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A novel bimetallic CaFe-MOF derivative for transesterification: Catalytic performance, characterization, and stability

Author

Listed:
  • Wang, Tianyu
  • Ma, Xiaoling
  • Bingwa, Ndzondelelo
  • Yu, Hao
  • Wang, Yunpu
  • Li, Guoning
  • Guo, Min
  • Xiao, Qiangqiang
  • Li, Shijie
  • Zhao, Xudong
  • Li, Hui

Abstract

Metal organic frameworks (MOFs) are ideal precursors for the synthesis of catalysts with high surface areas and homogenously distributed active sites. Compared to monometallic MOFs, MOF-on-MOF strategy shows enhanced properties originating from the synergistic interactions between two metals at atomic level. In this study, a bimetallic CaFe-MOF was synthesized and exploited to obtain magnetic CaO catalyst, which was subsequently applied to catalyze transesterification for biodiesel production. The catalysts were characterized with thermogravimetric/derivative thermogravimetric analysis (TG/DTG), X-ray diffraction (XRD), Fourier Transform Infrared spectrometer (FTIR), N2 adsorption-desorption, scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), and Hammett indicator method. The as-synthesized catalysts exhibit excellent catalytic activity of 98.53 % with 6 wt% catalyst amount and 12 methanol/oil molar ratio at 65 °C in 1 h. The synthesized catalyst showed good stability even after 6 recycles with favorable transesterification conversions. Moreover, the as-synthesized catalyst type is highly tolerant to free fatty acid (FFA) and free water (FW), with transesterification conversions of 85.35 % and 86.27 % achieved with the FFA of 9 wt% and FW of 11 wt%, respectively. The physicochemical properties of the obtained biodiesel meet requirements of ASTM D6751 and EN 14214, indicating it can be directly used for transport fuel.

Suggested Citation

  • Wang, Tianyu & Ma, Xiaoling & Bingwa, Ndzondelelo & Yu, Hao & Wang, Yunpu & Li, Guoning & Guo, Min & Xiao, Qiangqiang & Li, Shijie & Zhao, Xudong & Li, Hui, 2024. "A novel bimetallic CaFe-MOF derivative for transesterification: Catalytic performance, characterization, and stability," Energy, Elsevier, vol. 292(C).
    • Handle: RePEc:eee:energy:v:292:y:2024:i:c:s0360544224003153
    DOI: 10.1016/j.energy.2024.130544
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