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A wide range kinetic modeling study of pyrolysis and oxidation of methyl butanoate and methyl decanoate. Note I: Lumped kinetic model of methyl butanoate and small methyl esters

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  • Grana, Roberto
  • Frassoldati, Alessio
  • Cuoci, Alberto
  • Faravelli, Tiziano
  • Ranzi, Eliseo

Abstract

A lumped kinetic model of methyl butanoate pyrolysis and oxidation is presented and discussed in this work. The hierarchical approach first required the development and validation of sub-mechanisms of small esters such as methyl formate, methyl acrylate and methyl crotonate. A broad-ranging validation of the whole kinetic scheme of methyl butanoate oxidation was then carried out through comparisons with experimental data obtained in shock tube devices, plug flow and jet stirred reactors, rapid compression machines and premixed laminar flames. A detailed analysis of laminar flame speeds complements and extends this kinetic study. The lumped model predicts a wide range of experiments well, thus constituting a flexible and reliable kinetic scheme despite the reduced number of species involved. Moreover, this lumped approach and the proposed model lay the foundation for an extension to biodiesel fuel modeling.

Suggested Citation

  • Grana, Roberto & Frassoldati, Alessio & Cuoci, Alberto & Faravelli, Tiziano & Ranzi, Eliseo, 2012. "A wide range kinetic modeling study of pyrolysis and oxidation of methyl butanoate and methyl decanoate. Note I: Lumped kinetic model of methyl butanoate and small methyl esters," Energy, Elsevier, vol. 43(1), pages 124-139.
    • Handle: RePEc:eee:energy:v:43:y:2012:i:1:p:124-139
    DOI: 10.1016/j.energy.2012.01.044
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    1. Rashid, Umer & Rehman, Hafiz Abdul & Hussain, Irshad & Ibrahim, Muhammad & Haider, Muhammad Sajjad, 2011. "Muskmelon (Cucumis melo) seed oil: A potential non-food oil source for biodiesel production," Energy, Elsevier, vol. 36(9), pages 5632-5639.
    2. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Blends of biodiesels synthesized from non-edible and edible oils: Influence on the OS (oxidation stability)," Energy, Elsevier, vol. 35(8), pages 3449-3453.
    3. Tsolakis, A. & Megaritis, A. & Yap, D., 2008. "Application of exhaust gas fuel reforming in diesel and homogeneous charge compression ignition (HCCI) engines fuelled with biofuels," Energy, Elsevier, vol. 33(3), pages 462-470.
    4. Chen, Yi-Hung & Chen, Jhih-Hong & Luo, Yu-Min & Shang, Neng-Chou & Chang, Cheng-Hsin & Chang, Ching-Yuan & Chiang, Pen-Chi & Shie, Je-Lueng, 2011. "Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants," Energy, Elsevier, vol. 36(7), pages 4415-4421.
    5. Muralidharan, K. & Vasudevan, D., 2011. "Performance, emission and combustion characteristics of a variable compression ratio engine using methyl esters of waste cooking oil and diesel blends," Applied Energy, Elsevier, vol. 88(11), pages 3959-3968.
    6. Shuping, Zou & Yulong, Wu & Mingde, Yang & Kaleem, Imdad & Chun, Li & Tong, Junmao, 2010. "Production and characterization of bio-oil from hydrothermal liquefaction of microalgae Dunaliella tertiolecta cake," Energy, Elsevier, vol. 35(12), pages 5406-5411.
    7. Muralidharan, K. & Vasudevan, D. & Sheeba, K.N., 2011. "Performance, emission and combustion characteristics of biodiesel fuelled variable compression ratio engine," Energy, Elsevier, vol. 36(8), pages 5385-5393.
    8. Tsolakis, A. & Megaritis, A. & Wyszynski, M.L. & Theinnoi, K., 2007. "Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation)," Energy, Elsevier, vol. 32(11), pages 2072-2080.
    9. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K. & Kundu, K., 2009. "Effect of blends of Palm-Jatropha-Pongamia biodiesels on cloud point and pour point," Energy, Elsevier, vol. 34(11), pages 2016-2021.
    10. Haik, Yousef & Selim, Mohamed Y.E. & Abdulrehman, Tahir, 2011. "Combustion of algae oil methyl ester in an indirect injection diesel engine," Energy, Elsevier, vol. 36(3), pages 1827-1835.
    11. Satyanarayana, M. & Muraleedharan, C., 2011. "A comparative study of vegetable oil methyl esters (biodiesels)," Energy, Elsevier, vol. 36(4), pages 2129-2137.
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    1. Li, Chong & Zhang, Zhenpeng & He, Li & Ye, Mingzhi & Ning, Hongbo & Shang, Yanlei & Shi, Jinchun & Luo, Sheng-Nian, 2022. "Experimental and kinetic modeling study on the ignition characteristics of methyl acrylate and vinyl acetate: Effect of CC double bond," Energy, Elsevier, vol. 245(C).

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