IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v35y2010i7p1531-1536.html
   My bibliography  Save this article

The nanometer magnetic solid base catalyst for production of biodiesel

Author

Listed:
  • Liu, Chang
  • Lv, Pengmei
  • Yuan, Zhenhong
  • Yan, Fang
  • Luo, Wen

Abstract

Nanometer magnetic solid base catalysts were prepared by loading CaO on Fe3O4 with Na2CO3 and NaOH as precipitator, respectively. The optimum conditions for preparation of this catalyst were investigated. The influence of the proportion of Ca2+ to Fe3O4 on the catalytic performance has been studied. The catalyst with highest catalytic activity has been obtained when the proportion of Ca2+ to Fe3O4 is 7:1; the catalytic activity of the catalyst calcined from Ca(OH)2 to Fe3O4 is better than that calcined from CaCO3 to Fe3O4; under the conditions of methanol/oil molar ratio of 15:1, catalyst dosage of 2wt% and temperature of 70°C, the biodiesel yield reaches to 95% in 80min, even to 99% finally. The catalytic activity and recovery rate of the nanometer magnetic solid base catalysts are much better than those of CaO. Calcination temperature was determined by differential thermogravimetric analysis. Ca2Fe2O5, a kind of new metal multiple oxide, was found in the catalyst through X-ray diffraction. At the end, these catalysts were characterized by scanning electronic microscope (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM).

