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Numerical Predictions of a Swirl Combustor Using Complex Chemistry Fueled with Ammonia/Hydrogen Blends

Author

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  • Marco-Osvaldo Vigueras-Zuniga

    (Mechanical Engineering Department, Universidad Veracruzana, 91090 Veracruz, Mexico)

  • Maria-Elena Tejeda-del-Cueto

    (Mechanical Engineering Department, Universidad Veracruzana, 91090 Veracruz, Mexico)

  • José-Alejandro Vasquez-Santacruz

    (Mechanical Engineering Department, Universidad Veracruzana, 91090 Veracruz, Mexico)

  • Agustín-Leobardo Herrera-May

    (Mechanical Engineering Department, Universidad Veracruzana, 91090 Veracruz, Mexico)

  • Agustin Valera-Medina

    (College of Physical Sciences and Engineering, Cardiff University, Cardiff CF24 3AA, UK)

Abstract

Ammonia, a chemical that contains high hydrogen quantities, has been presented as a candidate for the production of clean power generation and aerospace propulsion. Although ammonia can deliver more hydrogen per unit volume than liquid hydrogen itself, the use of ammonia in combustion systems comes with the detrimental production of nitrogen oxides, which are emissions that have up to 300 times the greenhouse potential of carbon dioxide. This factor, combined with the lower energy density of ammonia, makes new studies crucial to enable the use of the molecule through methods that reduce emissions whilst ensuring that enough power is produced to support high-energy intensive applications. Thus, this paper presents a numerical study based on the use of novel reaction models employed to characterize ammonia combustion systems. The models are used to obtain Reynolds Averaged Navier-Stokes (RANS) simulations via Star-CCM+ with complex chemistry of a 70%–30% (mol) ammonia–hydrogen blend that is currently under investigations elsewhere. A fixed equivalence ratio (1.2), medium swirl (0.8), and confined conditions are employed to determine the flame and species propagation at various operating atmospheres and temperature inlet values. The study is then expanded to high inlet temperatures, high pressures, and high flowrates at different confinement boundary conditions. The results denote how the production of NOx emissions remains stable and under 400 ppm, whilst higher concentrations of both hydrogen and unreacted ammonia are found in the flue gases under high power conditions. The reduction of heat losses (thus higher temperature boundary conditions) has a crucial impact on further destruction of ammonia post-flame, with a raise in hydrogen, water, and nitrogen through the system, thus presenting an opportunity of combustion efficiency improvement of this blend by reducing heat losses. Final discussions are presented as a method to raise power whilst employing ammonia for gas turbine systems.

Suggested Citation

  • Marco-Osvaldo Vigueras-Zuniga & Maria-Elena Tejeda-del-Cueto & José-Alejandro Vasquez-Santacruz & Agustín-Leobardo Herrera-May & Agustin Valera-Medina, 2020. "Numerical Predictions of a Swirl Combustor Using Complex Chemistry Fueled with Ammonia/Hydrogen Blends," Energies, MDPI, vol. 13(2), pages 1-17, January.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:2:p:288-:d:305917
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    References listed on IDEAS

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    1. Honzawa, Takafumi & Kai, Reo & Okada, Akiko & Valera-Medina, Agustin & Bowen, Philip J. & Kurose, Ryoichi, 2019. "Predictions of NO and CO emissions in ammonia/methane/air combustion by LES using a non-adiabatic flamelet generated manifold," Energy, Elsevier, vol. 186(C).
    2. Andreas Goldmann & Waldemar Sauter & Marcel Oettinger & Tim Kluge & Uwe Schröder & Joerg R. Seume & Jens Friedrichs & Friedrich Dinkelacker, 2018. "A Study on Electrofuels in Aviation," Energies, MDPI, vol. 11(2), pages 1-23, February.
    3. Valera-Medina, A. & Vigueras-Zuniga, M.O. & Baej, H. & Syred, N. & Chong, C.T. & Bowen, P.J., 2017. "Outlet geometrical impacts on blowoff effects when using various syngas mixtures in swirling flows," Applied Energy, Elsevier, vol. 207(C), pages 195-207.
    4. Guteša Božo, M. & Vigueras-Zuniga, MO. & Buffi, M. & Seljak, T. & Valera-Medina, A., 2019. "Fuel rich ammonia-hydrogen injection for humidified gas turbines," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    5. Syred, N. & Giles, A. & Lewis, J. & Abdulsada, M. & Valera Medina, A. & Marsh, R. & Bowen, P.J. & Griffiths, A.J., 2014. "Effect of inlet and outlet configurations on blow-off and flashback with premixed combustion for methane and a high hydrogen content fuel in a generic swirl burner," Applied Energy, Elsevier, vol. 116(C), pages 288-296.
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    Cited by:

    1. Kai Huang & Damir M. Valiev & Hongtao Zhong & Wenhu Han, 2023. "Numerical Study of the Influence of the Thermal Gas Expansion on the Boundary Layer Flame Flashback in Channels with Different Wall Thermal Conditions," Energies, MDPI, vol. 16(4), pages 1-19, February.
    2. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.
    3. Marco Osvaldo Vigueras-Zúñiga & Maria Elena Tejeda-del-Cueto & Syed Mashruk & Marina Kovaleva & Cesar Leonardo Ordóñez-Romero & Agustin Valera-Medina, 2021. "Methane/Ammonia Radical Formation during High Temperature Reactions in Swirl Burners," Energies, MDPI, vol. 14(20), pages 1-13, October.
    4. Nguyen Van Duc Long & Le Cao Nhien & Moonyong Lee, 2023. "Advanced Technologies in Hydrogen Revolution," Energies, MDPI, vol. 16(5), pages 1-4, February.
    5. Joanna Jójka & Rafał Ślefarski, 2021. "Emission Characteristics for Swirl Methane–Air Premixed Flames with Ammonia Addition," Energies, MDPI, vol. 14(3), pages 1-19, January.
    6. Namsu Kim & Minjung Lee & Juwon Park & Jeongje Park & Taesong Lee, 2022. "A Comparative Study of NO x Emission Characteristics in a Fuel Staging and Air Staging Combustor Fueled with Partially Cracked Ammonia," Energies, MDPI, vol. 15(24), pages 1-15, December.

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