IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v259y2022ics0360544222019326.html
   My bibliography  Save this article

Preparation and characterization of CaCl2·6H2O based binary inorganic eutectic system for low temperature thermal energy storage

Author

Listed:
  • Wang, Yan
  • Sui, Jiahao
  • Xu, Zijie

Abstract

As a cost-effective phase change thermal storage material, calcium chloride hexahydrate exhibits high heat capacity and holds tremendous promise in building energy savings. However, as a kind of hydrated salt, it also suffers from the issues of phase stratification and high degree of supercooling. Thus, present work has studied the inorganic mixtures of hydrated chloride salts and prepared a novel kind of binary eutectic phase change thermal storage material via replacing calcium chloride hexahydrate by various mass ration of magnesium chloride hexahydrate. The initial research results showed that both the components liquefied simultaneously during melting and the phase stratification of eutectic system could be effectively alleviated. Nucleating agent led to a good restrain to the supercooling of inorganic eutectic and the subcooling degree could be found as small as 1 °C.Meanwhile, the small amount of additive would little affect the melting point and enthalpy of fusion of energy storage material. The thermal cycling tests showed that our as-prepared eutectic salts exhibited good thermal reliability with fixed phase transition temperature and almost no diminution of enthalpy, which indicated that this novel binary eutectic material possessed excellent and stable performance suitable for heat storage in building energy savings.