Suggested Citation

  • Liu, Chang & Lv, Pengmei & Yuan, Zhenhong & Yan, Fang & Luo, Wen, 2010. "The nanometer magnetic solid base catalyst for production of biodiesel," Renewable Energy, Elsevier, vol. 35(7), pages 1531-1536.
    • Handle: RePEc:eee:renene:v:35:y:2010:i:7:p:1531-1536
    DOI: 10.1016/j.renene.2009.10.009
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148109004352
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2009.10.009?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Carraretto, C. & Macor, A. & Mirandola, A. & Stoppato, A. & Tonon, S., 2004. "Biodiesel as alternative fuel: Experimental analysis and energetic evaluations," Energy, Elsevier, vol. 29(12), pages 2195-2211.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Samuel Santos & Luís Nobre & João Gomes & Jaime Puna & Rosa Quinta-Ferreira & João Bordado, 2019. "Soybean Oil Transesterification for Biodiesel Production with Micro-Structured Calcium Oxide (CaO) from Natural Waste Materials as a Heterogeneous Catalyst," Energies, MDPI, vol. 12(24), pages 1-10, December.
    2. Teuku Meurah Indra Riayatsyah & Hwai Chyuan Ong & Wen Tong Chong & Lisa Aditya & Heri Hermansyah & Teuku Meurah Indra Mahlia, 2017. "Life Cycle Cost and Sensitivity Analysis of Reutealis trisperma as Non-Edible Feedstock for Future Biodiesel Production," Energies, MDPI, vol. 10(7), pages 1-21, June.
    3. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    4. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    5. Vardast, Neda & Haghighi, Mohammad & Dehghani, Sahar, 2019. "Sono-dispersion of calcium over Al-MCM-41used as a nanocatalyst for biodiesel production from sunflower oil: Influence of ultrasound irradiation and calcium content on catalytic properties and perform," Renewable Energy, Elsevier, vol. 132(C), pages 979-988.
    6. Wang, Tianyu & Ma, Xiaoling & Bingwa, Ndzondelelo & Yu, Hao & Wang, Yunpu & Li, Guoning & Guo, Min & Xiao, Qiangqiang & Li, Shijie & Zhao, Xudong & Li, Hui, 2024. "A novel bimetallic CaFe-MOF derivative for transesterification: Catalytic performance, characterization, and stability," Energy, Elsevier, vol. 292(C).
    7. Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.
    8. Guo, Pingmei & Zheng, Chang & Zheng, Mingming & Huang, Fenghong & Li, Wenlin & Huang, Qingde, 2013. "Solid base catalysts for production of fatty acid methyl esters," Renewable Energy, Elsevier, vol. 53(C), pages 377-383.
    9. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sharma, Meeta & Malhotra, R.K., 2009. "Influence of metal contaminants on oxidation stability of Jatropha biodiesel," Energy, Elsevier, vol. 34(9), pages 1271-1275.
    2. Tsai, Wen-Tien & Lin, Chih-Chung & Yeh, Ching-Wei, 2007. "An analysis of biodiesel fuel from waste edible oil in Taiwan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(5), pages 838-857, June.
    3. Lee, Wen-Jhy & Liu, Yi-Cheng & Mwangi, Francis Kimani & Chen, Wei-Hsin & Lin, Sheng-Lun & Fukushima, Yasuhiro & Liao, Chao-Ning & Wang, Lin-Chi, 2011. "Assessment of energy performance and air pollutant emissions in a diesel engine generator fueled with water-containing ethanol–biodiesel–diesel blend of fuels," Energy, Elsevier, vol. 36(9), pages 5591-5599.
    4. Haseeb, A.S.M.A. & Jun, T.S. & Fazal, M.A. & Masjuki, H.H., 2011. "Degradation of physical properties of different elastomers upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(3), pages 1814-1819.
    5. Aytav, Emre & Kocar, Günnur, 2013. "Biodiesel from the perspective of Turkey: Past, present and future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 335-350.
    6. Kang, Sae Byul & Kim, Jong Jin & Im, Yong Hoon, 2013. "An experimental investigation of a direct burning of crude Jatropha oil (CJO) and pitch in a commercial boiler system," Renewable Energy, Elsevier, vol. 54(C), pages 8-12.
    7. Makasson R. Cland & Offong O. Aniekan & Muhammad A. Tahir & Ogbaka T. David, 2020. "Production of Biodiesel from Groundnut Crude Oil," International Journal of Research and Innovation in Applied Science, International Journal of Research and Innovation in Applied Science (IJRIAS), vol. 5(8), pages 133-136, August.
    8. Chang, Yu-Cheng & Lee, Wen-Jhy & Wu, Tser Son & Wu, Chang-Yu & Chen, Shui-Jen, 2014. "Use of water containing acetone–butanol–ethanol for NOx-PM (nitrogen oxide-particulate matter) trade-off in the diesel engine fueled with biodiesel," Energy, Elsevier, vol. 64(C), pages 678-687.
    9. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Nizami, Abdul-Sattar & Sultana, Shazia & Zafar, Muhammad & Rehan, Mohammad & Srinivasan, Gokul Raghavendra & Ali, Arshid Mahmood & Al, 2021. "Biodiesel production from novel non-edible caper (Capparis spinosa L.) seeds oil employing Cu–Ni doped ZrO2 catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    10. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    11. Gogoi, T.K. & Baruah, D.C., 2010. "A cycle simulation model for predicting the performance of a diesel engine fuelled by diesel and biodiesel blends," Energy, Elsevier, vol. 35(3), pages 1317-1323.
    12. Chauhan, Bhupendra Singh & Kumar, Naveen & Cho, Haeng Muk & Lim, Hee Chang, 2013. "A study on the performance and emission of a diesel engine fueled with Karanja biodiesel and its blends," Energy, Elsevier, vol. 56(C), pages 1-7.
    13. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    14. Singh, S.P. & Singh, Dipti, 2010. "Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 200-216, January.
    15. Natalia Duarte Forero & Donovan Arango Barrios & Jorge Duarte Forero, 2019. "Overview of Potential Use of Hydroxyl and Hydrogen as an Alternative Fuel in Colombia," International Journal of Energy Economics and Policy, Econjournals, vol. 9(6), pages 525-534.
    16. Luqman Razzaq & Shahid Imran & Zahid Anwar & Muhammad Farooq & Muhammad Mujtaba Abbas & Haris Mehmood Khan & Tahir Asif & Muhammad Amjad & Manzoore Elahi M. Soudagar & Nabeel Shaukat & I. M. Rizwanul , 2020. "Maximising Yield and Engine Efficiency Using Optimised Waste Cooking Oil Biodiesel," Energies, MDPI, vol. 13(22), pages 1-16, November.
    17. Enrico Mattarelli & Carlo Alberto Rinaldini & Tommaso Savioli, 2015. "Combustion Analysis of a Diesel Engine Running on Different Biodiesel Blends," Energies, MDPI, vol. 8(4), pages 1-11, April.
    18. Wiraditma Prananta & Ida Kubiszewski, 2021. "Assessment of Indonesia’s Future Renewable Energy Plan: A Meta-Analysis of Biofuel Energy Return on Investment (EROI)," Energies, MDPI, vol. 14(10), pages 1-15, May.
    19. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    20. Velásquez, H.I. & De Oliveira, S. & Benjumea, P. & Pellegrini, L.F., 2013. "Exergo-environmental evaluation of liquid biofuel production processes," Energy, Elsevier, vol. 54(C), pages 97-103.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:35:y:2010:i:7:p:1531-1536. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.