238(PC).
    3. Nie, Bin, 2023. "Development of low-metamorphic coalbed methane reservoirs with superheated steam injection: Simulation of wellbore heat transfer," Energy, Elsevier, vol. 275(C).
    4. Nima Mohammadi & Behnam Mousazadeh & Touba Hamoule, 2021. "Synthesis and characterization of NH2-SiO2@Cu-MOF as a high-performance adsorbent for Pb ion removal from water environment," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(2), pages 1688-1705, February.
    5. Duan, Zhongdi & Wang, Jianhu & Yuan, Yuchao & Tang, Wenyong & Xue, Hongxiang, 2023. "Near-wall thermal regulation for cryogenic storage by adsorbent coating: Modelling and pore-scale investigation," Applied Energy, Elsevier, vol. 349(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Malakoutirad, Mohammad & Bradley, Thomas H. & Hagen, Chris, 2015. "Design considerations for an engine-integral reciprocating natural gas compressor," Applied Energy, Elsevier, vol. 156(C), pages 129-137.
    2. Mohd Shariq Khan & Muhammad Abdul Qyyum & Wahid Ali & Aref Wazwaz & Khursheed B. Ansari & Moonyong Lee, 2020. "Energy Saving through Efficient BOG Prediction and Impact of Static Boil-off-Rate in Full Containment-Type LNG Storage Tank," Energies, MDPI, vol. 13(21), pages 1-14, October.
    3. Talibi, Midhat & Hellier, Paul & Ladommatos, Nicos, 2017. "Combustion and exhaust emission characteristics, and in-cylinder gas composition, of hydrogen enriched biogas mixtures in a diesel engine," Energy, Elsevier, vol. 124(C), pages 397-412.
    4. Orsi, Francesco & Muratori, Matteo & Rocco, Matteo & Colombo, Emanuela & Rizzoni, Giorgio, 2016. "A multi-dimensional well-to-wheels analysis of passenger vehicles in different regions: Primary energy consumption, CO2 emissions, and economic cost," Applied Energy, Elsevier, vol. 169(C), pages 197-209.
    5. Sun, Liang & Chen, Wenying, 2017. "Development and application of a multi-stage CCUS source–sink matching model," Applied Energy, Elsevier, vol. 185(P2), pages 1424-1432.
    6. Perejón, Antonio & Romeo, Luis M. & Lara, Yolanda & Lisbona, Pilar & Martínez, Ana & Valverde, Jose Manuel, 2016. "The Calcium-Looping technology for CO2 capture: On the important roles of energy integration and sorbent behavior," Applied Energy, Elsevier, vol. 162(C), pages 787-807.
    7. Fernández, Ignacio Arias & Gómez, Manuel Romero & Gómez, Javier Romero & Insua, Álvaro Baaliña, 2017. "Review of propulsion systems on LNG carriers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1395-1411.
    8. Adams, T. & Mac Dowell, N., 2016. "Off-design point modelling of a 420MW CCGT power plant integrated with an amine-based post-combustion CO2 capture and compression process," Applied Energy, Elsevier, vol. 178(C), pages 681-702.
    9. Duan, Zhongdi & Wang, Jianhu & Yuan, Yuchao & Tang, Wenyong & Xue, Hongxiang, 2023. "Near-wall thermal regulation for cryogenic storage by adsorbent coating: Modelling and pore-scale investigation," Applied Energy, Elsevier, vol. 349(C).
    10. Kumar, Satish & Kwon, Hyouk-Tae & Choi, Kwang-Ho & Lim, Wonsub & Cho, Jae Hyun & Tak, Kyungjae & Moon, Il, 2011. "LNG: An eco-friendly cryogenic fuel for sustainable development," Applied Energy, Elsevier, vol. 88(12), pages 4264-4273.
    11. Hao, Han & Liu, Zongwei & Zhao, Fuquan & Li, Weiqi, 2016. "Natural gas as vehicle fuel in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 521-533.
    12. Huerta, Felipe & Vesovic, Velisa, 2019. "A realistic vapour phase heat transfer model for the weathering of LNG stored in large tanks," Energy, Elsevier, vol. 174(C), pages 280-291.
    13. Migliore, Calogero & Salehi, Amin & Vesovic, Velisa, 2017. "A non-equilibrium approach to modelling the weathering of stored Liquefied Natural Gas (LNG)," Energy, Elsevier, vol. 124(C), pages 684-692.
    14. Viebahn, Peter & Vallentin, Daniel & Höller, Samuel, 2014. "Prospects of carbon capture and storage (CCS) in India’s power sector – An integrated assessment," Applied Energy, Elsevier, vol. 117(C), pages 62-75.
    15. Dai, C. & Cai, Y.P. & Li, Y.P. & Sun, W. & Wang, X.W. & Guo, H.C., 2014. "Optimal strategies for carbon capture, utilization and storage based on an inexact mλ-measure fuzzy chance-constrained programming," Energy, Elsevier, vol. 78(C), pages 465-478.
    16. Marques, C.H. & Belchior, C.R.P. & Caprace, J.-D., 2018. "Optimising the engine-propeller matching for a liquefied natural gas carrier under rough weather," Applied Energy, Elsevier, vol. 232(C), pages 187-196.
    17. Thiel, Christian & Nijs, Wouter & Simoes, Sofia & Schmidt, Johannes & van Zyl, Arnold & Schmid, Erwin, 2016. "The impact of the EU car CO2 regulation on the energy system and the role of electro-mobility to achieve transport decarbonisation," Energy Policy, Elsevier, vol. 96(C), pages 153-166.
    18. Thiaucourt, Jonas & Marty, Pierre & Hetet, Jean-François, 2020. "Impact of natural gas quality on engine performances during a voyage using a thermodynamic fuel system model," Energy, Elsevier, vol. 197(C).
    19. Cai, W. & Singham, D.I. & Craparo, E.M. & White, J.A., 2014. "Pricing Contracts Under Uncertainty in a Carbon Capture and Storage Framework," Energy Economics, Elsevier, vol. 43(C), pages 56-62.
    20. Khan, Muhammad Imran & Shahrestani, Mehdi & Hayat, Tasawar & Shakoor, Abdul & Vahdati, Maria, 2019. "Life cycle (well-to-wheel) energy and environmental assessment of natural gas as transportation fuel in Pakistan," Applied Energy, Elsevier, vol. 242(C), pages 1738-1752.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:91:y:2015:i:c:p:772-781. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.