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Co-gasification characteristics of coke blended with hydro-char and pyro-char from bamboo

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  • Sun, Minmin
  • Zhang, Jianliang
  • Li, Kejiang
  • Barati, Mansoor
  • Liu, Zhibin

Abstract

The renewable and carbon-neutral biomass is gaining a lot of interest in ironmaking as a substitute to metallurgical coke. The present study looked at partial replacement of coke with biochar obtained from hydrothermal carbonization (HTC) and pyrolysis of bamboo. Pyro-char has a higher carbon crystallinity, lower volatiles and better pore characteristics, while HTC is ideal for the removal of ash especially alkali metals. Devolatilization occurs at 500–900 °C for the hydro-char/coke mixture while the pyro-char/coke blend shows a continuous gasification reaction. The activation energy of gasification for the 50% pyro-char/50% coke is 200–320 kJ/mol, significantly lower than the competing mixture with hydro-char. Although the biochar obtained from pyrolysis of bamboo is more suitable for BF, the excellent ash removal and lower cost of hydrothermal treatment are offering benefits so that a combination of both may present an optimum blend for reducing the carbon footprint of ironmaking process.

Suggested Citation

  • Sun, Minmin & Zhang, Jianliang & Li, Kejiang & Barati, Mansoor & Liu, Zhibin, 2022. "Co-gasification characteristics of coke blended with hydro-char and pyro-char from bamboo," Energy, Elsevier, vol. 241(C).
    • Handle: RePEc:eee:energy:v:241:y:2022:i:c:s036054422103139x
    DOI: 10.1016/j.energy.2021.122890
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    1. Yuchiao Lu & Hanmin Yang & Andrey V. Karasev & Chuan Wang & Pär G. Jönsson, 2022. "Applications of Hydrochar and Charcoal in the Iron and Steelmaking Industry—Part 1: Characterization of Carbonaceous Materials," Sustainability, MDPI, vol. 14(15), pages 1-27, August.
    2. Felix Charvet & Arlindo Matos & José Figueiredo da Silva & Luís Tarelho & Mariana Leite & Daniel Neves, 2022. "Charcoal Production in Portugal: Operating Conditions and Performance of a Traditional Brick Kiln," Energies, MDPI, vol. 15(13), pages 1-21, June.
    3. Jiao, Kexin & Feng, Guangxiang & Zhang, Jianliang & Wang, Cui & Zhang, Lei, 2023. "Effect of multi-component gases on the behavior and mechanism of carbon deposition in hydrogen-rich blast furnaces," Energy, Elsevier, vol. 263(PA).

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