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Effects of P-based additives on agricultural biomass torrefaction and particulate matter emissions from fuel combustion

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  • Li, Yu
  • Tan, Zhiwu
  • Zhu, Youjian
  • Zhang, Wennan
  • Du, Zhenyi
  • Shao, Jingai
  • Jiang, Long
  • Yang, Haiping
  • Chen, Hanping

Abstract

The large scale utilization of agricultural biomass as fuel is restricted by the feedstock properties of low energy density, high moisture content, heterogeneous composition and chemical impurities. In this work, torrefaction of biomass fuel with NH4H2PO4 additive was carried out to investigate the effects of NH4H2PO4 mixing ratio and torrefaction temperature on the properties of the torrefied fuel and particulate matter (PM) emission characteristics from combustion. The results show many benefits from NH4H2PO4 addition in biomass feedstock: 1) the removal of O and retention of C can be enhanced leading to lower mass and energy losses during torrefaction, 2) more Cl and S are released to gas phase leading to a lower absolute content of Cl and S in the torrefied fuel, and 3) the occurrence of alkali and alkaline earth metals change significantly. Moreover, the emissions of the fine particulate matters (PM1) from the torrefied fuels are clearly reduced when NH4H2PO4 is added and the reduction rate is closely related to P/K molar ratio with the maximum reduction rate achieved at P/K molar ratio equal to 1. These results suggest that the proposed method can effectively upgrade the fuel qualities and reduce PM1 emissions from the fuel combustion.

Suggested Citation

  • Li, Yu & Tan, Zhiwu & Zhu, Youjian & Zhang, Wennan & Du, Zhenyi & Shao, Jingai & Jiang, Long & Yang, Haiping & Chen, Hanping, 2022. "Effects of P-based additives on agricultural biomass torrefaction and particulate matter emissions from fuel combustion," Renewable Energy, Elsevier, vol. 190(C), pages 66-77.
    • Handle: RePEc:eee:renene:v:190:y:2022:i:c:p:66-77
    DOI: 10.1016/j.renene.2022.03.101
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    2. Shi, Xiaopeng & Li, Pan & Wang, Xianhua & Song, Jiande & Fang, Shuqi & Chang, Chun & Pang, Shusheng, 2022. "Enhancement of the production of aromatics and bio-syngas from microwave ex-situ pyrolysis based on Zn/Zr modified biochar and multi-catalysts," Energy, Elsevier, vol. 261(PB).
    3. Sui, Haiqing & Chen, Jianfeng & Cheng, Wei & Zhu, Youjian & Zhang, Wennan & Hu, Junhao & Jiang, Hao & Shao, Jing'ai & Chen, Hanping, 2024. "Effect of oxidative torrefaction on fuel and pelletizing properties of agricultural biomass in comparison with non-oxidative torrefaction," Renewable Energy, Elsevier, vol. 226(C).
    4. Ruan, Renhui & Wang, Guan & Li, Shuaishuai & Wang, Min & Lin, Hui & Tan, Houzhang & Wang, Xuebin & Liu, Feng, 2024. "The effect of alkali and alkaline earth metals (AAEMs) on combustion and PM formation during oxy-fuel combustion of coal rich in AAEMs," Energy, Elsevier, vol. 293(C).
    5. Kostyniuk, Andrii & Likozar, Blaž, 2024. "Wet torrefaction of biomass waste into high quality hydrochar and value-added liquid products using different zeolite catalysts," Renewable Energy, Elsevier, vol. 227(C).
    6. Liu, Tianyu & Wen, Chang & Li, Changkang & Yan, Kai & Li, Rui & Jing, Zhenqi & Zhang, Bohan & Ma, Jingjing, 2022. "Integrated water washing and carbonization pretreatment of typical herbaceous and woody biomass: Fuel properties, combustion behaviors, and techno-economic assessments," Renewable Energy, Elsevier, vol. 200(C), pages 218-233.
    7. Lasek, Janusz A. & Matuszek, Katarzyna & Hrycko, Piotr & Głód, Krzysztof & Li, Yueh-Heng, 2023. "The combustion of torrefied biomass in commercial-scale domestic boilers," Renewable Energy, Elsevier, vol. 216(C).
    8. Wentao Li & Mingfeng Wang & Fanbin Meng & Yifei Zhang & Bo Zhang, 2022. "A Review on the Effects of Pretreatment and Process Parameters on Properties of Pellets," Energies, MDPI, vol. 15(19), pages 1-23, October.
    9. Zhou, Li & Li, Fashe & Zhang, Huicong & Duan, Yaozong & Wang, Hua, 2024. "Effect of phospholipids on the oxidative reactivity and microstructure of soot particles from Jatropha biodiesel combustion," Applied Energy, Elsevier, vol. 354(PB).

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