IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v312y2022ics0306261922002550.html
   My bibliography  Save this article

Utilization of carbon-based energy as raw material instead of fuel with low CO2 emissions: Energy analyses and process integration of chemical looping ammonia generation

Author

Listed:
  • Fang, Jing
  • Xiong, Chuhao
  • Feng, Mingqian
  • Wu, Ye
  • Liu, Dong

Abstract

Ammonia (NH3) has attracted much attention as both a fuel and an energy carrier due to its transportability and cleanliness. At present, most of NH3 is synthesized by the catalytic Haber-Bosch reaction (N2+3H2⇌2NH3). Due to its energy-intensive processes for hydrogen production, high carbon dioxide (CO2) emissions as well as high pressure required for NH3 synthesis, an alternative highly efficient system is needed. In this study, an integrated system based on chemical looping ammonia generation (CLAG), which combines air separation, N-sorption/desorption (ammonia synthesis), steam generation and urea production is proposed. The system employs a novel ammonia production loop and produces steam, carbon monoxide (CO) and urea as by-products. System modelling is conducted using Aspen Plus V11 (Aspen Technology, Inc.). The results showed the energy consumption can reach 6.88 GJ/tNH3. The total CO2 emission of the ammonia synthesis system was 2.05 kg/kg NH3 in which direct CO2 emission dropped to 0.43 kg/kg NH3, and with urea production, the direct CO2 emission can reduce to −0.86 kg/kg NH3, leading to negative CO2 emissions.

