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The hydrogen storage properties of MgH2–Fe3S4 composites

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  • Zhang, Wei
  • Cheng, Ying
  • Han, Da
  • Han, Shumin

Abstract

We report here a method of synthesizing MgH2–Fe3S4 composite with a series of remarkable hydrogen storage properties. For instance, compared to pure MgH2, three times higher hydrogen absorption weight (3.41 wt.% vs 0.98%) and two times faster hydrogen desorption rate (4.01 wt.% vs 2.32 wt.%) are seen in MgH2–Fe3S4 composite. Furthermore, the dehydrogenation temperature of MgH2 is also found to be reduced by 90 K with the addition of Fe3S4. By studying the reactions between MgH2 and Fe3S4 during the hydrogenation/dehydrogenation process, we found the formation of new phases (Fe and MgS) as well as their coordination play a remarkable effect on improving the hydrogen storage properties of MgH2.

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  • Zhang, Wei & Cheng, Ying & Han, Da & Han, Shumin, 2015. "The hydrogen storage properties of MgH2–Fe3S4 composites," Energy, Elsevier, vol. 93(P1), pages 625-630.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p1:p:625-630
    DOI: 10.1016/j.energy.2015.09.080
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    1. Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    2. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    3. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
    4. Ismail, M., 2015. "Effect of LaCl3 addition on the hydrogen storage properties of MgH2," Energy, Elsevier, vol. 79(C), pages 177-182.
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    1. El-Eskandarany, M. Sherif & Shaban, Ehab & Alsairafi, Ammar A., 2016. "Synergistic dosing effect of TiC/FeCr nanocatalysts on the hydrogenation/dehydrogenation kinetics of nanocrystalline MgH2 powders," Energy, Elsevier, vol. 104(C), pages 158-170.
    2. Wang, Peng & Wang, Zexuan & Tian, Zhihui & Xia, Chaoqun & Yang, Tai & Liang, Chunyong & Li, Qiang, 2020. "Enhanced hydrogen absorption and desorption properties of MgH2 with NiS2: The catalytic effect of in-situ formed MgS and Mg2NiH4 phases," Renewable Energy, Elsevier, vol. 160(C), pages 409-417.
    3. Dou, Binlin & Zhang, Hua & Cui, Guomin & He, Mingxing & Ruan, Chenjie & Wang, Zilong & Chen, Haisheng & Xu, Yujie & Jiang, Bo & Wu, Chunfei, 2019. "Hydrogen sorption and desorption behaviors of Mg-Ni-Cu doped carbon nanotubes at high temperature," Energy, Elsevier, vol. 167(C), pages 1097-1106.
    4. Yang, Tai & Wang, Peng & Li, Qiang & Xia, Chaoqun & Yin, Fuxing & Liang, Chunyong & Zhang, Yanghuan, 2018. "Hydrogen absorption and desorption behavior of Ni catalyzed Mg–Y–C–Ni nanocomposites," Energy, Elsevier, vol. 165(PA), pages 709-719.
    5. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.

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    Keywords

    Fe3S4; Magnesium hydride; Hydrogen storage kinetics;
    All these keywords.

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