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Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method

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  • Boyacı San, Fatma Gül
  • Okur, Osman
  • İyigün Karadağ, Çiğdem
  • Isik-Gulsac, Isil
  • Okumuş, Emin

Abstract

Borohydride has been considered as a potential fuel for the fuel cell application due to its high energy density. A DBFC (direct borohydride fuel cell) is an electrochemical device that converts chemical energy stored in borohydride and oxidant directly to electrical energy as long as the fuel and oxidant is supplied. One of the main problems encountered in a DBFC is the simultaneous hydrolysis of BH4− at the anode surface. The hydrolysis decreases the fuel utilization and fuel cell performance, since hydrogen bubbles hinder the contact of catalyst with reactant. This study investigates the effect of operating conditions (cell temperature, borohydride concentration, flow rates of fuel and oxidant) on DBFC performance by RSM (response surface methodology). PtRu/C is used as the anode catalyst to systematically investigate the effect of hydrogen evolution rate on the fuel cell performance. The maximum power density is obtained at 80 °C fuel cell temperature, 0.5 M NaBH4 concentration, 5 cm3 min−1 flow of anolyte and 100 cm3 min−1 flow of oxygen.

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  • Boyacı San, Fatma Gül & Okur, Osman & İyigün Karadağ, Çiğdem & Isik-Gulsac, Isil & Okumuş, Emin, 2014. "Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method," Energy, Elsevier, vol. 71(C), pages 160-169.
    • Handle: RePEc:eee:energy:v:71:y:2014:i:c:p:160-169
    DOI: 10.1016/j.energy.2014.04.037
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    2. Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.
    3. Zohdi-Fasaei, Hossein & Atashi, Hossein & Farshchi Tabrizi, Farshad & Mirzaei, Ali Akbar, 2017. "Modeling and optimization of Fischer-Tropsch synthesis over Co-Mn-Ce/SiO2 catalyst using hybrid RSM/LHHW approaches," Energy, Elsevier, vol. 128(C), pages 496-508.
    4. Najafi, Gholamhassan & Ghobadian, Barat & Yusaf, Talal & Safieddin Ardebili, Seyed Mohammad & Mamat, Rizalman, 2015. "Optimization of performance and exhaust emission parameters of a SI (spark ignition) engine with gasoline–ethanol blended fuels using response surface methodology," Energy, Elsevier, vol. 90(P2), pages 1815-1829.

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