IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v88y2015icp377-384.html
   My bibliography  Save this article

Microbial electrolysis cells with polyaniline/multi-walled carbon nanotube-modified biocathodes

Author

Listed:
  • Chen, Yingwen
  • Xu, Yuan
  • Chen, Liuliu
  • Li, Peiwen
  • Zhu, Shemin
  • Shen, Shubao

Abstract

In this paper, we modified biocathodes with PANI (Polyaniline)/MWCNT (Multi-Walled Carbon Nanotube) composites to improve hydrogen production in single-chamber, membrane-free biocathode MECs. The results showed that the hydrogen production rates increased with an increase in applied voltage. At an applied voltage of 0.9 V, the modified biocathode MECs achieved a hydrogen production rate of 0.67m3m−3d−1, current density of 205 Am−3, COD of 86.8%, coulombic efficiency of 72%, cathodic hydrogen recovery of 42%, and energy efficiency of 81% with respect to the electrical power input. LSV (Linear Sweep Voltammetry) scans, SEM (Scanning Electron Microscopy) images and DGGE (Denaturing Gradient Gel Electrophoresis) demonstrated that hydrogen production is catalyzed by the special biofilm attached on a modified biocathode, and the microorganism species and quantity present were significantly different between the modified biocathode and the non-modified biocathode. In general, the performance of MECs with modified biocathodes was improved in the presence of a higher current density and hydrogen generation rate.

