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The nanometer magnetic solid base catalyst for production of biodiesel

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  • Liu, Chang
  • Lv, Pengmei
  • Yuan, Zhenhong
  • Yan, Fang
  • Luo, Wen

Abstract

Nanometer magnetic solid base catalysts were prepared by loading CaO on Fe3O4 with Na2CO3 and NaOH as precipitator, respectively. The optimum conditions for preparation of this catalyst were investigated. The influence of the proportion of Ca2+ to Fe3O4 on the catalytic performance has been studied. The catalyst with highest catalytic activity has been obtained when the proportion of Ca2+ to Fe3O4 is 7:1; the catalytic activity of the catalyst calcined from Ca(OH)2 to Fe3O4 is better than that calcined from CaCO3 to Fe3O4; under the conditions of methanol/oil molar ratio of 15:1, catalyst dosage of 2wt% and temperature of 70°C, the biodiesel yield reaches to 95% in 80min, even to 99% finally. The catalytic activity and recovery rate of the nanometer magnetic solid base catalysts are much better than those of CaO. Calcination temperature was determined by differential thermogravimetric analysis. Ca2Fe2O5, a kind of new metal multiple oxide, was found in the catalyst through X-ray diffraction. At the end, these catalysts were characterized by scanning electronic microscope (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM).

Suggested Citation

  • Liu, Chang & Lv, Pengmei & Yuan, Zhenhong & Yan, Fang & Luo, Wen, 2010. "The nanometer magnetic solid base catalyst for production of biodiesel," Renewable Energy, Elsevier, vol. 35(7), pages 1531-1536.
    • Handle: RePEc:eee:renene:v:35:y:2010:i:7:p:1531-1536
    DOI: 10.1016/j.renene.2009.10.009
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    References listed on IDEAS

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    1. Carraretto, C. & Macor, A. & Mirandola, A. & Stoppato, A. & Tonon, S., 2004. "Biodiesel as alternative fuel: Experimental analysis and energetic evaluations," Energy, Elsevier, vol. 29(12), pages 2195-2211.
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    1. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    2. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    3. Vardast, Neda & Haghighi, Mohammad & Dehghani, Sahar, 2019. "Sono-dispersion of calcium over Al-MCM-41used as a nanocatalyst for biodiesel production from sunflower oil: Influence of ultrasound irradiation and calcium content on catalytic properties and perform," Renewable Energy, Elsevier, vol. 132(C), pages 979-988.
    4. Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.
    5. Guo, Pingmei & Zheng, Chang & Zheng, Mingming & Huang, Fenghong & Li, Wenlin & Huang, Qingde, 2013. "Solid base catalysts for production of fatty acid methyl esters," Renewable Energy, Elsevier, vol. 53(C), pages 377-383.
    6. Samuel Santos & Luís Nobre & João Gomes & Jaime Puna & Rosa Quinta-Ferreira & João Bordado, 2019. "Soybean Oil Transesterification for Biodiesel Production with Micro-Structured Calcium Oxide (CaO) from Natural Waste Materials as a Heterogeneous Catalyst," Energies, MDPI, vol. 12(24), pages 1-10, December.
    7. Teuku Meurah Indra Riayatsyah & Hwai Chyuan Ong & Wen Tong Chong & Lisa Aditya & Heri Hermansyah & Teuku Meurah Indra Mahlia, 2017. "Life Cycle Cost and Sensitivity Analysis of Reutealis trisperma as Non-Edible Feedstock for Future Biodiesel Production," Energies, MDPI, vol. 10(7), pages 1-21, June.
    8. Wang, Tianyu & Ma, Xiaoling & Bingwa, Ndzondelelo & Yu, Hao & Wang, Yunpu & Li, Guoning & Guo, Min & Xiao, Qiangqiang & Li, Shijie & Zhao, Xudong & Li, Hui, 2024. "A novel bimetallic CaFe-MOF derivative for transesterification: Catalytic performance, characterization, and stability," Energy, Elsevier, vol. 292(C).
    9. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.

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