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Vacuum pressure swing adsorption for efficient off-gas recycling: Techno-economic and CO2 abatement study

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  • Kim, Jinsu
  • Han, Sang Sup
  • Kim, Jungil
  • Lee, In-Beum
  • Oh, Hyunmin
  • Yoon, Young-Seek

Abstract

We suggest a vacuum pressure swing adsorption that uses CuCl/Boehmite adsorbent as a novel material to efficiently recycle a blast furnace gas into the blast furnace and discuss the techno-economic and CO2 abatement impact. To identify the crucial factors of the separation, five cases are simulated: three adsorption pressures at moderate CO purity, and three purity levels at moderate adsorption pressure. Also, the coke-replacement effects are estimated through the blast furnace simulation to consider the economic benefits. The result shows that the energy efficiency of the separation process varied 72–82%, and injection of highly purified off-gas (99% purity) was the most economically profitable, giving 86.7 US-MM$ of net present value. Cost sensitivity showed that the coke price is the most influential, but the adsorbent cost and carbon taxes have relatively little effect. In the best case, the coke-replacement ratio is 0.26kgCoke mgas−3. The suggested process reduces net emission by 0.19tCO2-eq tHM−1, and this corresponds to the 10% of net reduction which is the competitive strategy compared with the renewable hydrogen blast furnace. This study broadened the understanding of the separation process for off-gas recycling, and optimization of the process should be studied further.

Suggested Citation

  • Kim, Jinsu & Han, Sang Sup & Kim, Jungil & Lee, In-Beum & Oh, Hyunmin & Yoon, Young-Seek, 2023. "Vacuum pressure swing adsorption for efficient off-gas recycling: Techno-economic and CO2 abatement study," Energy, Elsevier, vol. 264(C).
    • Handle: RePEc:eee:energy:v:264:y:2023:i:c:s036054422203167x
    DOI: 10.1016/j.energy.2022.126281
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    References listed on IDEAS

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    1. Kim, Hansol & Lee, Jaewook & Lee, Soobin & Lee, In-Beum & Park, Joo-hyoung & Han, Jeehoon, 2015. "Economic process design for separation of CO2 from the off-gas in ironmaking and steelmaking plants," Energy, Elsevier, vol. 88(C), pages 756-764.
    2. Kim, Jinsu & Kim, Jungil & Oh, Hyunmin & Lee, Seokyoung & Lee, In-Beum & Yoon, Young-Seek, 2022. "Techno-economic and environmental impact analysis of tuyere injection of hot reducing gas from low-rank coal gasification in blast furnace," Energy, Elsevier, vol. 241(C).
    3. Liu, Lianzhi & Jiang, Zeyi & Zhang, Xinru & Lu, Yuanxiang & He, Junkai & Wang, Jingsong & Zhang, Xinxin, 2018. "Effects of top gas recycling on in-furnace status, productivity, and energy consumption of oxygen blast furnace," Energy, Elsevier, vol. 163(C), pages 144-150.
    4. Peng Wang & Morten Ryberg & Yi Yang & Kuishuang Feng & Sami Kara & Michael Hauschild & Wei-Qiang Chen, 2021. "Efficiency stagnation in global steel production urges joint supply- and demand-side mitigation efforts," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
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    1. Rumbo-Morales, Jesse Y. & Ortiz-Torres, Gerardo & Sarmiento-Bustos, Estela & Rosales, Antonio Márquez & Calixto-Rodriguez, Manuela & Sorcia-Vázquez, Felipe D.J. & Pérez-Vidal, Alan F. & Rodríguez-Cerd, 2024. "Purification and production of bio-ethanol through the control of a pressure swing adsorption plant," Energy, Elsevier, vol. 288(C).
    2. Kim, Jinsu & Jamdade, Shubham & Yuan, Yanhui & Realff, Matthew J., 2024. "System-level analysis of atmospheric water extraction with MIL-100 (Fe) for design and optimal site selection using meteorological characteristics," Energy, Elsevier, vol. 299(C).

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