Suggested Citation

  • Chen, Yingwen & Xu, Yuan & Chen, Liuliu & Li, Peiwen & Zhu, Shemin & Shen, Shubao, 2015. "Microbial electrolysis cells with polyaniline/multi-walled carbon nanotube-modified biocathodes," Energy, Elsevier, vol. 88(C), pages 377-384.
    • Handle: RePEc:eee:energy:v:88:y:2015:i:c:p:377-384
    DOI: 10.1016/j.energy.2015.05.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215006386
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.05.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Seul-Yi & Kim, Ji-Il & Park, Soo-Jin, 2014. "Activated carbon nanotubes/polyaniline composites as supercapacitor electrodes," Energy, Elsevier, vol. 78(C), pages 298-303.
    2. Hidalgo, Diana & Tommasi, Tonia & Cauda, Valentina & Porro, Samuele & Chiodoni, Angelica & Bejtka, Katarzyna & Ruggeri, Bernardo, 2014. "Streamlining of commercial Berl saddles: A new material to improve the performance of microbial fuel cells," Energy, Elsevier, vol. 71(C), pages 615-623.
    3. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    4. Schenk, Niels J. & Moll, Henri C. & Potting, José & Benders, René M.J., 2007. "Wind energy, electricity, and hydrogen in the Netherlands," Energy, Elsevier, vol. 32(10), pages 1960-1971.
    5. Oliveira, V.B. & Simões, M. & Melo, L.F. & Pinto, A.M.F.R., 2013. "A 1D mathematical model for a microbial fuel cell," Energy, Elsevier, vol. 61(C), pages 463-471.
    6. Guo, L.J. & Zhao, L. & Jing, D.W. & Lu, Y.J. & Yang, H.H. & Bai, B.F. & Zhang, X.M. & Ma, L.J. & Wu, X.M., 2010. "Reprint of: Solar hydrogen production and its development in China," Energy, Elsevier, vol. 35(11), pages 4421-4438.
    7. Neef, H.-J., 2009. "International overview of hydrogen and fuel cell research," Energy, Elsevier, vol. 34(3), pages 327-333.
    8. Ghasemi, Mostafa & Ismail, Manal & Kamarudin, Siti Kartom & Saeedfar, Kasra & Daud, Wan Ramli Wan & Hassan, Sedky H.A. & Heng, Lee Yook & Alam, Javed & Oh, Sang-Eun, 2013. "Carbon nanotube as an alternative cathode support and catalyst for microbial fuel cells," Applied Energy, Elsevier, vol. 102(C), pages 1050-1056.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ortiz-Martínez, V.M. & Salar-García, M.J. & Touati, K. & Hernández-Fernández, F.J. & de los Ríos, A.P. & Belhoucine, F. & Berrabbah, A. Alioua, 2016. "Assessment of spinel-type mixed valence Cu/Co and Ni/Co-based oxides for power production in single-chamber microbial fuel cells," Energy, Elsevier, vol. 113(C), pages 1241-1249.
    2. Khan, M.Z. & Nizami, A.S. & Rehan, M. & Ouda, O.K.M. & Sultana, S. & Ismail, I.M. & Shahzad, K., 2017. "Microbial electrolysis cells for hydrogen production and urban wastewater treatment: A case study of Saudi Arabia," Applied Energy, Elsevier, vol. 185(P1), pages 410-420.
    3. Bajracharya, Suman & Sharma, Mohita & Mohanakrishna, Gunda & Dominguez Benneton, Xochitl & Strik, David P.B.T.B. & Sarma, Priyangshu M. & Pant, Deepak, 2016. "An overview on emerging bioelectrochemical systems (BESs): Technology for sustainable electricity, waste remediation, resource recovery, chemical production and beyond," Renewable Energy, Elsevier, vol. 98(C), pages 153-170.
    4. Shahid, Kanwal & Ramasamy, Deepika Lakshmi & Haapasaari, Sampo & Sillanpää, Mika & Pihlajamäki, Arto, 2021. "Stainless steel and carbon brushes as high-performance anodes for energy production and nutrient recovery using the microbial nutrient recovery system," Energy, Elsevier, vol. 233(C).
    5. Kadier, Abudukeremu & Kalil, Mohd Sahaid & Abdeshahian, Peyman & Chandrasekhar, K. & Mohamed, Azah & Azman, Nadia Farhana & Logroño, Washington & Simayi, Yibadatihan & Hamid, Aidil Abdul, 2016. "Recent advances and emerging challenges in microbial electrolysis cells (MECs) for microbial production of hydrogen and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 501-525.
    6. Merabet, Nour Hane & Kerboua, Kaouther & Hoinkis, Jan, 2024. "Hydrogen production from wastewater: A comprehensive review of conventional and solar powered technologies," Renewable Energy, Elsevier, vol. 226(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohammadi, Amin & Mehrpooya, Mehdi, 2018. "A comprehensive review on coupling different types of electrolyzer to renewable energy sources," Energy, Elsevier, vol. 158(C), pages 632-655.
    2. Ortiz-Martínez, V.M. & Salar-García, M.J. & Hernández-Fernández, F.J. & de los Ríos, A.P., 2015. "Development and characterization of a new embedded ionic liquid based membrane-cathode assembly for its application in single chamber microbial fuel cells," Energy, Elsevier, vol. 93(P2), pages 1748-1757.
    3. Kolb, Sebastian & Plankenbühler, Thomas & Frank, Jonas & Dettelbacher, Johannes & Ludwig, Ralf & Karl, Jürgen & Dillig, Marius, 2021. "Scenarios for the integration of renewable gases into the German natural gas market – A simulation-based optimisation approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    5. Liu, Wen & Hu, Weihao & Lund, Henrik & Chen, Zhe, 2013. "Electric vehicles and large-scale integration of wind power – The case of Inner Mongolia in China," Applied Energy, Elsevier, vol. 104(C), pages 445-456.
    6. Díaz-González, Francisco & Sumper, Andreas & Gomis-Bellmunt, Oriol & Villafáfila-Robles, Roberto, 2012. "A review of energy storage technologies for wind power applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2154-2171.
    7. Pöschl, Martina & Ward, Shane & Owende, Philip, 2010. "Evaluation of energy efficiency of various biogas production and utilization pathways," Applied Energy, Elsevier, vol. 87(11), pages 3305-3321, November.
    8. Bossink, Bart A.G., 2017. "Demonstrating sustainable energy: A review based model of sustainable energy demonstration projects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1349-1362.
    9. Rabiee, Abdorreza & Khorramdel, Hossein & Aghaei, Jamshid, 2013. "A review of energy storage systems in microgrids with wind turbines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 316-326.
    10. Leong, Jun Xing & Daud, Wan Ramli Wan & Ghasemi, Mostafa & Liew, Kien Ben & Ismail, Manal, 2013. "Ion exchange membranes as separators in microbial fuel cells for bioenergy conversion: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 575-587.
    11. Theofilos Kamperidis & Asimina Tremouli & Antonis Peppas & Gerasimos Lyberatos, 2022. "A 2D Modelling Approach for Predicting the Response of a Two-Chamber Microbial Fuel Cell to Substrate Concentration and Electrolyte Conductivity Changes," Energies, MDPI, vol. 15(4), pages 1-15, February.
    12. Bellekom, Sandra & Benders, René & Pelgröm, Steef & Moll, Henk, 2012. "Electric cars and wind energy: Two problems, one solution? A study to combine wind energy and electric cars in 2020 in The Netherlands," Energy, Elsevier, vol. 45(1), pages 859-866.
    13. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    14. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Sang, Shengtian & Liu, Xiaowei, 2016. "Systemic modeling and analysis of DMFC stack for behavior prediction in system-level application," Energy, Elsevier, vol. 112(C), pages 1015-1023.
    15. Wang, Yun-Hai & Wang, Bai-Shi & Pan, Bin & Chen, Qing-Yun & Yan, Wei, 2013. "Electricity production from a bio-electrochemical cell for silver recovery in alkaline media," Applied Energy, Elsevier, vol. 112(C), pages 1337-1341.
    16. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    17. Sona Kazemi & Melissa Barazandegan & Madjid Mohseni & Khalid Fatih, 2016. "Systematic Study of Separators in Air-Breathing Flat-Plate Microbial Fuel Cells—Part 2: Numerical Modeling," Energies, MDPI, vol. 9(2), pages 1-16, January.
    18. Christinelli, W.A. & da Trindade, L.G. & Trench, A.B. & Quintans, C.S. & Paranhos, C.M. & Pereira, E.C., 2017. "High-performance energy storage of poly (o-methoxyaniline) film using an ionic liquid as electrolyte," Energy, Elsevier, vol. 141(C), pages 1829-1835.
    19. Shih-Chieh Huang & Shang-Lien Lo & Yen-Ching Lin, 2013. "To Re-Explore the Causality between Barriers to Renewable Energy Development: A Case Study of Wind Energy," Energies, MDPI, vol. 6(9), pages 1-24, August.
    20. Lin, Kuang C. & Lin, Yuan-Chung & Hsiao, Yi-Hsing, 2014. "Microwave plasma studies of Spirulina algae pyrolysis with relevance to hydrogen production," Energy, Elsevier, vol. 64(C), pages 567-574.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:88:y:2015:i:c:p:377-384. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.