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Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process

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  • Burdyny, Thomas
  • Struchtrup, Henning

Abstract

The process of oxy-fuel combustion requires the separation of oxygen from air on a large scale for use in the combustion chamber. This separation is currently done through energy intensive cryogenic distillation. To reduce the overall energy requirements for air separation it is examined whether a hybrid membrane and cryogenic process be utilized instead. The examined process uses an O2/N2 permeable membrane to create oxygen enriched air. This enriched air is then turned into high purity oxygen using cryogenic distillation. Several arrangements of such a system are investigated and compared on a practical and thermodynamic level to the current cryogenic process in use. It is found that using a vacuum pump arrangement to draw air through the membrane has potential to reduce energy requirements from the current standard. It is also found that the hybrid system is more productive in small to medium scale applications than in large scale applications because of the increased irreversibilities in the cryogenic process at smaller scales.

Suggested Citation

  • Burdyny, Thomas & Struchtrup, Henning, 2010. "Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process," Energy, Elsevier, vol. 35(5), pages 1884-1897.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:5:p:1884-1897
    DOI: 10.1016/j.energy.2009.12.033
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    References listed on IDEAS

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    6. Hashim, S.S. & Mohamed, A.R. & Bhatia, S., 2011. "Oxygen separation from air using ceramic-based membrane technology for sustainable fuel production and power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1284-1293, February.
    7. Tao, Ye & Tian, Wende & Kong, Lingqi & Sun, Suli & Fan, Chenyang, 2022. "Energy, exergy, economic, environmental (4E) and dynamic analysis based global optimization of chemical looping air separation for oxygen and power co-production," Energy, Elsevier, vol. 261(PB).
    8. Zonouz, Masood Jalali & Mehrpooya, Mehdi, 2017. "Parametric study of a hybrid one column air separation unit (ASU) and CO2 power cycle based on advanced exergy cost analysis results," Energy, Elsevier, vol. 140(P1), pages 261-275.
    9. Leung, Dennis Y.C. & Caramanna, Giorgio & Maroto-Valer, M. Mercedes, 2014. "An overview of current status of carbon dioxide capture and storage technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 426-443.
    10. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    11. Paweł Ziółkowski & Stanisław Głuch & Piotr Józef Ziółkowski & Janusz Badur, 2022. "Compact High Efficiency and Zero-Emission Gas-Fired Power Plant with Oxy-Combustion and Carbon Capture," Energies, MDPI, vol. 15(7), pages 1-39, April.
    12. Meriläinen, Arttu & Seppälä, Ari & Kauranen, Pertti, 2012. "Minimizing specific energy consumption of oxygen enrichment in polymeric hollow fiber membrane modules," Applied Energy, Elsevier, vol. 94(C), pages 285-294.
    13. Mehrpooya, Mehdi & Moftakhari Sharifzadeh, Mohammad Mehdi & Rosen, Marc A., 2015. "Optimum design and exergy analysis of a novel cryogenic air separation process with LNG (liquefied natural gas) cold energy utilization," Energy, Elsevier, vol. 90(P2), pages 2047-2069.
    14. Chu-Yun Cheng & Chia-Chen Kuo & Ming-Wei Yang & Zong-Yu Zhuang & Po-Wei Lin & Yi-Fang Chen & Hong-Sung Yang & Cheng-Tung Chou, 2021. "CO 2 Capture from Flue Gas of a Coal-Fired Power Plant Using Three-Bed PSA Process," Energies, MDPI, vol. 14(12), pages 1-15, June.
    15. Habib, Mohamed A. & Nemitallah, Medhat A. & Afaneh, Dia' Al-deen, 2018. "Numerical investigation of a hybrid polymeric-ceramic membrane unit for carbon-free oxy-combustion applications," Energy, Elsevier, vol. 147(C), pages 362-376.
    16. Fu, Chao & Gundersen, Truls, 2012. "Using exergy analysis to reduce power consumption in air separation units for oxy-combustion processes," Energy, Elsevier, vol. 44(1), pages 60-68.
    17. Rahaman, Muhammad Syukri Abd & Cheng, Li-Hua & Xu, Xin-Hua & Zhang, Lin & Chen, Huan-Lin, 2011. "A review of carbon dioxide capture and utilization by membrane integrated microalgal cultivation processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4002-4012.
    18. Cao, Yang & He, Boshu & Ding, Guangchao & Su, Liangbin & Duan, Zhipeng, 2017. "Energy and exergy investigation on two improved IGCC power plants with different CO2 capture schemes," Energy, Elsevier, vol. 140(P1), pages 47-57.

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