Author
Listed:
- He, Hengyi
- Liu, Peng
- Nie, Baisheng
- Zhao, Yulong
- Wang, Lei
- Liu, Xianfeng
- Deng, Bozhi
- Zhao, Zhengduo
- Zhang, Hao
- Zhao, Dan
- Bao, Song
Abstract
Carbon dioxide (CO2) injection into deep coal seams holds considerable significance in both carbon mitigation and enhanced recovery of clean coalbed methane (CBM). The CO2-coal interaction leads to changes in the physicochemical properties, potentially impacting the stability of the target sequestration coal reservoir. This study applied the nanoindentation, scanning probe microscopy (SPM), X-ray diffraction (XRD), and electron probe X-ray Micro-Analyzer (EPMA) techniques to probe the micromechanical property change and damage mechanism of coal subjected to ScCO2 injection. The result shows that the load-displacement behavior of the tested coal changes with continuous ScCO2 treatment, and the mechanical strength significantly weakens after 4 days of ScCO2 treatment. The nanoindentation test indicates that the peak and creep displacements of tested coal increased by 168.79 % and 1046.32 % respectively with 4-day ScCO2 treatment, inferring that the coal deformation increases and changes from elastic to plastic after ScCO2 injection. As the ScCO2 treatment time increases, Young's modulus and hardness of coal exhibit an exponential decay trend and rapidly decrease by 77.77 %∼89.76 % and 68.37 %∼81.63 % respectively after the initial 3-day treatment, followed by a slow decrease with the ScCO2 duration prolonging. The XRD and EPMA results show that the carbonate minerals reacted preferentially with ScCO2, and silicate minerals experienced gradual dissolution, while the amorphous carbon fluctuated almost unchanged in the tested coal. Carbonate minerals in tested coal have decreased by 70.68 % within the first 1-day ScCO2 treatment, making the most significant contribution to the initial rapid weakening of coal mechanics. The mineral distribution is closely related to the mechanical anisotropy of coal, which is confirmed by the phenomenon that the coal anisotropy gradually weakens with the mineral reaction process. It is inferred that the mineral component and distribution of coal seams are important indicators for evaluating the intensity of physical and chemical reactions in ScCO2-injected reservoirs, which directly determines the mechanical damage behavior of sequestration reservoirs. This research provides basic support for site selection and safety assessment of carbon sequestration in deep coal seams.
Suggested Citation
He, Hengyi & Liu, Peng & Nie, Baisheng & Zhao, Yulong & Wang, Lei & Liu, Xianfeng & Deng, Bozhi & Zhao, Zhengduo & Zhang, Hao & Zhao, Dan & Bao, Song, 2024.
"Micromechanical property evolution and damage mechanism of coal subjected to ScCO2 treatment,"
Energy, Elsevier, vol. 304(C).
Handle:
RePEc:eee:energy:v:304:y:2024:i:c:s0360544224018619
DOI: 10.1016/j.energy.2024.132087
Download full text from publisher
As the access to this document is restricted, you may want to search for a different version of it.
Corrections
All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:304:y:2024:i:c:s0360544224018619. See general information about how to correct material in RePEc.
If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.
We have no bibliographic references for this item. You can help adding them by using this form .
If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.
For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .
Please note that corrections may take a couple of weeks to filter through
the various RePEc services.