IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v269y2023ics0360544223002153.html
   My bibliography  Save this article

Carbon dioxide and acetone mixtures as refrigerants for industry heat pumps to supply temperature in the range 150–220 oC

Author

Listed:
  • Gómez-Hernández, J.
  • Grimes, R.
  • Briongos, J.V.
  • Marugán-Cruz, C.
  • Santana, D.

Abstract

Industry decarbonization is a key a challenge towards the transition to climate neutrality. Indeed, there is a need to satisfy heat at temperatures higher than 150 °C in relevant industrial sectors by upgrading lower temperature heat flows, such as heat from renewable heat sources, ambient heat or industrial waste heat. High temperature heat pumps (HTHP) can upgrade such heat flows enabling great savings in carbon emissions. New refrigerants are needed to develop HTHPs achieving high performances at high temperatures. This paper proposes the use of a new zeotropic mixture composed of carbon dioxide and acetone as the refrigerant of HTHPs working in the temperature range of 150–220 °C. The new fluid is compared with existing pure refrigerants currently used. The thermodynamic characterization of the CO2/acetone mixtures shows temperature glides below 50 K for CO2 mass fractions up to 10%. The best HTHP performance is shown for the mixture 5% CO2/95% acetone in mass fraction. For instance, such a mixture obtains a COP of 5.63 when the target outlet sink temperature is 200 °C and the temperature difference between the outlet heat sink and the inlet heat source is 70 K, showing an improvement of 46% compared to pure acetone.