Suggested Citation

  • Fang, Jing & Xiong, Chuhao & Feng, Mingqian & Wu, Ye & Liu, Dong, 2022. "Utilization of carbon-based energy as raw material instead of fuel with low CO2 emissions: Energy analyses and process integration of chemical looping ammonia generation," Applied Energy, Elsevier, vol. 312(C).
    • Handle: RePEc:eee:appene:v:312:y:2022:i:c:s0306261922002550
    DOI: 10.1016/j.apenergy.2022.118809
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261922002550
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2022.118809?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Hanfei & Wang, Ligang & Van herle, Jan & Maréchal, François & Desideri, Umberto, 2021. "Techno-economic comparison of 100% renewable urea production processes," Applied Energy, Elsevier, vol. 284(C).
    2. Penkuhn, Mathias & Tsatsaronis, George, 2017. "Comparison of different ammonia synthesis loop configurations with the aid of advanced exergy analysis," Energy, Elsevier, vol. 137(C), pages 854-864.
    3. Tian-Nan Ye & Sang-Won Park & Yangfan Lu & Jiang Li & Masato Sasase & Masaaki Kitano & Tomofumi Tada & Hideo Hosono, 2020. "Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst," Nature, Nature, vol. 583(7816), pages 391-395, July.
    4. Bargiacchi, Eleonora & Antonelli, Marco & Desideri, Umberto, 2019. "A comparative assessment of Power-to-Fuel production pathways," Energy, Elsevier, vol. 183(C), pages 1253-1265.
    5. Jiang, Jianrong & Feng, Xiao, 2019. "Energy optimization of ammonia synthesis processes based on oxygen purity under different purification technologies," Energy, Elsevier, vol. 185(C), pages 819-828.
    6. Wang, Xiaoyu & Su, Mingze & Zhao, Haibo, 2021. "Process design and exergy cost analysis of a chemical looping ammonia generation system using AlN/Al2O3 as a nitrogen carrier," Energy, Elsevier, vol. 230(C).
    7. Rafiqul, Islam & Weber, Christoph & Lehmann, Bianca & Voss, Alfred, 2005. "Energy efficiency improvements in ammonia production—perspectives and uncertainties," Energy, Elsevier, vol. 30(13), pages 2487-2504.
    8. Lee Pereira, Reinaldo Juan & Argyris, Panagiotis Alexandros & Spallina, Vincenzo, 2020. "A comparative study on clean ammonia production using chemical looping based technology," Applied Energy, Elsevier, vol. 280(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xiong, Chuhao & Wu, Jin & Ji, Zhengang & Wu, Ye & Liu, Dong, 2024. "Unraveling the role of alkali metal in the biochar for enhancing the chemical looping ammonia generation efficiency," Renewable Energy, Elsevier, vol. 220(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Meng, Wenliang & Wang, Dongliang & Zhou, Huairong & Yang, Yong & Li, Hongwei & Liao, Zuwei & Yang, Siyu & Hong, Xiaodong & Li, Guixian, 2023. "Carbon dioxide from oxy-fuel coal-fired power plant integrated green ammonia for urea synthesis: Process modeling, system analysis, and techno-economic evaluation," Energy, Elsevier, vol. 278(C).
    2. Xiong, Chuhao & Wu, Ye & Feng, Mingqian & Fang, Jing & Liu, Dong & Shen, Laihong & Argyle, Morris D. & A. M. Gasem, Khaled & Fan, Maohong, 2022. "High thermal stability Si-Al based N-carrier for efficient and stable chemical looping ammonia generation," Applied Energy, Elsevier, vol. 323(C).
    3. Ansarinasab, Hojat & Fatimah, Manal & Khojasteh-Salkuyeh, Yaser, 2024. "Sustainable production of ammonia and formic acid using three chemical looping reactors and CO2 electroreduction cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    4. Hunt, Julian David & Nascimento, Andreas & Zakeri, Behnam & Barbosa, Paulo Sérgio Franco, 2022. "Hydrogen Deep Ocean Link: a global sustainable interconnected energy grid," Energy, Elsevier, vol. 249(C).
    5. Piciu Gabriela-Cornelia, 2021. "Decarbonisation Of Economy In Romania," Annals - Economy Series, Constantin Brancusi University, Faculty of Economics, vol. 5, pages 98-104, October.
    6. Liu, Chenglin & Zhao, Lei & Zhu, Shun & Shen, Yuefeng & Yu, Jianhua & Yang, Qingchun, 2023. "Advanced exergy analysis and optimization of a coal to ethylene glycol (CtEG) process," Energy, Elsevier, vol. 282(C).
    7. Andrea Ramírez & Martin K. Patel & Kornelis Blok, 2011. "Using Physical Indicators to Monitor Energy Efficiency in Energy-Extensive Sectors," Chapters, in: Raymond J.G.M. Florax & Henri L.F. de Groot & Peter Mulder (ed.), Improving Energy Efficiency through Technology, chapter 4, Edward Elgar Publishing.
    8. Jiang, Jianrong & Feng, Xiao, 2019. "Energy optimization of ammonia synthesis processes based on oxygen purity under different purification technologies," Energy, Elsevier, vol. 185(C), pages 819-828.
    9. Wen, Du & Aziz, Muhammad, 2022. "Techno-economic analyses of power-to-ammonia-to-power and biomass-to-ammonia-to-power pathways for carbon neutrality scenario," Applied Energy, Elsevier, vol. 319(C).
    10. Michalsky, Ronald & Parman, Bryon J. & Amanor-Boadu, Vincent & Pfromm, Peter H., 2012. "Solar thermochemical production of ammonia from water, air and sunlight: Thermodynamic and economic analyses," Energy, Elsevier, vol. 42(1), pages 251-260.
    11. Talaei, Alireza & Ahiduzzaman, Md. & Kumar, Amit, 2018. "Assessment of long-term energy efficiency improvement and greenhouse gas emissions mitigation potentials in the chemical sector," Energy, Elsevier, vol. 153(C), pages 231-247.
    12. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    13. Kim, Jeongdong & Qi, Meng & Park, Jinwoo & Moon, Il, 2023. "Revealing the impact of renewable uncertainty on grid-assisted power-to-X: A data-driven reliability-based design optimization approach," Applied Energy, Elsevier, vol. 339(C).
    14. Guido Francesco Frate & Lorenzo Ferrari & Umberto Desideri, 2020. "Rankine Carnot Batteries with the Integration of Thermal Energy Sources: A Review," Energies, MDPI, vol. 13(18), pages 1-28, September.
    15. Pivetta, D. & Dall’Armi, C. & Sandrin, P. & Bogar, M. & Taccani, R., 2024. "The role of hydrogen as enabler of industrial port area decarbonization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    16. Egerer, Jonas & Farhang-Damghani, Nima & Grimm, Veronika & Runge, Philipp, 2024. "The industry transformation from fossil fuels to hydrogen will reorganize value chains: Big picture and case studies for Germany," Applied Energy, Elsevier, vol. 358(C).
    17. Sarkar, Susanjib & Kumar, Amit & Sultana, Arifa, 2011. "Biofuels and biochemicals production from forest biomass in Western Canada," Energy, Elsevier, vol. 36(10), pages 6251-6262.
    18. Caglayan, Hasan & Caliskan, Hakan, 2022. "Assessment of a cogeneration system for ceramic industry by using various exergy based economic approaches," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    19. Wenzhe Niu & Jie Feng & Junfeng Chen & Lei Deng & Wen Guo & Huajing Li & Liqiang Zhang & Youyong Li & Bo Zhang, 2024. "High-efficiency C3 electrosynthesis on a lattice-strain-stabilized nitrogen-doped Cu surface," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    20. Flórez-Orrego, Daniel & de Oliveira Junior, Silvio, 2016. "On the efficiency, exergy costs and CO2 emission cost allocation for an integrated syngas and ammonia production plant," Energy, Elsevier, vol. 117(P2), pages 341-360.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:312:y:2022:i:c:s0306261922002550. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.