IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v113y2016icp1090-1098.html
   My bibliography  Save this article

Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions

Author

Listed:
  • Alipour Najmi, Ali
  • Rowshanzamir, Soosan
  • Parnian, Mohammad Javad

Abstract

Direct methanol alkaline fuel cell (DMAFC) using a cation exchange membrane (CEM) was operated in passive condition and compared to passive direct methanol fuel cell (DMFC). A polymer electrolyte membrane for passive DMAFC was prepared by immersing Nafion117 membrane into KOH solution at temperature of 80 °C. The prepared membrane (potassium-doped Nafion117) exhibited higher mechanical properties and thermal stability than Nafion117. Ionic conductivity of K+ form Nafion117 membrane was measured to be lower than that for pristine Nafion117. Single cell in alkaline condition (passive DMAFC) exhibited better cell performance than that in the cell using Nafion117 in acidic condition (passive DMFC). The open circuit voltage (OCV) of passive DMAFC reached to about 1 V which was considerably higher than that for passive DMFC (0.45 V). The methanol crossover rate through membranes was also measured and the results implied that the potassium-doped Nafion117 membrane had lower permeability to methanol.

Suggested Citation

  • Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    • Handle: RePEc:eee:energy:v:113:y:2016:i:c:p:1090-1098
    DOI: 10.1016/j.energy.2016.07.134
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216310581
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.07.134?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yuan, Wei & Deng, Jun & Zhang, Zhaochun & Yang, Xiaojun & Tang, Yong, 2014. "Study on operational aspects of a passive direct methanol fuel cell incorporating an anodic methanol barrier," Renewable Energy, Elsevier, vol. 62(C), pages 640-648.
    2. Achmad, F. & Kamarudin, S.K. & Daud, W.R.W. & Majlan, E.H., 2011. "Passive direct methanol fuel cells for portable electronic devices," Applied Energy, Elsevier, vol. 88(5), pages 1681-1689, May.
    3. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    4. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    5. Döner, Ali & Solmaz, Ramazan & Kardaş, Gülfeza, 2015. "Fabrication and characterization of alkaline leached CuZn/Cu electrode as anode material for direct methanol fuel cell," Energy, Elsevier, vol. 90(P1), pages 1144-1151.
    6. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    7. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.
    8. Deng, Huichao & Zhang, Yufeng & Zheng, Xue & Li, Yang & Zhang, Xuelin & Liu, Xiaowei, 2015. "A CNT (carbon nanotube) paper as cathode gas diffusion electrode for water management of passive μ-DMFC (micro-direct methanol fuel cell) with highly concentrated methanol," Energy, Elsevier, vol. 82(C), pages 236-241.
    9. Iranzo, Alfredo & Boillat, Pierre & Oberholzer, Pierre & Guerra, José, 2014. "A novel approach coupling neutron imaging and numerical modelling for the analysis of the impact of water on fuel cell performance," Energy, Elsevier, vol. 68(C), pages 971-981.
    10. Deng, Huichao & Zhang, Xuelin & Ma, Zezhong & Chen, Hailong & Sun, Qiu & Zhang, Yufeng & Liu, Xiaowei, 2014. "A micro passive direct methanol fuel cell with high performance via plasma electrolytic oxidation on aluminum-based substrate," Energy, Elsevier, vol. 78(C), pages 149-153.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Prapainainar, Paweena & Du, Zehui & Theampetch, Apichaya & Prapainainar, Chaiwat & Kongkachuichay, Paisan & Holmes, Stuart M., 2020. "Properties and DMFC performance of nafion/mordenite composite membrane fabricated by solution-casting method with different solvent ratio," Energy, Elsevier, vol. 190(C).
    2. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    3. Hosseini, Mir Ghasem & Mahmoodi, Raana & Daneshvari-Esfahlan, Vahid, 2018. "Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated m," Energy, Elsevier, vol. 161(C), pages 1074-1084.
    4. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    2. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    3. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    4. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    5. Deng, Huichao & Zhang, Yufeng & Zheng, Xue & Li, Yang & Zhang, Xuelin & Liu, Xiaowei, 2015. "A CNT (carbon nanotube) paper as cathode gas diffusion electrode for water management of passive μ-DMFC (micro-direct methanol fuel cell) with highly concentrated methanol," Energy, Elsevier, vol. 82(C), pages 236-241.
    6. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    7. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.
    8. Oh, Taek Hyun & Jang, Bosun & Kwon, Sejin, 2015. "Estimating the energy density of direct borohydride–hydrogen peroxide fuel cell systems for air-independent propulsion applications," Energy, Elsevier, vol. 90(P1), pages 980-986.
    9. Xue, Rui & Zhang, Yufeng & Liu, Xiaowei, 2017. "A novel cathode gas diffusion layer for water management of passive μ-DMFC," Energy, Elsevier, vol. 139(C), pages 535-541.
    10. Arlt, Tobias & Klages, Merle & Messerschmidt, Matthias & Scholta, Joachim & Manke, Ingo, 2017. "Influence of artificially aged gas diffusion layers on the water management of polymer electrolyte membrane fuel cells analyzed with in-operando synchrotron imaging," Energy, Elsevier, vol. 118(C), pages 502-511.
    11. Iranzo, Alfredo & Boillat, Pierre & Biesdorf, Johannes & Salva, Antonio, 2015. "Investigation of the liquid water distributions in a 50 cm2 PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry," Energy, Elsevier, vol. 82(C), pages 914-921.
    12. Wang, Luwen & Yuan, Zhaoxia & Wen, Fei & Cheng, Yuhua & Zhang, Yufeng & Wang, Gaofeng, 2018. "A bipolar passive DMFC stack for portable applications," Energy, Elsevier, vol. 144(C), pages 587-593.
    13. Yuan, Zhenyu & Yang, Jie & Li, Zipeng & Sun, Yuge & Ye, Ning & Shen, Hongyuan, 2015. "Analysis of CO2 transmission in a micro direct methanol fuel cell," Energy, Elsevier, vol. 83(C), pages 496-502.
    14. Yin, Cong & Gao, Jianlong & Wen, Xuhui & Xie, Guangyou & Yang, Chunhua & Fang, Honglin & Tang, Hao, 2016. "In situ investigation of proton exchange membrane fuel cell performance with novel segmented cell design and a two-phase flow model," Energy, Elsevier, vol. 113(C), pages 1071-1089.
    15. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    16. Salva, J. Antonio & Iranzo, Alfredo & Rosa, Felipe & Tapia, Elvira, 2016. "Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions," Energy, Elsevier, vol. 101(C), pages 100-112.
    17. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    18. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    19. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Sang, Shengtian & Liu, Xiaowei, 2016. "Systemic modeling and analysis of DMFC stack for behavior prediction in system-level application," Energy, Elsevier, vol. 112(C), pages 1015-1023.
    20. Xu, Liangfei & Fang, Chuan & Hu, Junming & Cheng, Siliang & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2017. "Parameter extraction of polymer electrolyte membrane fuel cell based on quasi-dynamic model and periphery signals," Energy, Elsevier, vol. 122(C), pages 675-690.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:113:y:2016:i:c:p:1090-1098. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.