Suggested Citation

  • Wang, Yan & Sui, Jiahao & Xu, Zijie, 2022. "Preparation and characterization of CaCl2·6H2O based binary inorganic eutectic system for low temperature thermal energy storage," Energy, Elsevier, vol. 259(C).
    • Handle: RePEc:eee:energy:v:259:y:2022:i:c:s0360544222019326
    DOI: 10.1016/j.energy.2022.125036
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222019326
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.125036?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Macmanus Chinenye Ndukwu & Lyes Bennamoun & Merlin Simo-Tagne, 2021. "Reviewing the Exergy Analysis of Solar Thermal Systems Integrated with Phase Change Materials," Energies, MDPI, vol. 14(3), pages 1-26, January.
    2. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    3. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    4. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    5. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    6. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    7. Englmair, Gerald & Moser, Christoph & Furbo, Simon & Dannemand, Mark & Fan, Jianhua, 2018. "Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system," Applied Energy, Elsevier, vol. 221(C), pages 522-534.
    8. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xinchen Zhou & Xiang Xu & Jiping Huang, 2023. "Adaptive multi-temperature control for transport and storage containers enabled by phase-change materials," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    2. Li, T.X. & Xu, J.X. & Wu, D.L. & He, F. & Wang, R.Z., 2019. "High energy-density and power-density thermal storage prototype with hydrated salt for hot water and space heating," Applied Energy, Elsevier, vol. 248(C), pages 406-414.
    3. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    4. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    5. Dubey, Abhayjeet kumar & Sun, Jingyi & Choudhary, Tushar & Dash, Madhusmita & Rakshit, Dibakar & Ansari, M Zahid & Ramakrishna, Seeram & Liu, Yong & Nanda, Himansu Sekhar, 2023. "Emerging phase change materials with improved thermal efficiency for a clean and sustainable environment: An approach towards net zero," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    6. Giovanni Salvatore Sau & Valerio Tripi & Anna Chiara Tizzoni & Raffaele Liberatore & Emiliana Mansi & Annarita Spadoni & Natale Corsaro & Mauro Capocelli & Tiziano Delise & Anna Della Libera, 2021. "High-Temperature Chloride-Carbonate Phase Change Material: Thermal Performances and Modelling of a Packed Bed Storage System for Concentrating Solar Power Plants," Energies, MDPI, vol. 14(17), pages 1-17, August.
    7. Huo, Ying-Jie & Yan, Ting & Wu, Shao-Fei & Kuai, Zi-Han & Pan, Wei-Guo, 2024. "Preparation and thermal properties of palmitic acid/copper foam phase change materials," Energy, Elsevier, vol. 293(C).
    8. Wang, Ting & Qiu, Xiaolin & Chen, Xiaojing & Lu, Lixin & Zhou, Binglin, 2022. "Sponge-like form-stable phase change materials with embedded graphene oxide for enhancing the thermal storage efficiency and the temperature response in transport packaging applications," Applied Energy, Elsevier, vol. 325(C).
    9. Costa, Sol Carolina & Kenisarin, Murat, 2022. "A review of metallic materials for latent heat thermal energy storage: Thermophysical properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    10. Liu, Chenzhen & Cheng, Qingjiang & Li, Baohuan & Liu, Xinjian & Rao, Zhonghao, 2023. "Recent advances of sugar alcohols phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    11. Hekimoğlu, Gökhan & Nas, Memduh & Ouikhalfan, Mohammed & Sarı, Ahmet & Tyagi, V.V. & Sharma, R.K. & Kurbetci, Şirin & Saleh, Tawfik A., 2021. "Silica fume/capric acid-stearic acid PCM included-cementitious composite for thermal controlling of buildings: Thermal energy storage and mechanical properties," Energy, Elsevier, vol. 219(C).
    12. Yang, Guokun & Liu, Tianle & Aleksandravih, Blinov Pavel & Wang, Yazhou & Feng, Yingtao & Wen, Dayang & Fang, Changliang, 2022. "Temperature regulation effect of low melting point phase change microcapsules for cement slurry in nature gas hydrate-bearing sediments," Energy, Elsevier, vol. 253(C).
    13. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    14. Zhang, Huili & Kong, Weibin & Tan, Tianwei & Baeyens, Jan, 2017. "High-efficiency concentrated solar power plants need appropriate materials for high-temperature heat capture, conveying and storage," Energy, Elsevier, vol. 139(C), pages 52-64.
    15. Tombrink, Jonas & Bauer, Dan, 2022. "Demand-based process steam from renewable energy: Implementation and sizing of a latent heat thermal energy storage system based on the Rotating Drum Heat Exchanger," Applied Energy, Elsevier, vol. 321(C).
    16. Yang, Lizhong & Villalobos, Uver & Akhmetov, Bakytzhan & Gil, Antoni & Khor, Jun Onn & Palacios, Anabel & Li, Yongliang & Ding, Yulong & Cabeza, Luisa F. & Tan, Wooi Leong & Romagnoli, Alessandro, 2021. "A comprehensive review on sub-zero temperature cold thermal energy storage materials, technologies, and applications: State of the art and recent developments," Applied Energy, Elsevier, vol. 288(C).
    17. Zhong, Yajuan & Zhao, Bingchen & Lin, Jun & Zhang, Feng & Wang, Haoran & Zhu, Zhiyong & Dai, Zhimin, 2019. "Encapsulation of high-temperature inorganic phase change materials using graphite as heat transfer enhancer," Renewable Energy, Elsevier, vol. 133(C), pages 240-247.
    18. Wang, Wei & He, Xibo & Shuai, Yong & Qiu, Jun & Hou, Yicheng & Pan, Qinghui, 2022. "Experimental study on thermal performance of a novel medium-high temperature packed-bed latent heat storage system containing binary nitrate," Applied Energy, Elsevier, vol. 309(C).
    19. Mohammad Reza Safaei & Hamid Reza Goshayeshi & Issa Chaer, 2019. "Solar Still Efficiency Enhancement by Using Graphene Oxide/Paraffin Nano-PCM," Energies, MDPI, vol. 12(10), pages 1-13, May.
    20. Mousavi, Seyedmostafa & Rismanchi, Behzad & Brey, Stefan & Aye, Lu, 2021. "PCM embedded radiant chilled ceiling: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:259:y:2022:i:c:s0360544222019326. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.