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Biomass to Syngas: Modified Non-Stoichiometric Thermodynamic Models for the Downdraft Biomass Gasification

Author

Listed:
  • Hafiz Muhammad Uzair Ayub

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

  • Sang Jin Park

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

  • Michael Binns

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

Abstract

Biomass gasification is the most reliable thermochemical conversion technology for the conversion of biomass into gaseous fuels such as H 2 , CO, and CH 4 . The performance of a gasification process can be estimated using thermodynamic equilibrium models. This type of model generally assumes the system reaches equilibrium, while in reality the system may only approach equilibrium leading to some errors between experimental and model results. In this study non-stoichiometric equilibrium models are modified and improved with correction factors inserted into the design equations so that when the Gibbs free energy is minimized model predictions will more closely match experimental values. The equilibrium models are implemented in MatLab and optimized based on experimental values from the literature using the optimization toolbox. The modified non-stoichiometric models are shown to be more accurate than unmodified models based on the calculated root mean square error values. These models can be applied for various types of solid biomass for the production of syngas through biomass gasification processes such as wood, agricultural, and crop residues.

Suggested Citation

  • Hafiz Muhammad Uzair Ayub & Sang Jin Park & Michael Binns, 2020. "Biomass to Syngas: Modified Non-Stoichiometric Thermodynamic Models for the Downdraft Biomass Gasification," Energies, MDPI, vol. 13(21), pages 1-17, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:21:p:5668-:d:436974
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    References listed on IDEAS

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    1. Michael Binns & Hafiz Muhammad Uzair Ayub, 2021. "Model Reduction Applied to Empirical Models for Biomass Gasification in Downdraft Gasifiers," Sustainability, MDPI, vol. 13(21), pages 1-14, November.
    2. Marco Puglia & Nicolò Morselli & Simone Pedrazzi & Paolo Tartarini & Giulio Allesina & Alberto Muscio, 2021. "Specific and Cumulative Exhaust Gas Emissions in Micro-Scale Generators Fueled by Syngas from Biomass Gasification," Sustainability, MDPI, vol. 13(6), pages 1-13, March.
    3. Jacek Grams, 2022. "Upgrading of Lignocellulosic Biomass to Hydrogen-Rich Gas," Energies, MDPI, vol. 16(1), pages 1-5, December.
    4. María Pilar González-Vázquez & Fernando Rubiera & Covadonga Pevida & Daniel T. Pio & Luís A.C. Tarelho, 2021. "Thermodynamic Analysis of Biomass Gasification Using Aspen Plus: Comparison of Stoichiometric and Non-Stoichiometric Models," Energies, MDPI, vol. 14(1), pages 1-17, January.
    5. Zhang, Jinchun & Hou, Jinxiu & Zhang, Zichuan, 2022. "Real-time identification of out-of-control and instability in process parameter for gasification process: Integrated application of control chart and kalman filter," Energy, Elsevier, vol. 238(PB).
    6. Mohd Zeeshan & Rohan R. Pande & Purnanand V. Bhale, 2024. "A modeling study for the gasification of refuse-derived fuel as an alternative to waste disposal," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 26(9), pages 23985-24008, September.
    7. Silva, Isabelly P. & Lima, Rafael M.A. & Santana, Hortência E.P. & Silva, Gabriel F. & Ruzene, Denise S. & Silva, Daniel P., 2022. "Development of a semi-empirical model for woody biomass gasification based on stoichiometric thermodynamic equilibrium model," Energy, Elsevier, vol. 241(C).
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    9. Valentina Segneri & Jean Henry Ferrasse & Antonio Trinca & Giorgio Vilardi, 2022. "An Overview of Waste Gasification and Syngas Upgrading Processes," Energies, MDPI, vol. 15(17), pages 1-7, September.
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    11. M. Shahabuddin & Sankar Bhattacharya, 2021. "Co-Gasification Characteristics of Coal and Biomass Using CO 2 Reactant under Thermodynamic Equilibrium Modelling," Energies, MDPI, vol. 14(21), pages 1-12, November.

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