Suggested Citation

  • Gómez-Hernández, J. & Grimes, R. & Briongos, J.V. & Marugán-Cruz, C. & Santana, D., 2023. "Carbon dioxide and acetone mixtures as refrigerants for industry heat pumps to supply temperature in the range 150–220 oC," Energy, Elsevier, vol. 269(C).
    • Handle: RePEc:eee:energy:v:269:y:2023:i:c:s0360544223002153
    DOI: 10.1016/j.energy.2023.126821
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223002153
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.126821?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Heberle, Florian & Preißinger, Markus & Brüggemann, Dieter, 2012. "Zeotropic mixtures as working fluids in Organic Rankine Cycles for low-enthalpy geothermal resources," Renewable Energy, Elsevier, vol. 37(1), pages 364-370.
    2. Jiang, Jiatong & Hu, Bin & Wang, R.Z. & Deng, Na & Cao, Feng & Wang, Chi-Chuan, 2022. "A review and perspective on industry high-temperature heat pumps," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    3. Arpagaus, Cordin & Bless, Frédéric & Uhlmann, Michael & Schiffmann, Jürg & Bertsch, Stefan S., 2018. "High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials," Energy, Elsevier, vol. 152(C), pages 985-1010.
    4. Wang, Y. & Wang, J. & He, W., 2022. "Development of efficient, flexible and affordable heat pumps for supporting heat and power decarbonisation in the UK and beyond: Review and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Zühlsdorf, Benjamin & Jensen, Jonas Kjær & Cignitti, Stefano & Madsen, Claus & Elmegaard, Brian, 2018. "Analysis of temperature glide matching of heat pumps with zeotropic working fluid mixtures for different temperature glides," Energy, Elsevier, vol. 153(C), pages 650-660.
    6. Men, Yiyu & Liu, Xiaohua & Zhang, Tao, 2021. "A review of boiler waste heat recovery technologies in the medium-low temperature range," Energy, Elsevier, vol. 237(C).
    7. Schlosser, F. & Jesper, M. & Vogelsang, J. & Walmsley, T.G. & Arpagaus, C. & Hesselbach, J., 2020. "Large-scale heat pumps: Applications, performance, economic feasibility and industrial integration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    8. Zühlsdorf, B. & Meesenburg, W. & Ommen, T.S. & Thorsen, J.E. & Markussen, W.B. & Elmegaard, B., 2018. "Improving the performance of booster heat pumps using zeotropic mixtures," Energy, Elsevier, vol. 154(C), pages 390-402.
    9. Crespi, F. & Rodríguez de Arriba, P. & Sánchez, D. & Ayub, A. & Di Marcoberardino, G. & Invernizzi, C.M. & Martínez, G.S. & Iora, P. & Di Bona, D. & Binotti, M. & Manzolini, G., 2022. "Thermal efficiency gains enabled by using CO2 mixtures in supercritical power cycles," Energy, Elsevier, vol. 238(PC).
    10. Bamigbetan, Opeyemi & Eikevik, Trygve Magne & Nekså, Petter & Bantle, Michael & Schlemminger, Christian, 2019. "Experimental investigation of a prototype R-600 compressor for high temperature heat pump," Energy, Elsevier, vol. 169(C), pages 730-738.
    11. Chua, K.J. & Chou, S.K. & Yang, W.M., 2010. "Advances in heat pump systems: A review," Applied Energy, Elsevier, vol. 87(12), pages 3611-3624, December.
    12. Adamson, Keri-Marie & Walmsley, Timothy Gordon & Carson, James K. & Chen, Qun & Schlosser, Florian & Kong, Lana & Cleland, Donald John, 2022. "High-temperature and transcritical heat pump cycles and advancements: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chengyu Li & Yongzhen Wang & Qiang Guo & Youtang Wang & Hu Chen, 2023. "High-Temperature Heat Pump Using CO 2 -Based Mixture for Simultaneous Heat and Cold Energy Reservation," Energies, MDPI, vol. 16(18), pages 1-18, September.
    2. Sergio Bobbo & Giulia Lombardo & Davide Menegazzo & Laura Vallese & Laura Fedele, 2024. "A Technological Update on Heat Pumps for Industrial Applications," Energies, MDPI, vol. 17(19), pages 1-55, October.
    3. Hemin Hu & Tao Wang & Fan Zhang & Bing Zhang & Jian Qi, 2024. "Matching Characteristics of Refrigerant and Operating Parameters in Large Temperature Variation Heat Pump," Energies, MDPI, vol. 17(14), pages 1-24, July.
    4. Obika, Echezona & Heberle, Florian & Brüggemann, Dieter, 2024. "Thermodynamic analysis of novel mixtures including siloxanes and cyclic hydrocarbons for high-temperature heat pumps," Energy, Elsevier, vol. 294(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Adamson, Keri-Marie & Walmsley, Timothy Gordon & Carson, James K. & Chen, Qun & Schlosser, Florian & Kong, Lana & Cleland, Donald John, 2022. "High-temperature and transcritical heat pump cycles and advancements: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Barco-Burgos, J. & Bruno, J.C. & Eicker, U. & Saldaña-Robles, A.L. & Alcántar-Camarena, V., 2022. "Review on the integration of high-temperature heat pumps in district heating and cooling networks," Energy, Elsevier, vol. 239(PE).
