IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v277y2023ics0360544223011015.html
   My bibliography  Save this article

Thermal decomposition of polypropylene plastics through vacuum pyrolysis

Author

Listed:
  • Nugroho, Rusdan Aditya Aji
  • Alhikami, Akhmad Faruq
  • Wang, Wei-Cheng

Abstract

The technique of thermal pyrolysis has a great contribution to waste-to-energy platform and circular economic mission. This study used an internal heating process for the vacuum pyrolysis of plastic waste. Eight heating tubes were placed inside a reactor to accelerate heat transfer to the feedstock. Uniform temperature distribution was achieved in <1 h. After 90 min, three phases of pressure profiles were identified: decomposing samples, maximum feedstock cracking, and stability occurrences. Internal pressure decreased with the reduction of condensable gas. Pyrolytic oil was similar to conventional fuels (gasoline and diesel), with the percentage of lower hydrocarbons C5–C10 at 73%, C11–C22 at 18%, and >C22 at 9%. Gas chromatography–thermal conductivity detector analysis of noncondensable gases revealed that the main product of PP with 75% area was C2H6. Furthermore, the Taguchi method was used to optimize the vacuum pyrolysis of waste to energy. Optimal operating conditions for maximum pyrolytic yields were as follows: temperature 425 °C, heating rate 15 °C/min, residence time 6 h, and output flow rate 0.1 L/min. Moreover, the physical properties, cetane number, soot propensities, and auto-ignition temperature of pyrolytic oil were comparable to petroleum diesel. The heating value of the oil product was 55.96 MJ/kg, which was higher compared with petroleum fuels. Vacuum pyrolysis mass, carbon, and energy balances were also determined. This study demonstrated the novel use of internal heating in vacuum pyrolysis. Ultimately, this study provided a new technique of internal heating method in vacuum pyrolysis.

