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Fine characterization of pore structure of acidified anthracite based on liquid intrusion method and Micro-CT

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  • Yongzan, Wen
  • Guanhua, Ni
  • Xinyue, Zhang
  • Yicheng, Zheng
  • Gang, Wang
  • Zhenyang, Wang
  • Qiming, Huang

Abstract

Acidification erosion can seriously affect the pore structure characteristics of anthracite. In this paper, the low-temperature nitrogen adsorption method, mercury intrusion method, and Micro-CT scanning are used to analyze the pore structure of coal samples. The microscopic morphology and spatial distribution of coal pores are characterized by fractal dimension calculation and three-dimensional reconstruction. The results show that HCl has the highest removal efficiency of minerals in the Yuwu coal sample, which reduces the mass of coal samples by about 4%. HNO3 increases the proportion of micropore volume by 4.93%. HCl increases the proportion of mesoporous pore volume by 11.4%. Through the 3D reconstruction of coal, it is found that the mineral content in coal decreased by 48.14% after HCl dissolution, and the maximum diameter of mineral particles decreased from 173.588 μm to 57.449 μm. The spatial distribution of minerals is uneven, and the mineral content of coal samples decreases significantly along the direction of strong fluidity. At the same time, HCl increases the pore connectivity of coal samples, the pore roar increases by 56.72%, the isolated pores decrease, and the peak frequency of pore coordination number increases by 4 units, which greatly improves the transport capacity of fluid in coal matrix.

Suggested Citation

  • Yongzan, Wen & Guanhua, Ni & Xinyue, Zhang & Yicheng, Zheng & Gang, Wang & Zhenyang, Wang & Qiming, Huang, 2023. "Fine characterization of pore structure of acidified anthracite based on liquid intrusion method and Micro-CT," Energy, Elsevier, vol. 263(PA).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pa:s0360544222025257
    DOI: 10.1016/j.energy.2022.125639
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    1. Guo, Shengli & Yang, Wenwang & Yuan, Shujie & Zhuo Yan, & Geng, Weile, 2022. "Experimental investigation of erosion effect on microstructure and oxidation characteristics of long-flame coal," Energy, Elsevier, vol. 259(C).
    2. Pang, Mingkun & Zhang, Tianjun & Ji, Xiang & Wu, Jinyu & Song, Shuang, 2022. "Measurement of the coefficient of seepage characteristics in pore-crushed coal bodies around gas extraction boreholes," Energy, Elsevier, vol. 254(PA).
    3. Li, Jun & Huang, Qiming & Wang, Gang & Wang, Enmao & Ju, Shuang & Qin, Cunli, 2022. "Experimental study of effect of slickwater fracturing on coal pore structure and methane adsorption," Energy, Elsevier, vol. 239(PE).
    4. Wang, Ziwei & Qin, Yong & Shen, Jian & Li, Teng & Zhang, Xiaoyang & Cai, Ying, 2022. "A novel permeability prediction model for coal based on dynamic transformation of pores in multiple scales," Energy, Elsevier, vol. 257(C).
    5. Chen, Kang & Liu, Xianfeng & Nie, Baisheng & Zhang, Chengpeng & Song, Dazhao & Wang, Longkang & Yang, Tao, 2022. "Mineral dissolution and pore alteration of coal induced by interactions with supercritical CO2," Energy, Elsevier, vol. 248(C).
    6. Geng, Weile & Huang, Gun & Guo, Shengli & Jiang, Changbao & Dong, Ziwen & Wang, Wensong, 2022. "Influence of long-term CH4 and CO2 treatment on the pore structure and mechanical strength characteristics of Baijiao coal," Energy, Elsevier, vol. 242(C).
    7. Liu, Ang & Liu, Shimin, 2022. "Mechanical property alterations across coal matrix due to water-CO2 treatments: A micro-to-nano scale experimental study," Energy, Elsevier, vol. 248(C).
    8. Li, He & Shi, Shiliang & Lin, Baiquan & Lu, Jiexin & Ye, Qing & Lu, Yi & Wang, Zheng & Hong, Yidu & Zhu, Xiangnan, 2019. "Effects of microwave-assisted pyrolysis on the microstructure of bituminous coals," Energy, Elsevier, vol. 187(C).
    9. Sun, Lulu & Zhang, Chen & Wang, Gang & Huang, Qiming & Shi, Quanlin, 2022. "Research on the evolution of pore and fracture structures during spontaneous combustion of coal based on CT 3D reconstruction," Energy, Elsevier, vol. 260(C).
    10. Yan, Min & Zhou, Ming & Li, Shugang & Lin, Haifei & Zhang, Kunyin & Zhang, Binbin & Shu, Chi-Min, 2021. "Numerical investigation on the influence of micropore structure characteristics on gas seepage in coal with lattice Boltzmann method," Energy, Elsevier, vol. 230(C).
    11. Tao, Meng & Jl, Xie & Xm, Li & Jw, Ma & Yang, Yue, 2020. "Experimental study on the evolutional trend of pore structures and fractal dimension of low-rank coal rich clay subjected to a coupled thermo-hydro-mechanical-chemical environment," Energy, Elsevier, vol. 203(C).
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    Cited by:

    1. Liu, Haizhou & Mao, Lingtao & Ju, Yang & Hild, François, 2023. "Damage evolution in coal under different loading modes using advanced digital volume correlation based on X-ray computed tomography," Energy, Elsevier, vol. 275(C).
    2. Cai, Jiawen & Yu, Zhaoyang & Yang, Shengqiang & Tang, Jingxia & Ma, Zhenqian & Xie, Xionggang & Hu, Xincheng, 2023. "Fractal characteristics of coal surface structure during low-temperature oxidation and its effect on oxidizability," Energy, Elsevier, vol. 284(C).

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