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Thermal stability of a mixed working fluid (R513A) for organic Rankine cycle

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  • Xin, Liyong
  • Yu, Wei
  • Liu, Chao
  • Liu, Lang
  • Wang, Shukun
  • Li, Xiaoxiao
  • Liu, Yu

Abstract

Organic Rankine cycle (ORC) is an effective way to utilize low-grade energy, with R1234yf being considered a promising working fluid for ORC for its low global warming potential (GWP). Nevertheless, the weak thermal stability has limited the application R1234yf in ORC, emphasizing the necessity to find a way preventing the its pyrolysis in ORC. In this connection, a systematic study on the mechanism of R134a affecting the thermal stability of R1234yf in ORC was conducted in this work. Our experimental results indicate that the pyrolysis temperature of R513A (R1234yf/R134a) is in the range of 190–210 °C. Further, ReaxFF simulations and density functional theory (DFT) calculations were performed on the pyrolysis process of R1234yf, R134a and R513A. It is revealed that the main pyrolysis reaction pathways of working fluids can be divided into three types: the reactions of working fluid molecules collision with F radical (FCR) or H radical (HCR), and the self-decomposition reactions of working fluid molecules (SDR). In R513A, F and H radicals are the origin for the affected thermal stability of R1234yf. The results are of great significance to guide the selection of additive species to enhance the thermal stability of HFO working fluid.

Suggested Citation

  • Xin, Liyong & Yu, Wei & Liu, Chao & Liu, Lang & Wang, Shukun & Li, Xiaoxiao & Liu, Yu, 2023. "Thermal stability of a mixed working fluid (R513A) for organic Rankine cycle," Energy, Elsevier, vol. 263(PF).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pf:s0360544222030171
    DOI: 10.1016/j.energy.2022.126131
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    References listed on IDEAS

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    1. Huo, Erguang & Hu, Zheng & Wang, Shukun & Xin, Liyong & Bai, Mengna, 2022. "Thermal decomposition and interaction mechanism of HFC-227ea/n-hexane as a zeotropic working fluid for organic Rankine cycle," Energy, Elsevier, vol. 246(C).
    2. Xin, Liyong & Liu, Chao & Tan, Luxi & Xu, Xiaoxiao & Li, Qibin & Huo, Erguang & Sun, Kuan, 2021. "Thermal stability and pyrolysis products of HFO-1234yf as an environment-friendly working fluid for Organic Rankine Cycle," Energy, Elsevier, vol. 228(C).
    3. Huo, Erguang & Liu, Chao & Xu, Xiaoxiao & Li, Qibin & Dang, Chaobin & Wang, Shukun & Zhang, Cheng, 2019. "The oxidation decom position mechanisms of HFO-1336mzz(Z) as an environmentally friendly refrigerant in O2/H2O environment," Energy, Elsevier, vol. 185(C), pages 1154-1162.
    4. Xu, Bin & Rathod, Dhruvang & Yebi, Adamu & Filipi, Zoran & Onori, Simona & Hoffman, Mark, 2019. "A comprehensive review of organic rankine cycle waste heat recovery systems in heavy-duty diesel engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 145-170.
    5. Jianfeng Huang & Nicolas Hörmann & Emad Oveisi & Anna Loiudice & Gian Luca De Gregorio & Oliviero Andreussi & Nicola Marzari & Raffaella Buonsanti, 2018. "Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    6. Mota-Babiloni, Adrián & Belman-Flores, J.M. & Makhnatch, Pavel & Navarro-Esbrí, Joaquín & Barroso-Maldonado, J.M., 2018. "Experimental exergy analysis of R513A to replace R134a in a small capacity refrigeration system," Energy, Elsevier, vol. 162(C), pages 99-110.
    7. Ancona, Maria Alessandra & Bianchi, Michele & Branchini, Lisa & De Pascale, Andrea & Melino, Francesco & Peretto, Antonio & Poletto, Chiara & Torricelli, Noemi, 2022. "Solar driven micro-ORC system assessment for residential application," Renewable Energy, Elsevier, vol. 195(C), pages 167-181.
    8. Feng, Biao & Yang, Zhao & Zhai, Rui, 2018. "Experimental study on the influence of the flame retardants on the flammability of R1234yf," Energy, Elsevier, vol. 143(C), pages 212-218.
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    2. Chen, Yubo & Yang, Zhao & Zhang, Yong & He, Hongxia & Li, Jie, 2023. "Combustion and interaction mechanism of 2,3,3,3-tetrafluoropropene/1,1,1,2-tetrafluoroethane as an environmentally friendly mixed working fluid," Energy, Elsevier, vol. 284(C).

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