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Co-processing of pyrolysis vapors with bio-chars for ex-situ upgrading

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  • Jin, Wenjia
  • Singh, Kaushlendra
  • Zondlo, John

Abstract

Co-processing of woody biomass with two bio-chars (bio-chars made from switchgrass and red oak bark) was studied as a way of upgrading the pyrolysis vapors. The clean woodchips were pyrolyzed with and without bio-chars under atmospheric pressure at the target temperature of 500 °C. The co-processing with both bio-chars showed a significant influence on the bio-oil yields, moisture content and pH value of bio-oils. However, the vapor-upgrading process significantly decreased the carbon yield in the bio-oil when using switchgrass bio-char was used for co-processing. The bio-oil yield decreased from 49.31% (non-bio-char) to 44.81% with the switchgrass bio-char and to 48.68% with the bio-char from the red oak bark. The lost mass of bio-oil ended-up in the gaseous phase as reflected in an increased content of carbon dioxide and carbon monoxide. The gaseous-phase composition of hydrogen increased from 0.82% to 3.74%, of carbon dioxide from 21.16% to 32.33%, and of carbon monoxide from 16.49% to 23.19% with the addition of the switchgrass bio-char compared to non-bio-char pyrolysis.

Suggested Citation

  • Jin, Wenjia & Singh, Kaushlendra & Zondlo, John, 2015. "Co-processing of pyrolysis vapors with bio-chars for ex-situ upgrading," Renewable Energy, Elsevier, vol. 83(C), pages 638-645.
    • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:638-645
    DOI: 10.1016/j.renene.2015.04.067
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    References listed on IDEAS

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    1. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
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    3. Kim, Kwang Ho & Kim, Tae-Seung & Lee, Soo-Min & Choi, Donha & Yeo, Hwanmyeong & Choi, In-Gyu & Choi, Joon Weon, 2013. "Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis," Renewable Energy, Elsevier, vol. 50(C), pages 188-195.
    4. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
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    2. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.

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