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Thermogravimetric analysis of solid biomass fuels and corresponding emission of fine particles

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  • Sitek, Tomáš
  • Pospíšil, Jiří
  • Poláčik, Ján
  • Chýlek, Radomír

Abstract

A significant problem of biofuel combustion is the emerging emissions of particulate matter. This paper deals with the experimental determination of the particulate matter emission characteristics of 27 different types of conventional and less traditional solid biofuels. Thermogravimetric analysis is used for the controlled heating of all tested samples from 25 °C to 650 °C with a 10 °C·min−1 heating rate. The analysis is performed for two atmosphere compositions, namely 21 % O2 and 0 % O2. The resulting flue gas is fed to an instrument allowing fine particles' detection ranging from 18 to 545 nm in diameter. The relation between the temperature of fuel samples and the number and mass of the generated particles is investigated. The percentage of the original sample mass converted to particles is determined. Subsequently, particulate matter emission is expressed as a relation to sample ash content and sample volatile matter content. The specific particulate matter emissions range of all tested samples are expressed per megajoule of higher heating value (HHV): 1.02–2.67·1015 #·MJ−1 and 694–2844 mg MJ−1 in the atmosphere with 21 % of O2 and 1.11–3.29·1015 #·MJ−1 and 898–6823 mg MJ−1 in the atmosphere without oxygen (pyrolysis).

Suggested Citation

  • Sitek, Tomáš & Pospíšil, Jiří & Poláčik, Ján & Chýlek, Radomír, 2021. "Thermogravimetric analysis of solid biomass fuels and corresponding emission of fine particles," Energy, Elsevier, vol. 237(C).
  • Handle: RePEc:eee:energy:v:237:y:2021:i:c:s0360544221018570
    DOI: 10.1016/j.energy.2021.121609
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    References listed on IDEAS

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    1. Qiu, Guoquan, 2013. "Testing of flue gas emissions of a biomass pellet boiler and abatement of particle emissions," Renewable Energy, Elsevier, vol. 50(C), pages 94-102.
    2. Carvalho, Lara & Wopienka, Elisabeth & Pointner, Christian & Lundgren, Joakim & Verma, Vijay Kumar & Haslinger, Walter & Schmidl, Christoph, 2013. "Performance of a pellet boiler fired with agricultural fuels," Applied Energy, Elsevier, vol. 104(C), pages 286-296.
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    Cited by:

    1. Nikola Čajová Kantová & Michal Holubčík & Alexander Čaja & Juraj Trnka & Jozef Jandačka, 2022. "Analyses of Pellets Produced from Spruce Sawdust, Spruce Bark, and Pine Cones in Different Proportions," Energies, MDPI, vol. 15(8), pages 1-9, April.
    2. Chong, Cheng Tung & Fan, Yee Van & Lee, Chew Tin & Klemeš, Jiří Jaromír, 2022. "Post COVID-19 ENERGY sustainability and carbon emissions neutrality," Energy, Elsevier, vol. 241(C).
    3. Šnajdárek, Ladislav & Chýlek, Radomír & Pospíšil, Jiří, 2022. "Slow thermal decomposition of lignocelluloses compared to numerical model: Fine particle emission, gaseous products analysis," Energy, Elsevier, vol. 261(PB).
    4. Singara Veloo Kanageswari & Lope G. Tabil & Shahabaddine Sokhansanj, 2022. "Dust and Particulate Matter Generated during Handling and Pelletization of Herbaceous Biomass: A Review," Energies, MDPI, vol. 15(7), pages 1-18, April.

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