    3. Obika, Echezona & Heberle, Florian & Brüggemann, Dieter, 2024. "Thermodynamic analysis of novel mixtures including siloxanes and cyclic hydrocarbons for high-temperature heat pumps," Energy, Elsevier, vol. 294(C).
    4. Guo, Hao & Gong, Maoqiong & Qin, Xiaoyu, 2019. "Performance analysis of a modified subcritical zeotropic mixture recuperative high-temperature heat pump," Applied Energy, Elsevier, vol. 237(C), pages 338-352.
    5. Schlosser, F. & Jesper, M. & Vogelsang, J. & Walmsley, T.G. & Arpagaus, C. & Hesselbach, J., 2020. "Large-scale heat pumps: Applications, performance, economic feasibility and industrial integration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    6. Mateu-Royo, Carlos & Navarro-Esbrí, Joaquín & Mota-Babiloni, Adrián & Molés, Francisco & Amat-Albuixech, Marta, 2019. "Experimental exergy and energy analysis of a novel high-temperature heat pump with scroll compressor for waste heat recovery," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    7. Jouhara, Hussam & Żabnieńska-Góra, Alina & Delpech, Bertrand & Olabi, Valentina & El Samad, Tala & Sayma, Abdulnaser, 2024. "High-temperature heat pumps: Fundamentals, modelling approaches and applications," Energy, Elsevier, vol. 303(C).
    8. Uusitalo, Antti & Turunen-Saaresti, Teemu & Honkatukia, Juha & Tiainen, Jonna & Jaatinen-Värri, Ahti, 2020. "Numerical analysis of working fluids for large scale centrifugal compressor driven cascade heat pumps upgrading waste heat," Applied Energy, Elsevier, vol. 269(C).
    9. Walmsley, Timothy Gordon & Philipp, Matthias & Picón-Núñez, Martín & Meschede, Henning & Taylor, Matthew Thomas & Schlosser, Florian & Atkins, Martin John, 2023. "Hybrid renewable energy utility systems for industrial sites: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    10. Aguilera, José Joaquín & Meesenburg, Wiebke & Ommen, Torben & Markussen, Wiebke Brix & Poulsen, Jonas Lundsted & Zühlsdorf, Benjamin & Elmegaard, Brian, 2022. "A review of common faults in large-scale heat pumps," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    11. Elias Vieren & Toon Demeester & Wim Beyne & Chiara Magni & Hamed Abedini & Cordin Arpagaus & Stefan Bertsch & Alessia Arteconi & Michel De Paepe & Steven Lecompte, 2023. "The Potential of Vapor Compression Heat Pumps Supplying Process Heat between 100 and 200 °C in the Chemical Industry," Energies, MDPI, vol. 16(18), pages 1-28, September.
    12. Zou, Lingeng & Liu, Ye & Yu, Mengqi & Yu, Jianlin, 2023. "A review of solar assisted heat pump technology for drying applications," Energy, Elsevier, vol. 283(C).
    13. Feng, Chunyu & Guo, Cong & Chen, Junbin & Tan, Sicong & Jiang, Yuyan, 2024. "Thermodynamic analysis of a dual-pressure evaporation high-temperature heat pump with low GWP zeotropic mixtures for steam generation," Energy, Elsevier, vol. 294(C).
    14. Dai, Baomin & Feng, Yining & Liu, Shengchun & Yao, Xiaole & Zhang, Jianing & Wang, Bowen & Wang, Dabiao, 2023. "Dual pressure condensation heating high temperature heat pump using eco-friendly working fluid mixtures for industrial heating processes: 4E analysis," Energy, Elsevier, vol. 283(C).
    15. Jiang, Jiatong & Hu, Bin & Wang, R.Z. & Liu, Hua & Zhang, Zhiping & Wu, Yongqiang & Yue, Qingxue & Zhang, Ying, 2024. "Film condensation experiments of R1233zd(E) over horizontal tubes and high-temperature condensation predictions for high-temperature heat pump," Energy, Elsevier, vol. 300(C).
    16. Dong, Yixiu & Yan, Hongzhi & Wang, Ruzhu, 2024. "Significant thermal upgrade via cascade high temperature heat pump with low GWP working fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PA).
    17. Jesper, Mateo & Schlosser, Florian & Pag, Felix & Walmsley, Timothy Gordon & Schmitt, Bastian & Vajen, Klaus, 2021. "Large-scale heat pumps: Uptake and performance modelling of market-available devices," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    18. Lincoln, Benjamin James & Kong, Lana & Pineda, Alyssa Mae & Walmsley, Timothy Gordon, 2022. "Process integration and electrification for efficient milk evaporation systems," Energy, Elsevier, vol. 258(C).
    19. Albà, C.G. & Alkhatib, I.I.I. & Llovell, F. & Vega, L.F., 2023. "Hunting sustainable refrigerants fulfilling technical, environmental, safety and economic requirements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    20. Jiang, Jiatong & Hu, Bin & Wang, R.Z. & Deng, Na & Cao, Feng & Wang, Chi-Chuan, 2022. "A review and perspective on industry high-temperature heat pumps," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:269:y:2023:i:c:s0360544223002153. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.