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Organic compounds in the char deposits characterising the combustion of unauthorised fuels in residential boilers

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  • Růžičková, Jana
  • Raclavská, Helena
  • Juchelková, Dagmar
  • Kucbel, Marek
  • Raclavský, Konstantin
  • Švédová, Barbora
  • Šafář, Michal
  • Pfeifer, Christoph
  • Hrbek, Jitka

Abstract

The paper aims to find a way of simply identifying the addition of unauthorised waste (plastics) in residential boilers burning wood as the main fuel. The burning of plastics leaves a trace in char deposits, which are otherwise made up mostly of lignin breakdown products. Identification of combusted plastics in char deposits is made possible by determining unique organic compounds formed during the pyrolysis phase of combustion by pyrolysis gas chromatography. At temperatures above 800 °C, the amount of charring product from the incineration of PET is 19.5 wt%, while for PP, it is 5 wt%, and LDPE with HDPE 2.1 wt%. Combustion of polypropylene with wood has been verified by the presence of the compounds 2,4-dimethyl-1-heptene, 2-methyl-1-pentene, and 2,4,6-trimethyl-1-nonene. The thermal degradation of PE has been demonstrated by the presence of triplets of alkanes, alkenes, and alkadienes. Combustion of PET in domestic waste can be demonstrated by the presence of benzoic acid and its esters, benzoate compounds, and terephthalic acid. In summarising, sampling char in boilers and analysing samples for markers of plastics incineration could be used as a method for identification of unauthorised waste combustion by authorities.

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  • Růžičková, Jana & Raclavská, Helena & Juchelková, Dagmar & Kucbel, Marek & Raclavský, Konstantin & Švédová, Barbora & Šafář, Michal & Pfeifer, Christoph & Hrbek, Jitka, 2022. "Organic compounds in the char deposits characterising the combustion of unauthorised fuels in residential boilers," Energy, Elsevier, vol. 257(C).
    • Handle: RePEc:eee:energy:v:257:y:2022:i:c:s0360544222016279
    DOI: 10.1016/j.energy.2022.124724
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    1. Maulana G. Nugraha & Harwin Saptoadi & Muslikhin Hidayat & Bengt Andersson & Ronnie Andersson, 2021. "Particulate Matter Reduction in Residual Biomass Combustion," Energies, MDPI, vol. 14(11), pages 1-23, June.
    2. Tripathi, Manoj & Sahu, J.N. & Ganesan, P., 2016. "Effect of process parameters on production of biochar from biomass waste through pyrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 467-481.
    3. Farihahusnah Hussin & Mohamed Kheireddine Aroua & Mohd Azlan Kassim & Umi Fazara Md. Ali, 2021. "Transforming Plastic Waste into Porous Carbon for Capturing Carbon Dioxide: A Review," Energies, MDPI, vol. 14(24), pages 1-22, December.
    4. Choi, Min-Jun & Jeong, Yong-Seong & Kim, Joo-Sik, 2021. "Air gasification of polyethylene terephthalate using a two-stage gasifier with active carbon for the production of H2 and CO," Energy, Elsevier, vol. 223(C).
    5. Tao, Guangcan & Geladi, Paul & Lestander, Torbjörn A. & Xiong, Shaojun, 2012. "Biomass properties in association with plant species and assortments. II: A synthesis based on literature data for ash elements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3507-3522.
    6. Pérez-Orozco, Raquel & Patiño, David & Porteiro, Jacobo & Míguez, José Luis, 2020. "Bed cooling effects in solid particulate matter emissions during biomass combustion. A morphological insight," Energy, Elsevier, vol. 205(C).
    7. Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Bio-energy generation from sagwan sawdust via pyrolysis: Product distributions, characterizations and optimization using response surface methodology," Energy, Elsevier, vol. 170(C), pages 423-437.
    8. Tao, Guangcan & Lestander, Torbjörn A. & Geladi, Paul & Xiong, Shaojun, 2012. "Biomass properties in association with plant species and assortments I: A synthesis based on literature data of energy properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3481-3506.
    9. Abbas-Abadi, Mehrdad Seifali & Van Geem, Kevin M. & Fathi, Maryam & Bazgir, Hossein & Ghadiri, Mohammad, 2021. "The pyrolysis of oak with polyethylene, polypropylene and polystyrene using fixed bed and stirred reactors and TGA instrument," Energy, Elsevier, vol. 232(C).
    10. Rago, Yogeshwari Pooja & Collard, François-Xavier & Görgens, Johann F. & Surroop, Dinesh & Mohee, Romeela, 2022. "Co-combustion of torrefied biomass-plastic waste blends with coal through TGA: Influence of synergistic behaviour," Energy, Elsevier, vol. 239(PA).
    11. Horvat, Ivan & Dović, Damir & Filipović, Petar, 2021. "Numerical and experimental methods in development of the novel biomass combustion system concept for wood and agro pellets," Energy, Elsevier, vol. 231(C).
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    1. Růžičková, Jana & Raclavská, Helena & Kucbel, Marek & Pfeifer, Christoph & Juchelková, Dagmar & Hrbek, Jitka & Šafář, Michal & Slamová, Karolina & Švédová, Barbora & Kantor, Pavel, 2023. "Incidence and spread of additives from co-combustion of plastic waste in domestic boilers in indoor and outdoor environments around the family house," Energy, Elsevier, vol. 285(C).

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