Suggested Citation

  • Nugroho, Rusdan Aditya Aji & Alhikami, Akhmad Faruq & Wang, Wei-Cheng, 2023. "Thermal decomposition of polypropylene plastics through vacuum pyrolysis," Energy, Elsevier, vol. 277(C).
    • Handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223011015
    DOI: 10.1016/j.energy.2023.127707
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223011015
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.127707?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Al Afif, Rafat & Anayah, S. Sean & Pfeifer, Christoph, 2020. "Batch pyrolysis of cotton stalks for evaluation of biochar energy potential," Renewable Energy, Elsevier, vol. 147(P1), pages 2250-2258.
    2. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    3. Fakudze, Sandile & Wei, Yingyuan & Shang, Qianqian & Ma, Ru & Li, Yueh-Heng & Chen, Jianqiang & Zhou, Peiguo & Han, Jiangang & Liu, Chengguo, 2021. "Single-pot upgrading of run-of-mine coal and rice straw via Taguchi-optimized hydrothermal treatment: Fuel properties and synergistic effects," Energy, Elsevier, vol. 236(C).
    4. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.
    5. Chen, Guan-Lin & Chen, Guan-Bang & Li, Yueh-Heng & Wu, Wen-Teng, 2014. "A study of thermal pyrolysis for castor meal using the Taguchi method," Energy, Elsevier, vol. 71(C), pages 62-70.
    6. Soria-Verdugo, Antonio & Rubio-Rubio, Mariano & Goos, Elke & Riedel, Uwe, 2020. "On the characteristic heating and pyrolysis time of thermally small biomass particles in a bubbling fluidized bed reactor," Renewable Energy, Elsevier, vol. 160(C), pages 312-322.
    7. Hong, Ying-Yi & Beltran, Angelo A. & Paglinawan, Arnold C., 2018. "A robust design of maximum power point tracking using Taguchi method for stand-alone PV system," Applied Energy, Elsevier, vol. 211(C), pages 50-63.
    8. Stella Bezergianni & Athanasios Dimitriadis & Gian-Claudio Faussone & Dimitrios Karonis, 2017. "Alternative Diesel from Waste Plastics," Energies, MDPI, vol. 10(11), pages 1-12, October.
    9. Abbas-Abadi, Mehrdad Seifali & Van Geem, Kevin M. & Fathi, Maryam & Bazgir, Hossein & Ghadiri, Mohammad, 2021. "The pyrolysis of oak with polyethylene, polypropylene and polystyrene using fixed bed and stirred reactors and TGA instrument," Energy, Elsevier, vol. 232(C).
    10. Park, Ki-Bum & Jeong, Yong-Seong & Kim, Joo-Sik, 2019. "Activator-assisted pyrolysis of polypropylene," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yorinda Buyang, 2023. "Bio-oil production from pyrolysis of Polypropylene using dolomite catalyst," Technium, Technium Science, vol. 17(1), pages 36-40.
    2. Suarez, Mayra Alejandra & Januszewicz, Katarzyna & Cortazar, Maria & Lopez, Gartzen & Santamaria, Laura & Olazar, Martin & Artetxe, Maite & Amutio, Maider, 2024. "Selective H2 production from plastic waste through pyrolysis and in-line oxidative steam reforming," Energy, Elsevier, vol. 302(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ana B. Cuevas & David E. Leiva-Candia & M. P. Dorado, 2024. "An Overview of Pyrolysis as Waste Treatment to Produce Eco-Energy," Energies, MDPI, vol. 17(12), pages 1-32, June.
    2. Mostafa Esmaeili Shayan & Gholamhassan Najafi & Barat Ghobadian & Shiva Gorjian & Mohamed Mazlan & Mehdi Samami & Alireza Shabanzadeh, 2022. "Flexible Photovoltaic System on Non-Conventional Surfaces: A Techno-Economic Analysis," Sustainability, MDPI, vol. 14(6), pages 1-14, March.
    3. Liu, Zihan & Li, Pan & Chang, Chun & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Pang, Shusheng, 2022. "Influence of metal chloride modified biochar on products characteristics from biomass catalytic pyrolysis," Energy, Elsevier, vol. 250(C).
    4. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    5. Wang, Jian-jun & Deng, Yu-cong & Sun, Wen-biao & Zheng, Xiao-bin & Cui, Zheng, 2023. "Maximum power point tracking method based on impedance matching for a micro hydropower generator," Applied Energy, Elsevier, vol. 340(C).
    6. Berthold, Engamba Esso Samy & Deng, Wei & Zhou, Junbo & Bertrand, Aguenkeu Mefinnya Elie & Xu, Jun & Jiang, Long & Su, Sheng & Hu, Song & Hu, Xun & Wang, Yi & Xiang, Jun, 2023. "Impact of plastic type on synergistic effects during co-pyrolysis of rice husk and plastics," Energy, Elsevier, vol. 281(C).
    7. Kim, Jae-Kyung & Jeong, Yong-Seong & Kim, Jong-Woo & Kim, Joo-Sik, 2023. "Two-stage thermochemical conversion of polyethylene terephthalate using steam to produce a clean and H2- and CO-rich syngas," Energy, Elsevier, vol. 276(C).
    8. Park, Ki-Bum & Choi, Min-Jun & Chae, Da-Yeong & Jung, Jaeheum & Kim, Joo-Sik, 2022. "Separate two-step and continuous two-stage pyrolysis of a waste plastic mixture to produce a chlorine-depleted oil," Energy, Elsevier, vol. 244(PA).
    9. Anna Matuszewska & Adam Hańderek & Maciej Paczuski & Krzysztof Biernat, 2021. "Hydrocarbon Fractions from Thermolysis of Waste Plastics as Components of Engine Fuels," Energies, MDPI, vol. 14(21), pages 1-14, November.
    10. Chen, Wen-Lih & Currao, Gaetano & Li, Yueh-Heng & Kao, Chien-Chun, 2023. "Employing Taguchi method to optimize the performance of a microscale combined heat and power system with Stirling engine and thermophotovoltaic array," Energy, Elsevier, vol. 270(C).
    11. Vavilapalli, Sridhar & Umashankar, S. & Sanjeevikumar, P. & Ramachandaramurthy, Vigna K. & Mihet-Popa, Lucian & Fedák, Viliam, 2018. "Three-stage control architecture for cascaded H-Bridge inverters in large-scale PV systems – Real time simulation validation," Applied Energy, Elsevier, vol. 229(C), pages 1111-1127.
    12. Baghel, Paramjeet & Sakhiya, Anil Kumar & Kaushal, Priyanka, 2022. "Influence of temperature on slow pyrolysis of Prosopis Juliflora: An experimental and thermodynamic approach," Renewable Energy, Elsevier, vol. 185(C), pages 538-551.
    13. Chakraborty, Sourabh & Mohanty, Kaustubha & Vinu, Ravikrishnan, 2024. "Co-pyrolysis of bamboo biomass with polypropylene coverall: Distributed activation energy modeling and pyrolysate composition studies," Renewable Energy, Elsevier, vol. 220(C).
    14. Tong, Wenyao & Chu, Qiulu & Li, Jin & Xie, Xinyu & Wang, Jing & Jin, Yongcan & Wu, Shufang & Hu, Jinguang & Song, Kai, 2022. "Insight into understanding sequential two-stage pretreatment on modifying lignin physiochemical properties and improving holistic utilization of renewable lignocellulose biomass," Renewable Energy, Elsevier, vol. 187(C), pages 123-134.
    15. Li, Jinhu & Ye, Xinhao & Burra, Kiran G. & Lu, Wei & Wang, Zhiwei & Liu, Xuan & Gupta, Ashwani K., 2023. "Synergistic effects during co-pyrolysis and co-gasification of polypropylene and polystyrene," Applied Energy, Elsevier, vol. 336(C).
    16. Guzelciftci, Begum & Park, Ki-Bum & Kim, Joo-Sik, 2020. "Production of phenol-rich bio-oil via a two-stage pyrolysis of wood," Energy, Elsevier, vol. 200(C).
    17. Wei, Yingyuan & Fakudze, Sandile & Zhang, Yiming & Ma, Ru & Shang, Qianqian & Chen, Jianqiang & Liu, Chengguo & Chu, Qiulu, 2022. "Co-hydrothermal carbonization of pomelo peel and PVC for production of hydrochar pellets with enhanced fuel properties and dechlorination," Energy, Elsevier, vol. 239(PD).
    18. Cui, Yunlei & Zhang, Yaning & Cui, Longfei & Xiong, Qingang & Mostafa, Ehab, 2023. "Microwave-assisted fluidized bed reactor pyrolysis of polypropylene plastic for pyrolysis gas production towards a sustainable development," Applied Energy, Elsevier, vol. 342(C).
    19. Ke, Linyao & Wu, Qiuhao & Zhou, Nan & Xiong, Jianyun & Yang, Qi & Zhang, Letian & Wang, Yuanyuan & Dai, Leilei & Zou, Rongge & Liu, Yuhuan & Ruan, Roger & Wang, Yunpu, 2022. "Lignocellulosic biomass pyrolysis for aromatic hydrocarbons production: Pre and in-process enhancement methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    20. Gian Claudio Faussone & Andrej Kržan & Miha Grilc, 2021. "Conversion of Marine Litter from Venice Lagoon into Marine Fuels via Thermochemical Route: The Overview of Products, Their Yield, Quality and Environmental Impact," Sustainability, MDPI, vol. 13(16), pages 1-16, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:277:y:2023:i:c:s0360544223011015. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.